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The Influence of NaOH Activator Concentration on the Synthesis of Activated Carbon from Banana Peel for Pb(II) Adsorption Abdul Hamid; Zeni Rahmawati; Mohammad Abdullah; Tri Esti Purbaningtyas; Faizatur Rohmah; Ike Dayi Febriana
EKSAKTA: Berkala Ilmiah Bidang MIPA Vol. 23 No. 03 (2022): Eksakta: Berkala Ilmiah Bidang MIPA (E-ISSN : 2549-7464)
Publisher : Faculty of Mathematics and Natural Sciences (FMIPA), Universitas Negeri Padang, Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1118.799 KB) | DOI: 10.24036/eksakta/vol23-iss03/323

Abstract

Lead has been known as one of the heavy metals with a high adverse effect to the environment and human health. This study reports the activity of activated carbon from biomass of banana peel as an adsorbent to resolve the hazardous lead-contaminated wastewater. The influence of the activator was studied via the alteration of NaOH concentration from 1, 3, and 5 M, where the sample was denoted as AC-1, AC-3, and AC-5. Some techniques, including FTIR, XRD, and SEM were applied to characterize the sample with the highest adsorption capacity. FTIR result affirmed the presence of hydroxyl group on the activated carbon with NaOH 1 M (AC-1) that was beneficial for adsorption. XRD and SEM confirmed that the activated carbon possessed crystalline and amorphous phases with sheet-like morphology. Regarding Pb(II) adsorption, the higher concentration of activator caused the decline of adsorption capacity as the contact time prolonged. The highest adsorption capacity and efficiency were obtained using 1 M NaOH activator with a contact time of 1 hour, which was 3.71 mg/gram and 97.86%, respectively.
Pengaruh Tahap Kristalisasi pada Sintesis ZSM-5 Mesopori dari Kaolin Alam Abdul Hamid; Didik Prasetyo; Tri Esti Purbaningtias; Faizatur Rohmah; Ike Dayi Febriana
Indonesian Journal of Chemical Analysis (IJCA) Vol. 3 No. 2 (2020): Indonesian Journal of Chemical Analysis
Publisher : Universitas Islam Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20885/ijca.vol3.iss2.art1

Abstract

Pemanfaatan Batu Kapur Madura sebagai Katalis dalam Pembuatan Bioedesel dari Minyak Nyamplung Ike Dayi Febriana; Abdul Hamid; Amin Jakfar; Mohammad Abdullah; Faizatur Rohmah; Tri Esti Purbaningtias; Zeni Rahmawati; Septian Dwi Wijaya
Indonesian Journal of Chemical Analysis (IJCA) Vol. 5 No. 1 (2022): Indonesian Journal of Chemical Analysis
Publisher : Universitas Islam Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20885/ijca.vol5.iss1.art2

Abstract

Pemanfaatan batu kapur dari Pamekasan, Madura sebagai katalis heterogen pada reaksi pembuatan biodiesel dipelajari pada penelitian ini.  Batu kapur dikalsinasi pada suhu 900 ºC selama 3 jam untuk membentuk katalis CaO. Katalis CaO yang terbentuk dikarakterisasi menggunakan difraksi sinar-X (XRD), spektroskopi inframerah (FTIR) dan Scanning Electron Microscopy-Energy Dispersive X-Ray Analysis (SEM-EDX). Proses transesterifikasi dari minyak nyamplung dilakukan dengan rasio mol minyak terhadap methanol sebesar 1:16 pada temperatur 60 °C selama 1 jam dengan katalis CaO sebesar 4 % (w/w). Hasil analisis GC-MS diperoleh yield biodiesel sebesar 54% dengan konversi sebesar 49%.
UTILIZATION OF BLACK STICKY RICE FOR BIOETHANOL PRODUCTION AS GASOLINE FUEL BLENDS FOR MOTORCYCLES Abdul Hamid; Misbakhul Fatah; Tegar Hermawan Priambodo; Septian Dwi Wijaya
Jurnal Rekayasa Mesin Vol. 13 No. 2 (2022)
Publisher : Jurusan Teknik Mesin, Fakultas Teknik, Universitas Brawijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21776/jrm.v13i2.1190

