IJOG : Indonesian Journal on Geoscience
Vol. 10 No. 2 (2023)

Aliphatic Biomarker Signatures of Crude Oil from Tarakan Subbasin, Tarakan Basin, North Kalimantan, Indonesia

Yulfi Zetra (Molecular Geochemistry Laboratory, Department of Chemistry, Faculty of Science and Analysis Data, Institut Teknologi Sepuluh Nopember, Surabaya, Indonesia)
R.Y. Perry Burhan (Molecular Geochemistry Laboratory, Department of Chemistry, Faculty of Science and Analysis Data, Institut Teknologi Sepuluh Nopember, Surabaya, Indonesia)
Maulida Fitriyyah (Molecular Geochemistry Laboratory, Department of Chemistry, Faculty of Science and Analysis Data, Institut Teknologi Sepuluh Nopember, Surabaya, Indonesia)
Zjahra Vianita Nugrahaeni (Molecular Geochemistry Laboratory, Department of Chemistry, Faculty of Science and Analysis Data, Institut Teknologi Sepuluh Nopember, Surabaya, Indonesia)



Article Info

Publish Date
13 Nov 2023

Abstract

Organic geochemical studies of crude oil from Pamusian Field, Tarakan Subbasin, Tarakan Basin, North Kalimantan, have been done. Biomarker aliphatic hydrocarbon fractions were identified using a combined gas chromatography-mass spectrometer (GC - MS). Identified biomarkers consist of n-alkane groups, isoprenoids, bicyclic sesquiterpenoids, and pentacyclic triterpenoids. The most abundant aliphatic hydrocarbon biomarker is pristane followed by n-C19. The existence of n-alkanes shows a homologous (n-C16- n-C30) with a unimodal distribution type. The abundance of n-C19 is higher than other n-alkanes, supported by LHCPI value of 2.03, as an indicator of organic matter derived from microbial organisms. The amount of long chain n-alkanes (n-C25- n-C30) is almost the same as medium chain n-alkanes (n-C19 - n-C24) indicating the source of organic compounds is not only from microbial organisms, but also from terrestrial higher plants. The presence of 8β (H)-drimane compounds together with homodrimane shows the presence of bacterial input on the formation of oil from organic compounds. Ratio of Pr/Ph is 3.76, ratio of drimane/homodrimane is 1.058, ratio of Pr/n-C17 is 34.41, and ratio of Ph/n-C18 is 16.02 indicating the source of organic compounds came from terrestrial higher plants deposited in the oxic environment, and disposed to increase biodegradation. The CPI value is 0.95, and the highest amount of 17α (H), 21β (H)-hopane compounds suggest that Tarakan Subbasin oil was mature, and the source of organic compounds was derived from bacteria Keywords: Tarakan Basin, organic geochemistry, aliphatic hydrocarbon fraction, CPI

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Journal Info

Abbrev

IJOG

Publisher

Subject

Earth & Planetary Sciences

Description

The spirit to improve the journal to be more credible is increasing, and in 2012 it invited earth scientists in East and Southeast Asia as well as some western countries to join the journal for the editor positions in the Indonesia Journal of Geology. This is also to realize our present goal to ...