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Desi Nurandini
Department of Chemical Engineering, Faculty of Engineering, Lambung Mangkurat University, South Kalimantan, Indonesia Wetland Based Materials Research Group, Lambung Mangkurat University, South Kalimantan, Indonesia

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KINETIC STUDIES OF Cu ADSORPTION FROM SASIRANGAN LIQUID WASTE USING RICE HUSK ACTIVATED CARBON Isna Syauqiah; Desi Nurandini; Nopi Stiyati Prihatini; Jamiyaturrasidah Jamiyaturrasidah
Konversi Vol 10, No 2 (2021): Oktober 2021
Publisher : Universitas Lambung Mangkurat

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20527/k.v10i2.11660

Abstract

The industry of sasirangan – traditional fabric of Banjar Tribe – has been one of prime commodities of South Kalimantan. The coloring process  in sasirangan production used a lot of chemical elements containing heavy metals  and its waste potentially pollute the environment. One of the heavy metal waste contained is copper (Cu) which is toxic to aquatic organisms and humans. The treatment for sasirangan liquid waste can be done by adsorption process using activated carbon as adsorbent. This study aims to determine the appropriate kinetic model for adsorption of Cu metal from sasirangan liquid waste using activated carbon adsorbent made from rice husks.The process was conducted by batch system with chemical and physical activation. Chemical activation was done by soaking the activated carbon of rice husk with HCl solution for 24 hours. While physical activation was carried out by burning in a furnace at 500̊C for 2 hours. The adsorption treatment was given on sasirangan waste samples with variations on contact time (30, 60 and 120 minutes). The results of kinetics study showed that the adsorption process of Cu from sasirangan liquid waste onto rice husk activated carbon adsorbent followed first-order reaction kinetics with a correlation coefficient value (R2) of 0.96 and adsorption rate constant (k1) of 0.0044 min-1.
CHARACTERISTICS OF EDIBLE FILM (LAYER BY LAYER) FROM CARRAGEENAN-CHITOSAN WITH THE ADDITION OF BELIMBING WULUH LEAF EXTRACT AS ANTIOXIDANT SUBSTANCE Rahmah Isnaeni; Anisa Fitri; Desi Nurandini; Arif Tirtana; Muhmmad Zeva Prayitno
Konversi Vol 11, No 1 (2022): APRIL 2022
Publisher : Universitas Lambung Mangkurat

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20527/k.v11i1.13081

Abstract

Packaging use from synthetic materials can have a negative impact for environment. One of the steps to reduce this impact with edible film packaging uses. Film can be defined as a thin layer of material, that usually composed by a polymer that allows for mechanical strengthening of a structured stand. The quality that continues to be improved from the edible film is antioxidant activity, namely by adding antioxidant substances such as flavonoids and phenols from starfruit leaf extract. As well as improving its mechanical quality by adding shrimp shell chitosan and using the layer by layer method. The purpose of this research is to find out characteristics of edible film from carrageenan-chitosan layer by layer and find the best results from the addition of different concentrations of chitosan and Belimbing Wuluh leaf extract. The variation that will be carried out is the addition of Belimbing Wuluh leaf extract by 0.2%, 0.4% and 0.6% and chitosan by 1.5%, 2% and 2.5%. The results showed that the best formula of edible film was made from 2.5% chitosan concentration and 0.6% Belimbing Wuluh leaf extract. The results of test are the thickness test is 0.21 mm, the tensile strength is 2.87 MPa, the elongation at break is 13.6673%, the water vapor permeability is 2.1682 g/m2h and the antioxidant value in terms of fruit weight loss is 4.01%. 
INVESTIGATION OF THE INFLUENCE OF PARTICLE SIZE OF RICE HUSK ASH AS ADSORBENT FOR MERCURY IN COLUMN ADSORPTION SYSTEM Desi Nurandini; Riani Ayu Lestari; Isna Syauqiah; Ahmad Rizalli; Ryan Rahmatullah
Konversi Vol 10, No 2 (2021): Oktober 2021
Publisher : Universitas Lambung Mangkurat

