Bulletin of Chemical Reaction Engineering & Catalysis
2019: BCREC Volume 14 Issue 1 Year 2019 (April 2019)

Synthesis of Titania Doped Copper Ferrite Photocatalyst and Its Photoactivity towards Methylene Blue Degradation under Visible Light Irradiation

Md. Noor Arifin (Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang)
Kaykobad Md. Rezaul Karim (Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang)
Hamidah Abdullah (Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang)
Maksudur R. Khan (Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang)



Article Info

Publish Date
15 Apr 2019

Abstract

This paper reports the photocatalytic decomposition of methylene blue (MB) over titania doped copper ferrite, CuFe2O4/TiO2 with 50 wt% loading, synthesized via sol-gel method. The synthesized photocatalyst was characterized by X-ray diffraction, UV-vis diffuse reflectance, and photoluminescence, Mott-Schottky (MS) analysis and linear sweep voltammetry (LSV). The catalyst loadings were varied from 0.25 – 1.0 g/L and the optimum catalyst loading found to be 0.5 g/L. At the optimum loading, the conversion achieved was 83.7%. The other loadings produced slightly lower conversions at 82.7%, 80.6% and 80.0%, corresponding to 0.25, 1 and 0.75 g/L after 3 hours of irradiation. The study on the effect of initial concentration indicated that 20 ppm as the optimum concentration, tested with 0.5 g/L catalyst loading. The spent catalyst was used for the recyclability test and demonstrated a high longevity with a degradation efficiency less than 6 % for each time interval. The novelty of this study lies on the new application of photocatalytic material, CuFe2O4/TiO2 on thiazine dye that shows remarkable activity and reusability performance under visible light irradiation. 

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Journal Info

Abbrev

bcrec

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis, a reputable international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics, and chemical reaction engineering. Scientific articles dealing with the following topics in ...