Journal Of Carbazon
Vol 1, No 2 (2023): December 2023

Development of Solid State Reference Electrode Based on Polypyrrole (PPy) and Screen Printed Electrode (SPE)

Sagir Alva (University of Mercu Buana, Jakarta, Indonesia)
Mas’ud Asadullah (Unknown)
Vivi Friliandita (Unknown)
Deni Shidqi Khaerudini (Unknown)



Article Info

Publish Date
27 Dec 2023

Abstract

In this study, a Polypyrrole doped KCl/KCl saturated (PPy-Cl/KCl) reference electrode had been successfully developed. In this development process, the PPy-Cl/KCl reference electrode that had been provided consisted of two stages of refinement, specifically the PPy-Cl/KCl 1 reference electrode which became the PPy-Cl/KCl 2 reference electrode. Furthermore, the PPy-Cl/KCl 2 SRE was made into 3 types with cycle variations of 10, 15, and 20 cycles and the mV response value test and Scanning Electron Microscopy (SEM) test were carried out. Regarding the variation results, PPy-Cl/KCl 2 SRE was obtained with 15 cycles as the best PPy-Cl/KCl 2 reference electrode with ∆mV value of 3.43 mV. Subsequently, the PPy-Cl/KCl 2 SRE with 15 cycles was involved in the characterization test using cyclic voltammetry (CV) testing, response testing vs Cl sensors and drift testing. In the CV testing, the PPy-Cl/KCl 2 SRE with 15 cycles indicated a voltammogram graphic pattern similar to the Ag/AgCl reference electrode as a commercial reference electrode. Moreover, in the response testing vs the Cl sensor, the PPy-Cl/KCl 2 SRE with 15 cycles provided a Nernstian number value of -54.5 mV/s with a testing range of 0.1-104 M, and in the PPy-Cl/SRE drift testing, KCl 2 with 15 cycles indicated fairly good stability, particularly with a drift value of 1 mV/minute which was achieved after the conditioning process after 3.5 minutes.

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Journal Info

Abbrev

carbazon

Publisher

Subject

Biochemistry, Genetics & Molecular Biology Chemistry Materials Science & Nanotechnology

Description

Journal of Carbazon is a journal published by Chemistry Department, Faculty of Science and Mathematics, USK Banda Aceh. The journal aims to disseminate cutting-edge research in all areas of chemistry both theoretical and experimental studies. Journal of Carbazon provides readers with original ...