Indonesian Journal of Chemistry
Vol 18, No 4 (2018)

Synthesis of Amorphous Aluminosilicates from Bintan’s Red Mud as Alumina Source

Futri Wulandari (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Sepuluh Nopember, Keputih, Sukolilo, Surabaya 60111, Indonesia)
Eka Putra Ramdhani (Department of Chemistry Education, Faculty of Teacher Training and Education, Universitas Maritim Raja Ali Haji, Jl. Politeknik Km. 24, Senggarang, Tanjung Pinang, Kepulauan Riau 29115, Indonesia)
Yatim Lailun Ni’mah (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Sepuluh Nopember, Keputih, Sukolilo, Surabaya 60111, Indonesia)
Ahmad Anwarud Dawam (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Sepuluh Nopember, Keputih, Sukolilo, Surabaya 60111, Indonesia)
Didik Prasetyoko (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Sepuluh Nopember, Keputih, Sukolilo, Surabaya 60111, Indonesia)



Article Info

Publish Date
12 Nov 2018

Abstract

Red mud is a generated by-product in alumina production from bauxite ore. In this study, Bintan’s red mud has been used as alumina and silica source to synthesize amorphous mesoporous aluminosilicates material. Alkali fusion method with a NaOH/red mud ratio 0.8; 1.0; 1.2; 1.4 and 1.5 followed by hydrolysis method was used to extract dissolved alumina and silica from red mud. Synthesis of amorphous aluminosilicates by hydrothermal method was conducted at 80 °C for 24 h. Cetyltrimethylammonium bromide (CTABr) was added as the structure directing agent. Aluminosilicate products were characterized using FTIR spectroscopy (Fourier Transform Infra-Red Spectroscopy), XRD (X-ray Diffraction), SEM (Scanning Electron Microscopy), and nitrogen adsorption-desorption. XRD and SEM result shows that the product was amorphous with low uniformity in terms of surface morphology and particle size. Nitrogen adsorption-desorption profile shows that all aluminosilicates products has a meso pore structure, confirmed by the highest pore distribution at 3.05–17.70 nm. The highest surface area and pore volume were obtained in ASM 0.8 (NaOH/red mud ratio = 0.8) i.e. 177.97 m2/g and 1.09 cm3/g, respectively.

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Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...