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Scientific Contribution Oil and Gas
Published by Kementerian Energi dan Sumber Daya Mineral
ISSN : 20893361     EISSN : 25410520     DOI : https://doi.org/10.29017/SCOG.44.1.492
Core Subject : Science, Social, Engineering,
Chemical Engineering, Chemistry & Bioengineering Earth & Planetary Sciences Energy Environmental Science
research activities, technology engineering development and laboratory in the oil and gas field including regional geology/basin modeling, petroleum geology, sedimentology, stratigraphy, petroleum geoscience, drilling and completion technology, production engineering, well simulation, formation evaluation, petrophysics, reservoir characterization, oil and gas reserves, reservoir modeling, field development/management, EOR, geomachanics, unconventional hydrocarbon technology, field processing facilities, flow assurance, gas technology/processing/storage, petroleum processing/refining technology, petroleum products, fuel quality/specification/storage, biofuel technology, corrosion/scale problem/water treatment, environment/remediation, CCUS, health and safety/petroleum hazard, emerging technologies
Arjuna Subject : Energi (semua kategori) - Teknologi Bahan Bakar
Articles 5 Documents
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Search results for , issue " Vol 41, No 1 (2018)" : 5 Documents clear
SIMULTANEOUS MEASUREMENT OF SYN-GAS COMPONENT (H2, CO2, CH4, AND CO) AS PRODUCT OF BIOMASS GASIFICATION BY USING VALIDATED GC-TCD METHOD Mulyana, Muhammad Rizky; Zuas, Oman; Budiman, Harry; Simanungkalit, Sabar; Rinaldi, Nino
Scientific Contributions Oil and Gas Vol 41, No 1 (2018)
Publisher : Scientific Contributions Oil and Gas

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29017/SCOG.41.1.73

Abstract

Biomass gasification has been widely known method to produce syn-gases, which can be considered as great alternative substitution for fossil fuels. However, accurate verification of the syn-gas composition requires a reliable and validated method for simultaneous measurement of H2, CO2, CH4, and CO. In order to fulfill the aforementioned requirements, which is the objective of this study; a GC-TCD method for simultaneous measurement of H2, CO2, CH4, and CO component in syn-gas has been validated in accordance to ISO/IEC 17025 and its application for real samples. For the method validation purpose, all of the performance parameters were evaluated and discussed in detail in this study. Intraday precision and interday precision were found to be acceptable having the %RSD below 0.67xCV Horwitz and below 1.0xCV Horwitz, respectively. The bias value falls within +2σ for entire components, indicating that the method accuracy can be accepted. Coefficient correlation for all components was higher than 0.99, which means that the method has suffi cient linearity. LoD and LoQ for each component were found to be lower than typical syn-gas concentration range. The method roughness was also found in an acceptable level (the p-values was higher than 0.05 for allctarget components. Application of the validated method for the measurement of a real syn-gas samples indicated that the method is quite reliable to produce an accurate data and the validated methid can be used in a routine analysis. The innovation of this study, as shown by experiment results, is to evaluate the validated method’s performance for simultaneous determination of syn-gas components’ concentration in one channel, compared to common method in which the syn-gas components were measured separatedly in a different channel.Biomass gasifi cation has been widely known method to produce syn-gases, which can be consideredas great alternative substitution for fossil fuels. However, accurate verifi cation of the syn-gas compositionrequires a reliable and validated method for simultaneous measurement of H2, CO2, CH4, and CO. Inorder to fulfi ll the aforementioned requirements, which is the objective of this study; a GC-TCD methodfor simultaneous measurement of H2, CO2, CH4, and CO component in syn-gas has been validated inaccordance to ISO/IEC 17025 and its application for real samples. For the method validation purpose,all of the performance parameters were evaluated and discussed in detail in this study. Intraday precisionand interday precision were found to be acceptable having the %RSD below 0.67xCV Horwitz and below1.0xCV Horwitz, respectively. The bias value falls within +2σ for entire components, indicating that themethod accuracy can be accepted. Coeffi cient correlation for all components was higher than 0.99, whichmeans that the method has suffi cient linearity. LoD and LoQ for each component were found to be lowerthan typical syn-gas concentration range. The method roughness was also found in an acceptable level(the p-values was higher than 0.05 for allctarget components. Application of the validated method for themeasurement of a real syn-gas samples indicated that the method is quite reliable to produce an accuratedata and the validated methid can be used in a routine analysis. The innovation of this study, as shown byexperiment results, is to evaluate the validated method’s performance for simultaneous determination ofsyn-gas components’ concentration in one channel, compared to common method in which the syn-gascomponents were measured separatedly in a different channel.Keywords: syn-gas, GC-TCD, method validation.
CONVERSION OF CO2 TO HYDROCARBON SYNFUEL BY UTILIZING NUCLEAR HYDROGEN COGENERATION Salimy, Djati H
Scientific Contributions Oil and Gas Vol 41, No 1 (2018)
Publisher : Scientific Contributions Oil and Gas

