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The effect of temperature and pyrolysis time of plastic waste in producing methane Holisha Widiyanto; Boima Situmeang; Dina Alva Prastiwi; Ninik Triayu Susparini; Isna Laitusholihah
Jurnal Pendidikan Kimia (JPKIM) Vol 14, No 3 (2022): December
Publisher : Pascasarjana Universitas Negeri Medan

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (233.935 KB) | DOI: 10.24114/jpkim.v14i3.38984

Abstract

Plastic waste is a major environmental problem due to its widespread presence and lack of economic value. Pyrolysis is a process that can decompose plastic waste and produce methane gas, liquid, and solid products. This study aimed to investigate the factors that affect methane gas production and the amount of methane gas produced during the pyrolysis of various plastics, including a black plastic bag and plastic with aluminium foil. The results showed that the aluminium foil plastic produced more methane gas than the black bag, with optimal gas content at 7.74% for the aluminium foil plastic and 3.48% for the black bag. The type of plastic, time, and temperature all significantly affected the yield of methane gas produced. In addition, the interaction between variables in plastic type, time and temperature greatly affects the yield of methane gas (CH4) obtained, because the type of plastic F count (2904) is higher than F table 0.05 (4.00), at temperature F count (5449) is greater than F table 0.05 (2.76), when F count (746) is greater than F table 0.05 (2.76). In conclusion, the snack foil produced more methane gas than the black bag because it was made of low-density polyethylene and contained aluminium ions that catalysed the decomposition of the material, resulting in an increase in the amount of methane gas produced.Keywords: Methane gas; Pyrolysis; Plastic; Waste
Penurunan Logam Fe dan Co Pada Kerang Hijau (Perna viridis) dengan Metode Perendaman Larutan Belimbing Wuluh: Reduction Fe and Co Metals in Green Mussels (Perna viridis) by Soaking in Starfruit Solution Holisha Widiyanto; Hafidz Al Asad; Sriwijayanti; Dian Susvira; Boima Situmeang
KOVALEN: Jurnal Riset Kimia Vol. 9 No. 3 (2023): December Edition
Publisher : Chemistry Department, Mathematics and Natural Science Faculty, Tadulako University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22487/kovalen.2023.v9.i3.16586

Abstract

Green mussels with the Latin name Perna viridis are an animal that lives in the ocean and is a type of shellfish that is widely consumed by the public. Along with time, the emergence of factories that can pollute the oceans can cause contamination of marine life in it, one of the pollutants is the heavy metals of Fe and Co. The accumulation of heavy metals Fe and Co in green mussels can be toxic to people who consume them. This study aims to determine the concentration of heavy metals Fe and Co in green mussels before and after immersion in starfruit solution. Tests for immersion of the starfruit solution were carried out at 15, 30, and 45 minutes, then the destruction results were analyzed using inductively coupled plasma (ICP) with the calibration curve method. The Fe content in the green mussel sample before treatment was 2.946 mg/kg and the Co content in the green mussel sample before treatment was 2.6081 mg/kg. After soaking in starfruit solution for 15, 30, and 45 minutes, the Fe metal was 1.572 mg/kg, 1.275 mg/kg, and 1.035 mg/kg and the Co metal was 1.572 mg/kg, 1.275 mg/kg, and 0.683mg/kg. Research of immersing starfruit solution with soaking for 15, 30, and 45 minutes is effective in reducing levels of heavy metals Fe and Co in green mussels. The highest reduction was observed during a 45-minute immersion, with a decrease of 64.87% for Fe and 73.81% for Co, respectively.