KOVALEN: Jurnal Riset Kimia
Vol. 8 No. 3 (2022): December Edition

Efektivitas Fotodegradasi Lignin dari Limbah Ampas Sagu (Metroxylon sagu Rottb.) Menggunakan Katalis TiO₂: The Effectiveness of the Photodegradation of Lignin from Sago (Metroxylon sagu Rottb.) Waste Using TiO₂ Catalyst

Muh. Natsir (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Halu Oleo)
Aden Mula Pratiwi (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Halu Oleo)
Thamrin Azis (Unknown)
Nohong (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Halu Oleo)
Imran (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Halu Oleo)
Wa Ode Harlis (Department of Biology, Faculty of Mathematics and Natural Sciences, Universitas Halu Oleo)
Alimin (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Halu Oleo)
La Ode Kadidae (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Halu Oleo)
Ruslan (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Tadulako University)
C Bijang (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Patimura)
La Ode Abd Kadir (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Halu Oleo)
Laily Nurliana (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Halu Oleo)



Article Info

Publish Date
29 Dec 2022

Abstract

Lignin degradation from sago (Metroxylon sagu Rottb.) waste has been carried out using a TiO2 catalyst. This research aims to determine the effectiveness of lignin degradation from sago waste using a TiO2 catalyst. Lignin from sago pulp was isolated using 10% NaOH and characterized using Fourier Transform Infra Red (FTIR) spectroscopy. The results of the characterization using FTIR show that the absorption at wave number 2937.59 cm-1 is the -C-H stretching vibration of the alkane functional groups, the absorption at wave number 2360.87 cm-1 is the vibration of the C≡C triple bond, the wave numbers 1795.73 cm-1 and 1637.56 cm-1 are associated with the stretching of the carbonyl group. The absorption at wave number 1427.32 cm-1 is a C-H vibration connected to an unsaturated bond in an aromatic ring. Absorptions at wave number 1105.21 cm-1, 1128.36 cm-1, 1153.43 cm-1 were the stretching vibration of -C-H on the guaiasil ring, and the absorption at wave number 1022.27 cm-1 was the stretching vibration of C-O-C ether. From this spectrum, it can be seen that lignin is not completely pure because it is probably still mixed with cellulose. The results of the effectiveness test of lignin degradation using a TiO2 catalyst with the help of UV light were able to degrade the lignin isolated by 31.43%, for 3 hours at a lignin concentration of 40 ppm.

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Journal Info

Abbrev

kovalen

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

KOVALEN: Jurnal Riset Kimia is a peer-reviewed journal of chemistry published by the Tadulako University, Indonesia. This journal concern with publishing the original research articles, review articles, and the current issues related to chemistry. Publishing frequency 3 issues per year, in April, ...