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All Journal Indonesian Journal of Chemistry
W. M. Z. Wan Yunus
Department of Chemistry, Faculty of Science Universiti Putra Malaysia, 43400 UPM Serdang Selangor
Chemical Engineering, Chemistry & Bioengineering Chemistry

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SEPARATION AND PRECONCENTRATION OF COPPER (II) ION BY FATTY HYDROXAMIC ACIDS IMMOBILIZED ONTO AMBERLITE XAD – 4 RESIN Dedy Suhendra; W. M. Z. Wan Yunus; Md. Jelas Haron; Mahiran Basri; Sidik Silong
Indonesian Journal of Chemistry Vol 6, No 2 (2006)
Publisher : Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (203.904 KB) | DOI: 10.22146/ijc.21754

Abstract

A method of copper (II) ion preconcentration and separation from other ions by using a column containing fatty hydroxamic acids - loaded Amberlite XAD 4 resin (FHA-Amb) is described. Several factors, which affect the separation and preconcentration efficiency such as pH, sample volume, and concentration of eluent and flow rate, have been investigated.  A quantitative recovery of copper (II) ion from FHA-Amb resin column was obtained using 10% HNO3 solutions as eluent with a preconcentration factor of 60. A method for separation of Cu(II) from Zn(II) and Cd(II) is proposed.  A rapid sample throughput, a clean separation, a high preconcentration factor and simplicity are the main advantages in these analytical procedures.
Co-Authors Dedy Suhendra Mahiran Basri Md. Jelas Haron Sidik Silong