Bulletin of Chemical Reaction Engineering & Catalysis
2015: BCREC Volume 10 Issue 1 Year 2015 (April 2015)

Selective Synthesis of Benzaldehydes by Hypochlorite Oxidation of Benzyl Alcohols under Phase Transfer Catalysis

K. Bijudas (Department of Chemistry, N. S. S. College, Manjeri, Malappuram, Kerala - 676122)
P. Bashpa (Department of Chemistry, N. S. S. College, Manjeri, Malappuram, Kerala - 676122)
V. P. Bibin (Graduate Program, Department of Chemistry, N. S. S. College, Manjeri, Malappuram, Kerala - 676122)
Lakshmi Nair (Graduate Program, Department of Chemistry, N. S. S. College, Manjeri, Malappuram, Kerala - 676122)
A. P. Priya (Graduate Program, Department of Chemistry, N. S. S. College, Manjeri, Malappuram, Kerala - 676122)
M. Aswathy (Graduate Program, Department of Chemistry, N. S. S. College, Manjeri, Malappuram, Kerala - 676122)
C. Krishnendu (Graduate Program, Department of Chemistry, N. S. S. College, Manjeri, Malappuram, Kerala - 676122)
P. Lisha (Graduate Program, Department of Chemistry, N. S. S. College, Manjeri, Malappuram, Kerala - 676122)

Article Info

Publish Date
30 Apr 2015

Abstract

The selective synthesis of benazaldehyde and substituted benzaldehydes from corresponding benzyl al-cohols has been carried out by using hypochlorite as an oxidant in organic medium under phase trans-fer catalysis. The reaction is highly selective since no traces of benzoic acid or substituted benzoic acids have been detected and the yield is found to be more than 90%. The products obtained were precipi-tated as 2,4-dinitrophenylhydrazone and the recrystallised products were characterized by melting point and by spectrophotometric techniques like infra red and UV-Visible analysis. © 2015 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0)

Copyrights © 2015




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Journal Info
Bulletin of Chemical Reaction Engineering & Catalysis
Website

Abbrev

bcrec

Publisher

Masyarakat Katalis Indonesia - Indonesian Catalyst Society

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis, a reputable international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics, and chemical reaction engineering. Scientific articles dealing with the following topics in ...