Abstract

Despite possessing non-renewable properties, fossil fuel is still widely used as a major energy source. Subsequently, the fossil fuel demand has been increasing while the supply is depleting over time leading to an energy crisis. Fossil fuel also causes associated environmental problems such as emissions as the primary driver of global warming and climate change. Thereby, the development of alternative fuels, such as bioethanol, is beneficial to combat the fossil fuel challenges. Bioethanol is a promising fuel owing to its renewable and environmentally friendly characteristics. In this study, bioethanol was synthesized by a fermentation process over yeast (Saccharomyces Cerevisiae). The feedstock for this process is an abundant resource namely black sticky rice. Bioethanol resulting from this process was mixed with gasoline and applied to a motorcycle machine. The performance of bioethanol was defined by power, torque, and emission. The proportion of the mixture was varied with bioethanol content of 0%, 10 %, 20 %, 30 %, and 40%. The mixture of bioethanol-gasoline produced higher power and torque value compared to gasoline. The E40 mixture had the highest power and torque value with 8.5 hp and 9.2 Nm respectively. However, the combustion of bioethanol-gasoline resulted in more CO2 emission, while the emissions of O2, NO, and NOx were lower. The lowest NOx emissions content was obtained at E30 and E40 blends, about 7 ppm. Meanwhile, the lowest NO emission content was obtained at E30 and E40 blends, about 6 ppm.
Pengembangan Pusat Unggulan Teknologi, Center Of Heavy Equipment Untuk Mempersiapkan Sdm Bidang Mekanik Dan Operator Alat Berat Yang Kompeten Mohammad Anas Fikri; Ike Dayi Febriana; Laily Ulfiyah; Misbakhul Fatah; Lukman Hadiwijaya; Amin Jakfar; Auliana Diah Wilujeng; Annafiyah Annafiyah; Faizatur Rohmah; Abdul Hamid; Ratna Ayu Pawestri K. D; Septian Dwi Wijaya; Nadiyah Ulfah; Dimas Aryo Wicaksono; Ghopal Ahmad Fachrudin; Eddy Harsono
Journal of Applied Mechanical Engineering and Renewable Energy Vol 3 No 1: Februari2023
Publisher : Indonesian Society of Applied Science

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.52158/jamere.v3i1.438

Abstract

The low demand for vocational education graduates has led to high unemployment. The low demand for vocational education graduates has led to high unemployment. Vocational college graduates still need to be commensurate with industrial needs. Many Senior High School, Vocational High School, and Vocational College graduates have not been able to find a job for more than six months. Conditions on Madura island worsened this, and the lack of accelerated industrialization even after the Suramadu Bridge was built. Madura has the lowest Human Development Index (HDI) score in East Java. Data from the Central Bureau of Statistics (BPS) Sampang in Figures 2021) shows that the HDI value in 2020 only increased by 0.76 from 2019 of 62.70. Politeknik Negeri Madura (Poltera) together with PT. United Tractors and LSP ABI want to take an active role in improving Madura's HDI by preparing human resources on heavy equipment mechanics through the development of a centre of excellence for technology (PUT) of Heavy Equipment (CHE). Using the causal-comparative method, the researcher observed the impact of each stage on PUT-CHE development activities and reviewed the data to find causal factors and correlations. Poltera took a strategic step by equipping lecturers with virtual training on heavy equipment mechanics (SOBAT Program), organized by PT United Tractors. The SOBAT program has positively impacted heavy equipment engineering graduates in 2022, which has increased significantly. Academic data showed that 13 out of 34 heavy equipment mechanical engineering graduates were employed in leading heavy equipment industries before three months. Other data stated that three lecturers participating in Virtual Training on heavy equipment mechanics were selected as 50 interns at PT United Tractors.
Transesterification of Waste Cooking Oil using CaO Catalyst Derived from Madura Limestone for Biodiesel Production and Its Application in Diesel Engine Abdul Hamid; Amin Jakfar; Sirly Bifadilatur Romaniyah; Ike Dayi Febriana; Mohammad Abdullah; Zeni Rahmawati; Didik Prasetyoko
Automotive Experiences Vol 6 No 1 (2023)
Publisher : Automotive Laboratory of Universitas Muhammadiyah Magelang in collaboration with Association of Indonesian Vocational Educators (AIVE)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.31603/ae.7879