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29017/SCOG.41.1.79

Abstract

A study of the utilization of hydrogen cogeneration with nuclear energy as a technology for the conversion of CO2 into synthetic liquid hydrocarbon fuels has been carried out. The aim of the study is to understand the conversion of CO2 and H2 into synthetic fuels, as well as the role of nuclear hydrogen cogeneration for the production of hydrogen and as a source of process heat energy. The method used is literature study based on the results of existing research. Conventionally, synthetic fuel production from coal is produced through coal gasification process, followed by reacting synthesis gas (mixture of CO and H2) in FT reactor to synthesis fuel. In this study, we studied the production of synthetic fuels with CO2 and H2 raw materials. CO2 comes from emissions of coal-fired plants, whereas H2 is produced by nuclear hydrogen cogeneration systems. The results show that compared to conventional processes, CO2 and H2-based processes supported by coal cogeneration systems provide significant advantages in terms of CO2 emissions. The process based on coal gasification and nuclear cogeneration, capable of reducing emissions by up to 75% and saving up to 40% of coal consumption. While the process based only on CO2 and nuclear hydrogen cogeneration (without coal gasification), teoretically can operate witout any CO2 emission at all. Even this process can captured and utilize CO2 emissions from coal fired plant, and use it as a raw material for the process
A CUSTOMIZED QUASI THREE-PHASE DRAINAGE RELATIVE PERMEABILITY MODEL FOR SOME INDONESIAN WATER-WET SANDSTONES Widarsono, M.Sc., Prof. Dr. Ir. Bambang
Scientific Contributions Oil and Gas Vol 41, No 1 (2018)
Publisher : Scientific Contributions Oil and Gas

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29017/SCOG.41.1.61

Abstract

Information about drainage effective two-phase – i.e. quasi three-phase – relative permeability characteristics of reservoir rocks is regarded as very important in hydrocarbon reservoir modeling. The data governs various processes in reservoir such as gas cap expansion, solution gas expansion, and immiscible gas drive in enhanced oil recovery (EOR). The processes are mechanisms in reservoir that in the end determines reserves and resevoir production performance. Nevertheless, the required information is often unavailable for various reasons. This study attempts to provide solution through customizing an existing drainage relative permeability model enabling it to work for Indonesian reservoir rocks. The standard and simple Corey et al. relative permeability model is used to model 32 water-wet sandstones taken from 5 oil wells. The sandstones represent three groups of conglomeratic sandstones, micaceous-argillaceous sandstones, and hard sandstones. Special correlations of permeability – irreducible water saturation and permeability ratio – irreducible water saturation have also been established. Model applications on the 32 sandstones have yielded specific pore size distribution index (λ) and wetting phase saturation parameter (Sm) values for the three sandstone groups, and established a practical procedure for generating drainage quasi three-phase relative permeability curves in absence of laboratory direct measurement data. Other findings such as relations between λ and permeability and influence of sample size in the modeling are also made.
DRY CLIMATE EXPANSION ON THE PLEISTOCENE OF INDONESIA AS RECORDED IN ITS POLLEN ASSEMBLAGE Lelono, Eko Budi
Scientific Contributions Oil and Gas Vol 41, No 1 (2018)
Publisher : Scientific Contributions Oil and Gas

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29017/SCOG.41.1.69

Abstract

Most researchers agree that Pleistocene is characterised by glacial and inter glacial periods which are strongly related to dry/ cool and wet/ warm climates. Apparently these are refl ected on their pollen records. The period of dry climate (glacial climate) is characterised by abundant Gramineae pollen, whilst the period of wetter climate (interglacial climate) is indicated by an increase of coastal and mangrove palynomorphs, but greatly reduced frequencies of Gramineae pollen. On the contrary, previous works on the Pleistocene sediments of Java indicated high abundance of grass pollen along this age marking drier climate condition. This paper publishes the study which is intended to evaluate paleoclimate of Java and other area of Indonesia during Pleistocene. For this purpose, some well samples from East Java and Papua were collected. Standar laboratory preparation was employed to extract pollen from the cutting samples. This study applies quantitative method which allows detail climate change interpretation. This study shows that Pleistocene of East Java is characterised by abundant grass pollen of Monoporites annulatus which may correspond to the period of expansion of savanna vegetation coinciding with glacial period. More over, it is indicated by abundant charred Gramineae cuticles which derive from burning grass. This might have been caused by extreme heat which could relate to the volcanic activities existed in East Java. Slightly different record appears in Papua which shows repetition of dry/ wet condition or low/ high sea level. The moist climate related to the phase of sea level rise is marked by abundant brackish pollen which possibly represented interglacial period. It is also supported by the increase of peat swamp and freshwater palynomorphs. On the other hand, dry climate representing glacial period is defined by significant decrease of these brackish and freshwater elements.
ASP INJECTIVITY ANALYSIS AS PREPARATION FOR FIELD IMPLEMENTATION Sugihardjo, Sugihardjo
Scientific Contributions Oil and Gas Vol 41, No 1 (2018)
Publisher : Scientific Contributions Oil and Gas

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.29017/SCOG.41.1.70

Abstract

This laboratory experiment is a highlight of the preparation of ASP (Alkaline-Surfactant-Polymer Mixture) chemical injection for field implementation to determine the injectivity parameter and the effect of fluid properties change during flow into the porous media. Therefore, the experiments were focus on injectivity which is represented by permeability change. Besides, IFT and viscosity reduction, and also adsorption of injected chemical on the surface of pore throat were also investigated. ASP chemical solution has been prepared for experiments, the mixture consists of 0.3% of Surfactant-A, 1000 ppm Polymer KP and 0.2% alkaline of NaOH. This mixture has been evaluated the bulk properties for instance: IFT, viscosity and other parameter such as: compatibility, thermal stability, phase behavior, and filtration that are suitable for enhanced oil recovery for the target oil field. The next step is to examine the interaction between rock and injected fluid that may change the fluid and rock properties. ASP injection in carbonate rock in this experiment may result in permeability damage and almost totally block the pore throat. Reduction of permeability is very significantly approaching the value of PRF of level 88.76%. The damage could not be revocable after post flush of water that is indicated that the permeability reduction is permanent. Fluid properties of the ASP including IFT and viscosity show that the IFT looks constant and no signifycant change, on the hand the viscosity of the fluid drops down to almost 32.6% from the original. However, the adsorptions are still categorized as normal.

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