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Nobuyuki Ichikuni
2Department of Applied Chemistry and Biotechnology, Chiba University, 1-33 Yayoi, Inage, Chiba 263-8522, Japan
Astronomy Chemistry Earth & Planetary Sciences Mathematics Physics

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Ring-Opening of Oxiranes using Taeniolite-Supported Tris(β-Diketonato)Zirconium Yessi Permana; Nobuyuki Ichikuni; Shogo Shimazu
Journal of Mathematical and Fundamental Sciences Vol. 44 No. 3 (2012)
Publisher : Institute for Research and Community Services (LPPM) ITB

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/itbj.sci.2012.44.3.6

Abstract

A series of tris(β-diketonato)zirconium(IV) complexes was immobilized into a synthetic clay structure of Taeniolite by an ion-exchange method to generate organic/inorganic hybrid compounds. The hybrid compound served as a good catalyst for ring-opening reactions of methyl, ethyl, and dimethyl oxiranes with various alcohols to generate primary alkoxy alcohols in appreciable selectivity. This method describes a technique to immobilize cationic zirconium complexes without losing selectivity.
Co-Authors Shogo Shimazu Yessi Permana