Mechatronics, Electrical Power, and Vehicular Technology
Vol 13, No 1 (2022)

Fabrication of nitrate ion sensor based on conductive polyaniline doped with nitrate using thick film technology

Charlotha Charlotha (Electrical and Informatic Department, Politeknik Manufaktur Negeri Bangka Belitung)
Robeth Viktoria Manurung (National Research and Innovation Agency – Indonesia, Reseacrh Center For Telecommunication)
Aminuddin Debataraja (Electro Engineering, Politeknik Negeri Jakarta)
Indra Dwisaputra (Electrical and Informatic Department, Politeknik Manufaktur Negeri Bangka Belitung)
Subkhan Subkhan (Mechanical Engineering Department, Politeknik Manufaktur Negeri Bangka Belitung)
Iqbal Syamsu (Institute of Semiconductor Technology (IHT), Laboratory for Emerging Nanometrology (LENA), Technische Universität Braunschweig, Langer Kamp 6, 38106 Braunschweig, Germany)



Article Info

Publish Date
29 Jul 2022

Abstract

Nitrate is one of the nutrients that can give an effect on the environment if it is applied in excess. It is also easily soluble in water and it has the potential to be a pollutant in groundwater by the over-process of fertilizer. Therefore, it needs a detected component to give the right measure for nitrate in the soil, called a nitrate ion sensor. It consists of three electrodes configuration, namely, working, counter, and reference electrodes with conductive polyaniline doped with Nitrate (NO₃‾) which is fabricated by thick film technology. In previous research, acidic media was used as a solvent for polyaniline, while this research used water (H2O) solvent. The result of characterization showed that particles were distributed evenly on the sample with the form of particles being small balls with a dimension of 0.18 µm and the percentage of atomic elements being: 91.96 % carbon, 3.14 % nitrogen, and 4.9 % oxygen. The performance of sensors was investigated using potentiostat with four concentrations of nitrate standard solution. The result showed good response with a voltage range in each concentration of nitrate standard solution being 0.5002 Volt (10 mg/l), 1.3552 Volt (20 mg/l), 1.1208 Volt (50 mg/l), and 0.8963 Volt (100 mg/l). It was found that nitrate sensors with nitrate-doped conductive polymer, polyaniline, as the sensitive membrane responded well to detecting nitrate elements in precision farming and the sensitivity showed that for every 1 mg/l concentration in nitrate standard solution, the voltage increases by 0.0007.

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Journal Info

Abbrev

mev

Publisher

Subject

Electrical & Electronics Engineering

Description

Mechatronics, Electrical Power, and Vehicular Technology (hence MEV) is a journal aims to be a leading peer-reviewed platform and an authoritative source of information. We publish original research papers, review articles and case studies focused on mechatronics, electrical power, and vehicular ...