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Journal : JURNAL PHOTON

IKATAN SILANG POLIURETAN DARI METILEN -4,4’ DIFENILDIISOSIANAT (4,4’-MDI), POLIETILEN GLIKOL 400 (PEG 400), DAN MINYAK BEKAS PENGGORENGAN -, Prasetya; Siregar, Sri Hilma
Sistem Informasi Vol 4 No 1 (2013): Jurnal Photon
Publisher : Fakultas MIPA dan Kesehatan Universitas Muhammadiyah Riau

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (407.366 KB)

Abstract

Sintesis poliuretan telah dilakukan dengan menggunakan monomer 4,4-MDI, PEG 400, dan minyak Bekas Penggorengan. Gugus fungsi karakteristik poliuretan, dan ikatan silang (derajat penggembungan), masing-masingnya dianalisis dengan spektofotometer FT-IR, beberapa pelarut (THF). Berdasarkan hasil penelitian diketahui serapan inframerah poliuretan hasil sintesis memiliki korelasi dengan serapan inframerah poliuretan standar. Hasil pengujian derajat penggembungan menunjukkan poliuretan hasil sintesis memiliki derajat penggembungan.
OPTIMUM CONDITION OF BIOETANOL PRODUCTION VIA ACIDIC HYDROLYSIS FROM PINEAPLE (Ananas comosus Merr.) PEEL WASTE IN KUALU VILLAGE-KAMPAR Hilma, Rahmiwati; Akbar, Unggul; Prasetya, -
Sistem Informasi Vol 7 No 02 (2017): Jurnal Photon
Publisher : Fakultas MIPA dan Kesehatan Universitas Muhammadiyah Riau

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (798.469 KB)

Abstract

Bioethanol is an alternative and potential fuel derived from plants, which has the ability to reduce CO2 emissions. It contains sugar that can be utilized and processed into bioethanol. This study aims to produce bioethanol from pineapple peel (Ananas comosus Merr.) through acidic hydrolysis and fermentation process using Sacharomyces cereviceae. This research was expected to know the optimum condition of S. Cereviceae mass and the time of fermentation on the conversion of pineapple peel into bioethanol towards amount and content of ethanol produced. The hydrolysis was using sulfuric acid (H2SO4), fermented with variations yeast 20, 40 and 60 gram and 2, 4 and 6 days of time variations. The resulting bioethanol was purified using a distillation process, then analyzed by gas chromatography. The results showed that optimum ethanol content was obtain in yeasts 20 and 40 grams and 2 days of fermentation. The resulting ethanol content was 26.3% and 24.6%.
IKATAN SILANG POLIURETAN DARI METILEN -4,4’ DIFENILDIISOSIANAT (4,4’-MDI), POLIETILEN GLIKOL 400 (PEG 400), DAN MINYAK BEKAS PENGGORENGAN Prasetya -; Sri Hilma Siregar
Sistem Informasi Vol 4 No 1 (2013): Jurnal Photon
Publisher : LPPM Universitas Muhammadiyah Riau

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.37859/jp.v4i1.170

Abstract

Sintesis poliuretan telah dilakukan dengan menggunakan monomer 4,4'-MDI, PEG 400, dan minyak Bekas Penggorengan. Gugus fungsi karakteristik poliuretan, dan ikatan silang (derajat penggembungan), masing-masingnya dianalisis dengan spektofotometer FT-IR, beberapa pelarut (THF). Berdasarkan hasil penelitian diketahui serapan inframerah poliuretan hasil sintesis memiliki korelasi dengan serapan inframerah poliuretan standar. Hasil pengujian derajat penggembungan menunjukkan poliuretan hasil sintesis memiliki derajat penggembungan.
OPTIMUM CONDITION OF BIOETANOL PRODUCTION VIA ACIDIC HYDROLYSIS FROM PINEAPLE (Ananas comosus Merr.) PEEL WASTE IN KUALU VILLAGE-KAMPAR Rahmiwati Hilma; Unggul Akbar; - Prasetya
Sistem Informasi Vol 7 No 02 (2017): Jurnal Photon
Publisher : LPPM Universitas Muhammadiyah Riau

