Journal of Mathematical and Fundamental Sciences
Vol. 44 No. 3 (2012)

Ring-Opening of Oxiranes using Taeniolite-Supported Tris(β-Diketonato)Zirconium

Yessi Permana (1Inorganic & Physical Chemistry Research Division, Institut Teknologi Bandung, Jl. Ganesha 10, Bandung, Jawa Barat 40132, Indonesia)
Nobuyuki Ichikuni (2Department of Applied Chemistry and Biotechnology, Chiba University, 1-33 Yayoi, Inage, Chiba 263-8522, Japan)
Shogo Shimazu (2Department of Applied Chemistry and Biotechnology, Chiba University, 1-33 Yayoi, Inage, Chiba 263-8522, Japan)

Article Info

Publish Date
07 Aug 2014

Abstract

A series of tris(β-diketonato)zirconium(IV) complexes was immobilized into a synthetic clay structure of Taeniolite by an ion-exchange method to generate organic/inorganic hybrid compounds. The hybrid compound served as a good catalyst for ring-opening reactions of methyl, ethyl, and dimethyl oxiranes with various alcohols to generate primary alkoxy alcohols in appreciable selectivity. This method describes a technique to immobilize cationic zirconium complexes without losing selectivity.

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Journal Info
Journal of Mathematical and Fundamental Sciences
Website

Abbrev

jmfs

Publisher

Institut Teknologi Bandung

Subject

Astronomy Chemistry Earth & Planetary Sciences Mathematics Physics

Description

Journal of Mathematical and Fundamental Sciences welcomes full research articles in the area of Mathematics and Natural Sciences from the following subject areas: Astronomy, Chemistry, Earth Sciences (Geodesy, Geology, Geophysics, Oceanography, Meteorology), Life Sciences (Agriculture, Biochemistry, ...