Bulletin of Chemical Reaction Engineering & Catalysis
2017: BCREC Volume 12 Issue 2 Year 2017 (August 2017)

Synthesis of SrO.SiO2 Catalyst and Its Application in the Transesterification Reactions of Soybean Oil

Nuni Widiarti (Chemistry Department, Faculty Mathematics and Science, Universitas Negeri Semarang)
Lisa Amalia Suryana (Chemistry Department, Faculty Mathematics and Science, Universitas Negeri Semarang)
Nanik Wijayati (Chemistry Department, Faculty Mathematics and Science, Universitas Negeri Semarang)
Endah Fitriani Rahayu (Chemistry Department, Faculty Mathematics and Science, Universitas Negeri Semarang)
Harjito Harjito (Chemistry Department, Faculty Mathematics and Science, Universitas Negeri Semarang)
Samuel Budi Wardhana (Chemistry Department, Faculty Mathematics and Science, Universitas Negeri Semarang)
Didik Prasetyoko (Chemistry Departmen,Faculty Mathematics and Science Institut Teknologi Sepuluh November, Surabaya)
Suprapto Suprapto (Chemistry Department, Faculty Mathematics and Science Institut Teknologi Sepuluh November, Surabaya)



Article Info

Publish Date
01 Aug 2017

Abstract

The synthesis and characterization of SrO.SiO2 were carried out. The rice hull ash was utilized as a source for SiO2. The SrO.SiO2 was prepared by sol-gel technique, and the ratios of SrO:SiO2 were      varied as 0:1, 1:0, 3:2, 2:4, and 2:7. The sol-gel was calcined at 800 oC for 4 hours. The result was    characterized using XRD and FTIR. The diffraction pattern shows that the diffraction angle was shifted, and the intensity of the main peaks was increased. This research indicated that the            crystallinity of SrO was improved at the higher SiO content. Further, a new peak was observed in the IR spectra at a wavenumber of 900 cm-1 indicating the appearance of new functional groups of the SrO.SiO2. The catalytic activity of SrO.SiO2 on transesterification reaction was optimized. The optimum condition was obtained at SrO.SiO2 of 2:7, reaction time of 30 minutes, reaction temperature of 65 oC, the amount of catalyst of 1 % w/v of reactants, and the biodiesel yield of 96.66 %. 

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Journal Info

Abbrev

bcrec

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis (e-ISSN: 1978-2993), an international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics studies, and chemical reaction ...