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All Journal Bulletin of Chemical Reaction Engineering & Catalysis Bulletin of Chemical Reaction Engineering & Catalysis
Muh. Siddik Ibrahim
Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada
Chemical Engineering, Chemistry & Bioengineering Chemistry

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Nickel Supported Parangtritis Beach Sand (PP) Catalyst for Hydrocracking of Palm and Malapari Oil into Biofuel Muh. Siddik Ibrahim; Wega Trisunaryanti; Triyono Triyono
Bulletin of Chemical Reaction Engineering & Catalysis 2022: BCREC Volume 17 Issue 3 Year 2022 (September 2022)
Publisher : Department of Chemical Engineering - Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.17.3.15668.638-649

Abstract

Nickel supported Parangtritis beach sand (PP) catalyst for hydrocracking of palm and malapari oil into biofuel has been conducted. The impregnation process of Nickel (Ni) metal on PP was carried out through the dry impregnation method (blending) using a precursor salt of NiCl2.6H2O with variations of Ni metal as much as 10 and 15 wt% of PP which produced Ni(A) and Ni(B) catalysts. Each catalyst was tested for activity and selectivity through the hydrocracking process of oil into biofuel using a semi-batch system reactor at a temperature of 450 oC, a hydrogen gas flow rate of 20 mL/minute for 2 hours, and a weight ratio of 1:200 catalyst:feed (w/w). The results showed that the Ni(A)/PP catalyst had the highest activity and selectivity with the yield of liquid products and the total biofuel fraction (biohydrocarbons) obtained from hydrocracking of palm oil of 68.50 and 49.87 wt%, respectively. Ni(A)/PP catalyst has a total acidity, surface area, and crystal size of 0.051 mmol/g, 4.44 m2/g, 25.86 nm, respectively. The reusability test of the Ni(A)/PP catalyst in the hydrocracking process of palm oil into biofuel after the third use resulted in a liquid product and the total biofuel fraction obtained was 64.20 and 41.46 wt%, respectively. The yield of liquid product and the total fraction of biofuel (biohydrocarbon) in hydrocracking malapari oil were 66.10, 47.83 wt%, respectively. Copyright © 2022 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
Nickel Supported Parangtritis Beach Sand (PP) Catalyst for Hydrocracking of Palm and Malapari Oil into Biofuel Muh. Siddik Ibrahim; Wega Trisunaryanti; Triyono Triyono
Bulletin of Chemical Reaction Engineering & Catalysis 2022: BCREC Volume 17 Issue 3 Year 2022 (September 2022)
Publisher : Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.9767/bcrec.17.3.15668.638-649

Abstract

Nickel supported Parangtritis beach sand (PP) catalyst for hydrocracking of palm and malapari oil into biofuel has been conducted. The impregnation process of Nickel (Ni) metal on PP was carried out through the dry impregnation method (blending) using a precursor salt of NiCl2.6H2O with variations of Ni metal as much as 10 and 15 wt% of PP which produced Ni(A) and Ni(B) catalysts. Each catalyst was tested for activity and selectivity through the hydrocracking process of oil into biofuel using a semi-batch system reactor at a temperature of 450 oC, a hydrogen gas flow rate of 20 mL/minute for 2 hours, and a weight ratio of 1:200 catalyst:feed (w/w). The results showed that the Ni(A)/PP catalyst had the highest activity and selectivity with the yield of liquid products and the total biofuel fraction (biohydrocarbons) obtained from hydrocracking of palm oil of 68.50 and 49.87 wt%, respectively. Ni(A)/PP catalyst has a total acidity, surface area, and crystal size of 0.051 mmol/g, 4.44 m2/g, 25.86 nm, respectively. The reusability test of the Ni(A)/PP catalyst in the hydrocracking process of palm oil into biofuel after the third use resulted in a liquid product and the total biofuel fraction obtained was 64.20 and 41.46 wt%, respectively. The yield of liquid product and the total fraction of biofuel (biohydrocarbon) in hydrocracking malapari oil were 66.10, 47.83 wt%, respectively. Copyright © 2022 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). 
Co-Authors Triyono Triyono Wega Trisunaryanti