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Nuraini Nuraini
Department of Chemical Engineering, Universitas Ahmad Dahlan, Yogyakarta

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Synthesis of Silica-PEG By Physically Coating With PEG 4000 For Absorption of Ion Nitrate Aster Rahayu; Maryudi Maryudi; Joni Aldilla Fajri; Lee Wah Lim; Nuraini Nuraini
Elkawnie: Journal of Islamic Science and Technology Vol 8, No 2 (2022)
Publisher : Universitas Islam Negeri Ar-Raniry Banda Aceh

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22373/ekw.v8i2.14680

Abstract

Abstract: All production activities will eventually produce waste, especially liquid waste. The nitrate ion (NO3-) is one of the substances in liquid waste that can have a significant impact on water systems and human health. Several methods can be used to treat the nitrate contained in the water, such as adsorption, phytoremediation, and wetland treatment. One of its methods was adsorption. The silica was modified with polymer due to its huge carbon chain. This research was focused on optimizing the ability of silica-based materials using PEG by physically coating them since PEG has a long carbon chain that could be transformed into a helix. In this research, the adsorbent will be prepared from modified silica gel with PEG 4000 by physical coating. Several parameters will be observed, including the effect of coating time, silica-PEG ratio, and PEG concentration. The capacity of silica-PEG to absorb NO3- is being studied. The characterization of functional group content in silica-PEG was carried out by Fourier Transform Infrared (FTIR). The study results show that the coating time was 10 minutes with the ratio of silica to PEG of 1:5, and the concentration of PEG used was 15%, indicating the optimum performance of silica-PEG when used as an absorbent, which achieved 84.44 % nitrate removal. An increase in the absorption capacity of silica-PEG demonstrates the ability of silica-PEG as a porous material. It was compared to silica gel without the PEG coating process, which was 9.09% to 84.44%.Abstrak: Semua kegiatan produksi pada akhirnya akan menghasilkan limbah, terutama limbah cair. Limbah cair biasanya akan bermuara di sungai dan berakhir di laut. Salah satu zat dalam limbah cair adalah ion nitrat (NO3-) yang mana dalam jumlah banyak dapat mengganggu sistem perairan dan kesehatan. Beberapa metode dapat digunakan untuk mengolah nitrat yang terkandung dalam air, seperti adsorpsi. Salah satunya dimodifikasi dengan polimer karena memiliki rantai karbon yang besar. Penelitian ini dikonsentrasikan untuk menyelidiki optimalisasi kemampuan silika dengan PEG dengan pelapisan fisik karena PEG memiliki rantai karbon panjang yang dapat bertransformasi menjadi heliks. Dalam penelitian ini, adsorben akan dibuat dari silika gel termodifikasi dengan PEG 4000 dengan pelapisan fisik. Beberapa parameter yang akan diamati antara lain pengaruh waktu pelapisan, rasio silika-PEG, konsentrasi PEG, dan temperatur pelapisan. Kinerja silika-PEG untuk menyerap NO3- diselidiki. Karakterisasi kandungan gugus fungsi pada silika-PEG dilakukan dengan Fourier Transform InfraRed (FTIR). Hasil penelitian menunjukkan bahwa waktu pelapisan adalah 10 menit dengan perbandingan silika dan PEG 1:5, dan konsentrasi PEG yang digunakan adalah 15%, menunjukkan kinerja silika-PEG yang optimum bila digunakan sebagai penyerap NO3-. Kemampuan silika-PEG sebagai bahan berpori dibuktikan dengan peningkatan kapasitas penyerapan silika-PEG dibandingkan silika gel tanpa proses pelapisan PEG.
Removal of Ion Nitrate and Phosphate Using Cocoa Shell Skin Modified With Functional Polymer Aster Rahayu; Nafira Alfi Zaini Amrillah; Nuraini Nuraini; Veranica Veranica; Siti Jamilatun
Elkawnie: Journal of Islamic Science and Technology Vol 9, No 2 (2023)
Publisher : Universitas Islam Negeri Ar-Raniry Banda Aceh

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22373/ekw.v9i2.18260

Abstract

Abstract: Cocoa is a plant that is widely cultivated in Indonesia, one of which is in the Yogyakarta area. On the outside of the cocoa fruit, it is known as the cocoa shell skin. Cocoa shell skin is an agricultural waste that is a simple, cheap, and environmentally friendly development that is used as an adsorbent for nitrate and phosphate removal. This article discusses the observation of the ability of the cacao shell against ion nitrate and phosphate adsorption and then compares it after being modified with a functional polymer. Modification of the surface of cacao shell skin with 2-[(methacryloyloxy)ethyl]trimethylammonium chloride (META) resulted in an improvement; the percentages of removal of ion nitrate and phosphate were 89.67% and 92%, respectively. In addition, this study compared the characterization of materials resulting from the absorption of Cocoa Shell Skin (CH) and Cocoa Shell Skin Modified META (CH-META) for nitrate and phosphate ions using Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy (SEM). The modification with META could improve the C-N group and N-H groups on the surface of cacao shell skin. Abstrak: Kakao merupakan tanaman yang banyak dibudidayakan di Indonesia salah satunya di daerah Yogyakarta. Bagian luar buah kakao dikenal dengan kulit cangkang kakao. Kulit cangkang kakao merupakan limbah pertanian yang merupakan pengembangan sederhana yang murah dan ramah lingkungan serta digunakan sebagai adsorben penyerap nitrat dan fosfat. Artikel ini membahas tentang observasi kemampuan kulit cangkang kakao terhadap adsorpsi ion nitrat dan fosfat kemudian adanya perbandingan dengan cangkang cacao setelah dilakukan modifikasi dengan polimer fungsional. Modifikasi permukaan kulit cangkang kakao dengan META menghasilkan peningkatan persentase penyerapan ion nitrat dan fosfat masing-masing sebesar 89,67% dan 92%. Selain itu, penelitian ini membandingkan karakterisasi bahan hasil penyerapan Cocoa Shell Skin (CH) dan Cocoa Shell Skin – Modifikasi META (CH-META) untuk ion nitrat dan fosfat menggunakan Fourier-Transform Infrared (FTIR) dan Scanning Electron Microscopy (SEM). Modifikasi dengan META dapat meningkatkan gugus C-N dan gugus N-H pada permukaan kulit cangkang kakao.