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Journal : Infotekmesin

Pengaruh Waktu Karbonisasi Terhadap Kadar Air dan Abu Serta Kemampuan Adsorpsi Arang Tempurung Nipah Teraktivasi Asam Klorida Theresia Evila Purwanti Sri Rahayu; Rosita Dwityaningsih; Ulikaryani
Infotekmesin Vol 13 No 1 (2022): Infotekmesin: Januari, 2022
Publisher : P3M Politeknik Negeri Cilacap

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.35970/infotekmesin.v13i1.1027

Abstract

The Cilacap region, Central Java, Indonesia is a coastal area that is overgrown with nipa palm trees, making it one of the potential local natural resources to be exploited. Utilization of this plant has been carried out for the fields of food, energy, clothing, pharmaceuticals, and furniture, but as an anode material for lithium-ion batteries is still being researched. Studies on lithium-ion batteries in Indonesia in particular have not started long ago so that research in this field is still limited and few in number, but the development of lithium-ion batteries has become one of the national research priorities in the field of new and renewable energy sources as stated in the Indonesian national research master plan (RIRN) for the period 2017 – 2045. This study was conducted to examine the potential feasibility of activated charcoal from nipah shells as anode material for lithium-ion batteries. The feasibility test parameters studied in this study include water content, ash content and adsorption capacity stated as iodine and methylene blue number which are the basic characterizations for activated charcoal referring to SNI 06-3730-1995. The nipah shell carbonization process was carried out in the presence of oxygen at an optimized temperature of 210 oC with a 1 hour time interval variation from 3 to 8 hours, followed by an activation process using a strong acid, namely HCl with a concentration of 2 M. The experimental results showed the average value of moisture content, ash content, iodine, and methylene blue number are 12.5%, respectively; 1.75%; 2515.9161 mg/g; and 97%, all of which are above the quality standard values, so the conclusion from this study is that activated charcoal from nipah shell has basic characteristics that have the potential to be further developed, including as raw material for lithium-ion battery anodes.
Efek Temperatur Pengarangan Cangkang Kerang dan Tulang Sapi Terhadap Proximate Mohammad Nurhilal; Rosita Dwityaningsih; Theresia Evila Purwanti Sri Rahayu; Radhi Ariawan
Infotekmesin Vol 13 No 1 (2022): Infotekmesin: Januari, 2022
Publisher : P3M Politeknik Negeri Cilacap

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.35970/infotekmesin.v13i1.1018

Abstract

Studies on the use of animal waste as charcoal ingredient in the needs of activated charcoal material has been carried out and developed. Activated charcoal is produced through activation process at a certain temperature, condition, and time in order to creat a higher carbon content in charcoal . One of the important factors in the manufacture of activated charcoal is the temperature during the production process. The purpose of this study is to discuss the influence of temperature factor of mussel shells and beef bones on water content, ash content, volatile matter and fixed carbon during the charcoal production process. The research is carried out through experimental method of making chorcoal with temperature variations of 400, 500, 600, 700, and 800 oC. The result of the experiment shows the highest ash content and water content found respectively in beef bone charcoal of 800 oC which is 98,697 %, and of 400 oC which is 4,942 %, while the highest volatile matter and fixed carbon levels are found in clam shell charcoal of 800 oC which is 6,717 %, and of 500 oC which is 43,282 %. The result concluded that the effect of the temperature of the production process affects the water content, ash, volatile matter and fixed carbon.
Pengaruh Variasi Konsentrasi H3PO4 Sebagai Zat Aktivator Terhadap Karakteristik Karbon Aktif dari Sekam Padi Rosita Dwityaningsih; Theresia Evila Purwanti Sri Rahayu; Murni Handayani; Mohammad Nurhilal
Infotekmesin Vol 14 No 1 (2023): Infotekmesin: Januari, 2023
Publisher : P3M Politeknik Negeri Cilacap

