Indonesian Journal of Chemistry
Vol 22, No 3 (2022)

Ion Impregnation Effect of Fe, Cu, Cr-attributed Mordenite on Stearic Acid Cracking

Abdulloh Abdulloh (Department of Chemistry, Faculty of Science and Technology, Airlangga University, Surabaya 60115, Indonesia)
Ulfa Rahmah (Department of Chemistry, Faculty of Science and Technology, Airlangga University, Surabaya 60115, Indonesia)
Satya Candra Wibawa Sakti (Department of Chemistry, Faculty of Science and Technology, Airlangga University, Surabaya 60115, Indonesia)
Alfa Akustia Widati (Department of Chemistry, Faculty of Science and Technology, Airlangga University, Surabaya 60115, Indonesia)
Ahmadi Jaya Permana (Department of Chemistry, Faculty of Science and Technology, Airlangga University, Surabaya 60115, Indonesia)
Rochadi Prasetya (Department of Chemistry, Faculty of Science and Technology, Airlangga University, Surabaya 60115, Indonesia)
Musbahu Adam Ahmad (Department of Chemistry, Faculty of Science and Technology, Airlangga University, Surabaya 60115, Indonesia)
Mochamad Zakki Fahmi (Department of Chemistry, Faculty of Science and Technology, Airlangga University, Surabaya 60115, Indonesia)



Article Info

Publish Date
09 Jun 2022

Abstract

The improvement in the design of mordenite-based catalysts focuses on the present study to fulfill the massive demand for bio-aviation fuel (BAF) as renewable energy. Modification of the mordenite through ionic impregnation of Fe, Cu, and Cr, has supported the mordenite to perform with better efficiency and activity in catalyzing the cracking process of stearic acid. The adjustment on catalytic activity was carried out by simply reacting the catalyst with stearic acid at 190 °C and investigating cracking products with Gas Chromatography-Mass Spectroscopy. The results of the GC-MS test of the cracking product showed the formation of alkane-alkene and aromatic compounds. BAF was selectively obtained (30.27%) when the reaction was catalyzed by FeCuCr/mordenite catalyst. The BAF derived from FeCuCr/mordenite contained hydrocarbons that include xylene, mesitylene, dodecane, tridecane, tetradecane, and pentadecane. However, reduced selectivity was realized (19.85%) when the reaction was catalyzed by nano FeCuCr/mordenite. Its hydrocarbon constituents include benzene, tetradecane, and pentadecane compounds.

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Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...