Indonesian Journal of Chemistry
Vol 20, No 3 (2020)

Synthesis and Characterization of Controlled-Release Urea Fertilizer from Superabsorbent Hydrogels

Salih Muharam (Department of Chemistry, Faculty of Science and Technology, Muhammadiyah University of Sukabumi, Jl. R. Syamsudin S.H. No. 50, Cikole, Sukabumi 43113, West Java, Indonesia)
Afria Fitri (Department of Chemistry, Faculty of Science and Technology, Muhammadiyah University of Sukabumi, Jl. R. Syamsudin S.H. No. 50, Cikole, Sukabumi 43113, West Java, Indonesia)
Lela Mukmilah Yuningsih (Department of Chemistry, Faculty of Science and Technology, Muhammadiyah University of Sukabumi, Jl. R. Syamsudin S.H. No. 50, Cikole, Sukabumi 43113, West Java, Indonesia)
Yulia Mariana Tessa Ayudia Putri (Department of Chemistry, Faculty of Mathematics and Natural Science, Universitas Indonesia, Pondok Cina, Depok 16424, West Java, Indonesia)
Isnaini Rahmawati (Department of Chemistry, Faculty of Mathematics and Natural Science, Universitas Indonesia, Pondok Cina, Depok 16424, West Java, Indonesia)



Article Info

Publish Date
09 May 2020

Abstract

It is very important to develop controlled-release fertilizers to ensure efficiency and environmental protection. This study aims to make a superabsorbent hydrogel-based controlled-release urea fertilizer. Superabsorbent hydrogels were prepared from the cellulose of corn cobs cross-linking with epichlorohydrin, and then an amount of urea as a fertilizer was stored inside the hydrogels (GEL-A). The GEL-A functionalization with carboxy-methyl was also carried out in this study to improve the hydrophilicity of hydrogels (GEL-B). GEL-A and GEL-B were immersed in water at a certain pH and temperature range and the urea concentration released from the hydrogels was monitored by a spectrophotometer. The results showed that the urea released by GEL-A and GEL-B was not much different. Respectively, the urea efficiency of GEL-A and GEL-Bwas around 5.29% and 5.56% for 180 min. The urea released from both hydrogels was not significantly affected by changes in the temperature of the solution. Urea release was influenced by pH, and the rate of urea release of GEL-B was faster than GEL-A, so pH control was needed in the application of this slow-release fertilizer.

Copyrights © 2020






Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...