Reva Edra Nugraha
Department of Chemical Engineering, Faculty of Engineering, Universitas Pembangunan Nasional “Veteran” Jawa Timur, Surabaya, East Java, 60294, Indonesia

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Preparation of a hollow fiber membrane made of antifouling PVDF/Zeolit using the dip-coating technique Zuhriah Mumtazah; Adinda Yufriza; Husna Wardati; Ditta Kharisma Yolanda Putri; Meta Fitri Rizkiana; Reva Edra Nugraha
Journal of Biobased Chemicals Vol. 3 No. 1 (2023): Journal of Biobased Chemicals
Publisher : Program Studi Teknik Kimia Universitas Jember

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.19184/jobc.v3i1.279

Abstract

The practical technique for membrane modification is dip coating. This study coats a PVDF hollow fiber membrane-based composite with a coating of zeolite. The composite is made of a polyvinylidene fluoride (PVDF) membrane. During water filtering, the separation capabilities and propensities of composite membranes for organic impurities were examined. SEM and Fourier-transform infrared spectroscopy analysis of the findings demonstrated that the Zeolite coating was successfully deposited on the PVDF membrane. The flux recovery ratio increases from 69% to 80% while the relative flux drop decreases from 63% to 50%. A composite PVDF membrane dip-coating of Fe2O3/Zeolite with a GA and H2SO4 ratio of 1:2 is needed to remove about 75% of humic compounds from effluent. The results of this study show that the addition of Fe2O3/Zeolite with a GA and H2SO4 layer can greatly improve the hydrophilicity, selectivity, and anti-organic fouling of the PVDF hollow fiber membrane.
Characterization and Kinetic Study of Methylene Blue Photocatalytic on ZnO/ZSM-5 Hellna Tehubijuluw; Fensia Analda Souhoka; Yuly Kusumawati; Didik Prasetyoko; Riki Subagyo; Reva Edra Nugraha; Aishah Abdul Jalil
Indonesian Journal of Chemical Research Vol 11 No 2 (2023): Edition for September 2023
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598//ijcr.2023.11-hln

Abstract

Photodegradation of organic pollutants depends significantly on the structure of metal oxide-based semiconductor photocatalysts. ZnO/ZSM-5 has shown the potential to significantly improve its photocatalytic efficiency for removing waterborne pollutants. ZnO/ZSM-5 has been reported to be an active catalyst for degrading methylene blue. These methods commonly involve various catalytic reactions, with the Langmuir-Hinshelwood process being used to describe the reaction kinetics. A kinetic study on the photocatalytic degradation of methylene blue using ZnO/ZSM-5 was conducted under UV-LED lamp irradiation. ZnO/ZSM-5 was characterized using XRD, SEM, and N2 adsorption-desorption, and it was prepared via the impregnation method. The interaction between ZnO/ZSM-5 and methylene blue solutions over a period of 30 to 180 minutes was monitored using a UV-Vis spectrophotometer. The photocatalytic degradation of methylene blue followed first-order rate kinetics. The Langmuir-Hinshelwood (L-H) kinetic analysis revealed that the photocatalytic reaction constant (kc) was 4.207 L.mg-1. menit-1, and the Langmuir-Hinshelwood constant (K) was 261.509 L.mg-1.