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Journal : Indonesian Journal of Science and Technology

Experimental Study on The Characterization of Pyrolysis Products from Bagasse (Saccharum Officinarum L.): Bio-oil, Biochar, and Gas Products Siti Jamilatun; Joko Pitoyo; Shinta Amelia; Alfian Ma’arif; Dhias Cahya Hakika; Ilham Mufandi
Indonesian Journal of Science and Technology Vol 7, No 3 (2022): IJOST: VOLUME 7, ISSUE 3, December 2022
Publisher : Universitas Pendidikan Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17509/ijost.v7i3.51566

Abstract

Sugarcane bagasse is one of the most abundant biomasses. This study aims to examine the characteristics of bagasse using a pyrolysis system to produce liquid, solid (Biochar), and gaseous. A fixed bed reactor was installed in pyrolysis with temperature variations from 300 to 600°C. The ultimate and proximate analysis was applied to evaluate the characteristic of bagasse. The experimental result found that the maximum bio-oil was obtained at a temperature of 550°C. Several characterizations were done, including gas chromatography and surface area analysis. The Levoglucosan compound of 78% area. The temperature effect on pyrolysis influenced the O/C ratio, H/C ratio, HHV value, and surface area of biochar. The High Heating Value was obtained from 16.698 to 18.496 kJ/kg. Biochar results indicated that the surface area, average pore size, and total pore volume are 180.3-198.0 m2/g, 1.42-4.33 nm, and 0.11-0.12 nm, respectively. The study also analyzed its composition in biochar.
Multi-Distributed Activation Energy Model for Pyrolysis of Sugarcane Bagasse: Modelling Strategy and Thermodynamic Characterization Siti Jamilatun; Muhammad Aziz; Joko Pitoyo
Indonesian Journal of Science and Technology Vol 8, No 3 (2023): (ONLINE FIRST) IJOST: December 2023
Publisher : Universitas Pendidikan Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.17509/ijost.v8i3.60175

Abstract

The multi-distributed activation energy model (multi-DAEM) is the most effective approach for outlining the kinetics model of biomass pyrolysis. The purpose of this study is to identify the optimal number and shape of the DAEM for sugarcane bagasse pyrolysis and to discuss its thermodynamic characteristics using the combination of multi-DAEM and differential thermal analysis (DTA). The heating rate of 10, 30, and 50 °C/min was employed. The results revealed that the multi-DAEM with five pseudo components and Weibull distribution shape gave the lowest relative root mean of the squared error (RRMSE) of 0.66% and 0.41%, respectively. Kinetic and thermodynamic studies showed that the 1st and 4th pseudo components which represent lignin, have activation energy (E0) of 189.6 and 180.6 kJ/mol, and less endothermic or possibly exothermic properties. Meanwhile, the 2nd, 3rd, and 5th pseudo components which represent cellulose, hemicellulose, and moisture have activation energy (E0) of 176.1, 152.2, and 145.6 kJ/mol, respectively, and endothermic properties.