Indonesian Journal of Chemistry
Vol 18, No 3 (2018)

Synthesis and Photoactivity of Fe3O4/TiO2-Co as a Magnetically Separable Visible Light Responsive Photocatalyst

Eko Sri Kunarti (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Indriana Kartini (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Akhmad Syoufian (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Karolina Martha Widyandari (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)



Article Info

Publish Date
30 Aug 2018

Abstract

Synthesis of magnetic photocatalyst, Fe3O4/TiO2-Co, with characterization and photoactivity examination have been conducted. The synthesis was initiated by preparation of Fe3O4 particles using coprecipitation method. The Fe3O4 particles were then coated with TiO2-Co at a various ratio of Fe3O4:TiO2 and concentration of Co(II) dopant. The Fe3O4/TiO2-Co was characterized by FTIR, XRD, TEM, SEM-EDX, VSM, and SR UV-visible methods. Photoactivity of the Fe3O4/TiO2-Co was carried out using methylene blue as a target molecule in degradation reaction within a batch system. By using optimum conditions, the degradation of methylene blue solution was performed under exposure to UV, visible light and dark condition. Results showed that the Fe3O4/TiO2-Co formation was confirmed by the presence of Fe3O4 and anatase diffraction peaks in the X-ray diffractogram. SR UV-Vis spectra indicated that the Fe3O4/TiO2-Co was responsive to visible light. Band gap energy of the Fe3O4/TiO2-Co with dopant concentration of 1; 5; 10 and 15% were 3.22; 3.12; 3.09 and 2.81 eV, respectively. The methylene blue solution can be well photodegraded at a pH of 10 for 210 min. The Fe3O4/TiO2-Co has the highest ability to methylene blue photodegradation with dopant concentration of 10% gave degradation yield of 80.51 and 95.38% under UV and visible irradiation, respectively.

Copyrights © 2018






Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...