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20527/k.v10i2.11726

Abstract

The presence of heavy metal mercury (Hg2+) in liquid waste has caused serious problems to environmental pollution. One of the most effective method to reduce the levels of heavy metals mercury (Hg2+) in liquid waste is adsorption. Rice husk ash is highly potential to adsorb heavy metals in water because it is a porous material with a high silica content. Therefore, rice husk ash can be used as an adsorbent for heavy metals in liquid waste. The purpose of this study was to determine the level of mercury (Hg2+) that can be adsorbed from the column adsorption process using adsorbent of rice husk ash and to determine the optimum mass of rice husk ash as an adsorbent. The research was conducted using a series of simple adsorption column tools with a circulation time of 120 minutes. While the independent variables were adsorbent particle size of 50, 100, and 200 mesh. Measurement of mercury (Hg2+) levels was carried out on samples before and after treatment with Atomic Absorption Spectrophotometer (AAS). The results showed a significant decrease in Hg2+ levels with the optimum adsorbent particle size of 200 mesh. The value of the adsorbed Hg2+ ion content reached 101.670 mg/L in the adsorption process using adsorbent with 200 mesh particle size . 
CHARACTERISTICS ANALYSIS OF ADSORBENT FROM RUBBER TREE TRUNK AND RUBBER SEED SHELLS Desi Nurandini; Riani Ayu Lestari; Muhammad Zeva Prayitno; Isna Syauqiah
Konversi Vol 11, No 2 (2022): OKTOBER 2022
Publisher : Universitas Lambung Mangkurat

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20527/k.v11i2.14600

Abstract

The efforts to control heavy metal waste are developingg to obtain an economical, effective, and efficient method. One method that is widely used in industry is adsorption. In general, the use of conventional adsorbents requires relatively more expensive operational and regeneration costs, thus it is necessary to investigate alternative adsorbents derived from nature. Local commodities that can be taken as the basic material for adsorbents are rubber plants. In the rubber seed shell there are fibers containing cellulose, hemicellulose, lignin, and waxes. The rubber tree trunk at the base has a relatively high cellulose content (67.38%), the middle part has a cellulose content of (59.37%) and the end part has a cellulose content of (45.73%). Therefore, this study was conducted to determine the potential of rubber stems and rubber seed shell waste to be processed into adsorbents. The making of the adsorbent is preceded by the delignification stage and then followed by the activation process. Based on the characterization tests that have been carried out, it is known that the moisture content in the biosorbent of the rubber seed and shell is 10% and 11%, while the ash content is 1.23% and 2.33%, respectively. The volatile matter levels for the adsorbents from the stems and shells were 6.43% and 6.18%, respectively.The efforts to control heavy metal waste are developingg to obtain an economical, effective, and efficient method. One method that is widely used in industry is adsorption. In general, the use of conventional adsorbents requires relatively more expensive operational and regeneration costs, thus it is necessary to investigate alternative adsorbents derived from nature. Local commodities that can be taken as the basic material for adsorbents are rubber plants. In the rubber seed shell there are fibers containing cellulose, hemicellulose, lignin, and waxes. The rubber tree trunk at the base has a relatively high cellulose content (67.38%), the middle part has a cellulose content of (59.37%) and the end part has a cellulose content of (45.73%). Therefore, this study was conducted to determine the potential of rubber stems and rubber seed shell waste to be processed into adsorbents. The making of the adsorbent is preceded by the delignification stage and then followed by the activation process. Based on the characterization tests that have been carried out, it is known that the moisture content in the biosorbent of the rubber seed and shell is 10% and 11%, while the ash content is 1.23% and 2.33%, respectively. The volatile matter levels for the adsorbents from the stems and shells were 6.43% and 6.18%, respectively.