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.35970/infotekmesin.v14i1.1641

Abstract

Rice husk is an organic material that has a high lignocellulosic content so it has the potential to be turned into activated carbon. One method of making activated carbon is activation with a phosphoric acid activator (H3PO4). The purpose of this research was to study the effect of varying concentrations of H3PO4 as an activator on the characteristics of rice husk-activated carbon. The characterization refers to SNI 06-3730-1995 regarding the technical quality requirements of activated charcoal. Activation of rice husk carbon was carried out by contacting the carbon with H3PO4 for 24 hours and shaking it. The H3PO4 consisted of 3 concentration variations, namely 4M, 6M, and 8M. From the research results, the water content was 3.936%; 4.037%; 4.070%, the absorption of iodine has met the character of activated charcoal according to SNI, namely 1217.204 mg/g; 1204.255 mg/g; 1184.832 mg/g while the ash content value does not meet the SNI standard, which is still above 10%. The highest adsorption capacity and adsorption efficiency could be activated with 8M H3PO4, namely 22.42 mg/g and 89.68%. IR spectra on activated carbon with three variations of H3PO4 concentration showed the presence of aromatic C-H, C=C, and C-O anhydride functional groups.
Analisis Porositas, Tekstur, dan Morfologi Karbon Tempurung Nipah Hasil Pirolisis Suhu Tinggi Untuk Anoda Baterai Sekunder Theresia Evila Purwanti Sri Rahayu; Mohammad Nurhilal; Rosita Dwityaningsih
Infotekmesin Vol 14 No 1 (2023): Infotekmesin: Januari, 2023
Publisher : P3M Politeknik Negeri Cilacap

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.35970/infotekmesin.v14i1.1666

Abstract

Lithium-ion batteries are the recent main store of electrochemical energy that have been widely used for electronic equipment, electric vehicles, and also renewable energy storage such as wind and solar. Lithium-ion batteries have many electrochemical advantages but lithium availability in nature is reduced very quickly and its distribution is uneven throughout the world. Sodium is attractive as an alternative to lithium insertion for secondary batteries because of its abundant availability and oxidation reduction potential to standard hydrogen electrodes only 0.3 volts higher than lithium. This study aims to synthesize hard carbon from nipah shell biomass using thermal methods of low-temperature pyrolysis (lower than 200 oC) followed by high-temperature pyrolysis (higher than 1000 oC). Characterization is carried out by iodine number analysis to determine porosity and SEM-EDX to determine texture and morphology. The result of the analysis of carbon iodine number is 346.86 mg/g while SEM-EDX analysis showed that carbon has a structure similar to a combination of graphene and nano-tube carbon.
Pengaruh Penambahan Arang Tempurung Kelapa Terhadap Kualitas Briket dari Arang Pelepah Nipah Menggunakan Tepung Tapioka Sebagai Perekat Mohamad Arifin; Rosita Dwityaningsih; Taufan Ratri Harjanto
Infotekmesin Vol 14 No 2 (2023): Infotekmesin: Juli, 2023
Publisher : P3M Politeknik Negeri Cilacap

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.35970/infotekmesin.v14i2.1938

Abstract

Nipa Palm fronds is one of the biomass that has potential to be used as briquettes because it has high cellulose. The calorific value of nypa palm frond will cause low briquettes quality. The aims of this study is to determine the effect of the addition of coconut shell charcoal. The research method used was by mixing coconut shell charcoal with nipa palm charcoal with various compositions and using tapioca flour as an adhesive as much as 10% of the total weight of briquettes. It was found that the addition of coconut shell charcoal can improve the quality of briquettes according to SNI No.1/6235/2000 with the best composition ratio palm charcoal:coconut shell charcoal which is 20%:80%. Briquettes have a moisture content 2,43%, ash content 7,3%, a calorific value 6779,64 Kal/gram, density 1 gram/cm2 and a burning rate of 0,0393 gram/minute.