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.37859/jp.v7i02.519

Abstract

Bioethanol is an alternative and potential fuel derived from plants, which has the ability to reduce CO2 emissions. It contains sugar that can be utilized and processed into bioethanol. This study aims to produce bioethanol from pineapple peel (Ananas comosus Merr.) through acidic hydrolysis and fermentation process using Sacharomyces cereviceae. This research was expected to know the optimum condition of S. Cereviceae mass and the time of fermentation on the conversion of pineapple peel into bioethanol towards amount and content of ethanol produced. The hydrolysis was using sulfuric acid (H2SO4), fermented with variations yeast 20, 40 and 60 gram and 2, 4 and 6 days of time variations. The resulting bioethanol was purified using a distillation process, then analyzed by gas chromatography. The results showed that optimum ethanol content was obtain in yeasts 20 and 40 grams and 2 days of fermentation. The resulting ethanol content was 26.3% and 24.6%.
Sintesis Biodiesel dari Minyak Jelantah Menggunakan Katalis Bentonit, K-Bentonit Dan K-Bentonit Terimpregnasi CaO Hasmalina Nasution; Wahyuni Puspita Sanda; Rahmadini Syafri; Sri Hilma Siregar; Yuhelson; Prasetya
Sistem Informasi Vol 12 No 1 (2021): Jurnal Photon
Publisher : LPPM Universitas Muhammadiyah Riau

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.37859/jp.v12i1.3312

Abstract

Biodiesel is an alternative fuel for diesel engines produced by a transesterification reaction between vegetable oils or animal fats containing triglycerides and alcohol, one of which is methanol. The use of homogeneous base catalysts in the synthesis of biodiesel still poses a problem for the environment because it is difficult to separate, therefore, researchers use variations of heterogeneous base catalysts. The synthesis of biodiesel from used cooking oil was carried out through a transesterification reaction with technical methanol with a catalyst of CaO impregnated Bentonite, K-Bentonite and Bentonite using the reflux method at 65ºC for 2 hours. The ratio of the volume of oil, methanol, and catalyst used is 5:1:1%-w oil. Based on the research that has been done, the yield of each catalyst is 84.85% bentonite, 84.24% K-bentonite and 89.27% ​​K-bentonite-CaO. The characteristics of biodiesel obtained from each of these catalysts such as calorific value and density have met the quality requirements of the Indonesian National Standard (SNI 7182-2012), except for the acid number and kinematic viscosity which still exceed the quality requirements of SNI 7182-2012.
Karakterisasi Hasil Sintesis Fotokatalis TiO2 Dengan Metode Sol-Gel dan Hidrothermal Untuk Aplikasi Limbah Petroleum Manja Nanda Resa Manja; Hasmalina Nasution; Zumrotun Nasihah; Tengku Finalia; Laila Rahmadanis; Prasetya Prasetya; Rahmadini Syafri; Sri Hilma Siregar
Sistem Informasi Vol 12 No 2 (2022): Jurnal Photon
Publisher : LPPM Universitas Muhammadiyah Riau

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.37859/jp.v12i2.3473

Abstract

Petroleum waste (crude oil) has become one of the sources of pollution in the sea. The pollution caused comes from several factors, oil spills from tankers, deliberate disposal of irresponsible industries. The layer of crude oil on the surface of the air holds back gas exchange from the atmosphere and reduces the solubility of oxygen in the waters so that it interferes with the respiration and photosynthesis processes in phytoplankton which are food producers in the sea. This study aims to characterize the synthesized TiO2 photocatalyst material using two methods, namely Sol-Gel (SG) and Hydrothermal (HD) which will then be used for applications in petroleum waste. To determine effectiveness of TiO2 photocatalyst in reducing crude oil spills on the sea surface based on fatty oil parameter tests. The synthesis of TiO2 was carried out by the solgel method (SG) and the hydrothermal method (HD) at various temperatures of 300 oC, 500 oC, and 700 oC. Characterization of the material formed using the SEM-EDX instrument, showed that in general it is spherical in shape, and is composed of C, O and Ti elements. The maximum effectiveness of SG-300, SG-500, and SG-700 was able to reduce fat oil content by 57.19%, 66.14% and 41.42% while HD-300, HD-500, and HD-700 were able to reduce fatty oil content. maximum of 60.87%. , 56.41% and 45.68% in the 120 minute irradiation time. The results showed that the photodegradation process in petroleum waste treatment using TiO2 material was able to reduce the fat oil content.