Abstract

In this study, we report biodiesel production from waste cooking oil using CaO catalyst derived from Madura limestone through a transesterification reaction. Many limestone quarries in Madura can be used as heterogeneous catalysts because they are cheap, easy to separate, and have high basicity. Conversion of limestone into CaO catalyst through calcination at 900°C for 3 hours. The CaO catalyst formed was characterized using X-Ray Diffraction (XRD), Fourier Transform Infra-Red (FTIR), and Scanning Electron Microscopy-Energy Dispersive X-Ray (SEM-EDX) instruments. Biodiesel formed through the transesterification reaction was analyzed using GC-MS. Furthermore, biodiesel blends from waste cooking oil and pure diesel were prepared in volume percentages (B-10, B-20, B-30, B-40, and B-100) for testing on diesel engine performance. The results of testing the highest torque and brake horsepower (BHP) were obtained on pure diesel fuel (S-100) at 2.49 Nm and 381.12 watts, respectively. The lowest fuel consumption at 1500 rpm is produced on the B-20 at 0.186 kg/h. Overall, the emission characteristics of carbon monoxide (CO), nitrogen oxides (NOx), and nitrogen monoxide (NO) with the lowest concentration resulted from biodiesel blends rather than pure diesel.
Effect the Addition of Biodiesel from Nyamplung Oil (Calophyllum Inophyllum) on Performance and Emission Characteristics of Diesel Engines Abdul Hamid; Amin Jakfar; Saiful Saiful; Ike Dayi Febriana; Faizatur Rohmah
Jurnal Teknik Kimia dan Lingkungan Vol. 6 No. 2 (2022): October 2022
Publisher : Politeknik Negeri Malang

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (738.218 KB) | DOI: 10.33795/jtkl.v6i2.336

Abstract

In this study, the use of biodiesel from nyamplung oil (Calophyllum Inophyllum) was studied through a transesterification reaction using a heterogeneous catalyst of CaO from limestone originating from Pamekasan, Madura. The composition ratio used between nyamplung oil and methanol in the transesterification reaction was 1:12 (mol/mol) with the addition of 4% CaO catalyst. The biodiesel that is formed is then tested for its performance and emission characteristics in diesel engines with various fuel mixtures between pure diesel and biodiesel (B-10, B-20, B-30, B-40, B-100 and S-100). The test results for biodiesel blends with the highest power produced from B-10, B-20, B-30 and B-100 fuels were 0.26 kW each at a load of 250 watts. While at a load of 500 watts, the highest power is obtained from the B-40 fuel, which is 0.58 kW. The results of performance testing using S-100 fuel obtained the highest power values ​​of 0.27 and 0.58 kW, respectively, with a load of 250 and 500 watts. Performance testing for biodiesel blends, the highest torque value was obtained when using B-10, B-20, B-30 and B-100 fuels, which were 1.65 N.m each with a load of 250 watts. While at a load of 500 watts, the highest torque is obtained on B-40 fuel, which is 3.69 N.m. The fuel S-100 produces torque of 1.71 and 3.69 N.m, respectively, with a load of 250 and 500 watts. Emission gases characteristics of carbon monoxide (CO), nitrogen monoxide (NO) and nitrogen oxides (NOx) showed the lowest concentrations obtained in B-100 fuel were 387 ppm, 92 ppm and 96 ppm, respectively. Meanwhile, the highest concentrations of CO, NO and NOx emissions were produced from pure diesel fuel (S-100), namely 574 ppm, 126 ppm and 132 ppm, respectively.