Indonesian Journal of Chemistry
Vol 23, No 2 (2023)

Advanced Oxidation Processes of Amoxicillin Based on Visible Light Active Nitrogen-Doped TiO2 Photocatalyst

Kusuma Putri Suwondo (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Nurul Hidayat Aprilita (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Endang Tri Wahyuni (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)



Article Info

Publish Date
03 Apr 2023

Abstract

Environmental consequences during the COVID-19 pandemic have attracted attention due to the excessive use of antibiotics which lead to the release of the drug's residue, such as amoxicillin (AMX), into the environment. In this work, an advanced oxidation process based on a visible, active N-doped TiO2 photocatalyst was carried out to eliminate AMX. Nitrogen with different initial doping concentrations (15, 30, 45% w/w) was doped into TiO2 by the sol-gel method. The characterization technique such as XRD, FTIR, UV-SRS, and SEM-EDX revealed that nitrogen with 30% doping concentration improved the TiO2 response in the visible region, attributed to the lower band gap energy (2.97 eV). In the photodegradation processes, the TiO2-N (30%) photocatalyst possessed higher AMX degradation than undoped TiO2 for both UV and visible light irradiation. In an aqueous solution, the degradation percentage of AMX by TiO2-N (30%) was 68.5 and 84.12%, while the degradation percentage of AMX by TiO2 was 38.7 and 78.01% under visible and UV light, respectively.

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Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...