JKPK (Jurnal Kimia dan Pendidikan Kimia)
Vol 4, No 3 (2019): JKPK (Jurnal Kimia dan Pendidikan Kimia)

Synthesis and Characterization of Material LiNi0.8Co0.15Al0.05O2 Using One-Step Co-Precipitation Method for Li-Ion Batteries

Cornelius Satria Yudha (Progam Studi Magister Teknik Kimia, Fakultas Teknik, Universitas Sebelas Maret, Jl. Ir. Sutami No. 36A, Surakarta, Jawa Tengah, 57126)
Luthfi Mufidatul Hasanah (Progam Studi Magister Teknik Kimia, Fakultas Teknik, Universitas Sebelas Maret, Jl. Ir. Sutami No. 36A, Surakarta, Jawa Tengah, 57126)
Soraya Ulfa Muzayanha (Progam Studi Magister Teknik Kimia, Fakultas Teknik, Universitas Sebelas Maret, Jl. Ir. Sutami No. 36A, Surakarta, Jawa Tengah, 57126)
Hendri Widiyandari (Program Studi Fisika, Fakultas MIPA, Universitas Sebelas Maret, Jl. Ir. Sutami No. 36A, Surakarta, Jawa Tengah, 57126)
Agus Purwanto (Progam Studi Magister Teknik Kimia, Fakultas Teknik, Universitas Sebelas Maret, Jl. Ir. Sutami No. 36A, Surakarta, Jawa Tengah, 57126)



Article Info

Publish Date
31 Dec 2019

Abstract

Li-ion battery is an energy storage device which could be applied as power source for electronic devices. The capacity of a battery is determined by the cathode material. Over this last decade, high nickel content cathode material is applied for electric vehicular technology. This study aims to synthesize a nickel-rich cathode material, LiNi0.8Co0.15Al0.05O2 (NCA) via one-step co-precipitation and study its characteristics. The Ni, Co and Al metal ion conversion during co-precipitation were analyzed using Atomic Adsorption Spectroscopy (AAS). Based on X-Ray diffraction analysis, NCA sample exhibited hexagonal-layered structure with high crystallinity. Based on Scherrer equation, the mean crystallite diameter of NCA sample is 40 nm. Scanning electron microscope (SEM) showed micron-sized homogenous particles with smooth surface. The final composition of Ni, Co and Al metal were confirmed using XRF. The capacity of the battery was determined using galvanostic test method with voltage range of 2.7-4.25 V using graphite as the counter anode. The initial specific discharge capacity of NCA is 60 mAh/g while the capacity loss per cycle is 1%.

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Journal Info

Abbrev

jkpk

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

The JKPK (Jurnal Kimia dan Pendidikan Kimia) is a national journal, published three times a year in April, August, and December, containing research articles on Chemistry and Chemistry ...