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Pengaruh Laju Alir Biogas dan Ukuran Partikel Pembentuk Pelet terhadap Penyisihan Karbon Dioksida (CO2) dalam Biogas dengan Proses Adsorpsi - Desorpsi Menggunakan Adsorben Berbasis Zeolit Alam untuk Peningkatan Kualitas Biogas Sidabutar, Rivaldi; Trisakti, Bambang; Irvan
Jurnal Teknik Kimia USU Vol. 12 No. 1 (2023): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jtk.v12i1.10134

Abstract

Adsorption is the process of fluid molecules contacting the surface of a solid material. This study aims to remove carbon dioxide (CO2) gas in biogas using natural zeolite-based adsorbent pellets by adsorption and desorption of CO2 from the adsorbent using air. CO2 removal was carried out to determine the percentage of CO2 removal efficiency with variations in biogas flow rates (100 mL/minute, 300 mL/minute, and 500 mL/minute) and variations in the type of adsorbent pellets (particle size, activation time, calcination time, and dealumination activation treatment). Determination of the percentage of CO2 removal is carried out by flowing the biogas into the column and contacting it with the adsorbent continuously for 30 minutes and the output gas is collected in a gas collector to analyze the remaining CO2 content. The results showed that the best CO2 removal was 97.7% using an adsorbent with a particle size of 140 mesh, 4 hours of calcination, 90 minutes of activation time, and dealumination activation at a flow rate of 100 mL/minute. The breakthrough characteristic curve presents the characteristic “S” profile at constant flow rate (100 mL/minute).
Karakteristik Sifat Fisik Membran Elektrolit Polimer Berbasis Kitosan Larva Black Soldier Fly/Polivinil Alkohol/Poliakrilonitril dengan Penambahan Ammonium Klorida Muhammad Thoriq Al Fath; Dalimunthe, Nisaul Fadilah; Sidabutar, Rivaldi; Michael; Samosir, Rosma Natalia; Thiodorus Marvin Tjandra
Jurnal Teknik Kimia USU Vol. 13 No. 1 (2024): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jtk.v13i1.15595

Abstract

Black soldier fly larvae shells/BSF-based chitosan can be utilized as polymer electrolyte membrane. This research aims to analyze the physical characteristics of BSF chitosan/PVA/PAN/NH4Cl by varying amount of chitosan and ratio of PVA: PAN. Membrane was fabricated using the phase inversion method. Polymer electrolyte with a mixture of 1.20 g of PVA/PAN with ratio variations of 10:90 and 20:80 and chitosan variations of 2.4 g; 2.8 g; and 3.2 g. Chitosan was also FTIR-characterized. Density and wáter absorption of polymer electrolyte with chitosan composition of 2.4 g; 2.8 g; 3.2 g and PVA/PAN ratio of 10:90 were 0.824 g/mL; 1 g/mL and 1.51 g/mL and water absorption 28.571%; 38.333%; and 46.154%, respectively; and at PVA/PAN ratio of 20:80 were 0.734 g/mL; 1.03 g/mL and 1.096 g/mL and water absorption 62.5%; 66.667% dan 100%, respectively. Best physical property was obtained with the incorporation of 2.4 g of chitosan and 10:90 PVA/PAN ratio.
Pengurangan Nilai COD pada Effluent Fermentor Biogas UASB-HCPB dengan Memanfaatkan Mikroalga Chlorella vulgaris Sidabutar, Rivaldi; Trisakti, Bambang; Irvan; Bani, Okta; Nasution, Juan Akmal
Jurnal Teknik Kimia USU Vol. 13 No. 2 (2024): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jtk.v13i2.16161

Abstract

Palm oil mill effluent (POME) is the main waste generated from the palm oil industry. LCPKS has a COD level of 57,000-60,400 mg/L. High levels of COD can harm the environment. LCPKS treatment techniques generally use a combination of anaerobic and aerobic waste treatment methods. The anaerobic process has been conducted using a UASB-HCPB reactor. But, the COD levels of anaerobic results have not reached the quality standards so that further processing is needed. Microalgae have the potential to reduce contaminant levels in wastewater. Chlorella vulgaris microalgae is a microalgae that is widely used in wastewater treatment. This study utilized Chorella vulgaris in reducing the COD levels of the effluent of the UASB-HCPB biogas fermentor with variations in lighting intensity and variations in the ratio of effluent to microalgae. It was found that the lighting intensity of light:dark (24:0) hours provided optimal microalgae growth so as to provide the best COD reduction with a COD reduction efficiency of 87.5%. The ratio of microalgae to effluent of 1000 mL: 500 mL showed the best COD reduction with an efficiency of 93.75%.
Pengaruh Laju Alir Biogas dan Ukuran Partikel Pembentuk Pelet terhadap Penyisihan Karbon Dioksida (CO2) dalam Biogas dengan Proses Adsorpsi - Desorpsi Menggunakan Adsorben Berbasis Zeolit Alam untuk Peningkatan Kualitas Biogas Sidabutar, Rivaldi; Trisakti, Bambang; Irvan
Jurnal Teknik Kimia USU Vol. 12 No. 1 (2023): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jtk.v12i1.10134

Abstract

Adsorption is the process of fluid molecules contacting the surface of a solid material. This study aims to remove carbon dioxide (CO2) gas in biogas using natural zeolite-based adsorbent pellets by adsorption and desorption of CO2 from the adsorbent using air. CO2 removal was carried out to determine the percentage of CO2 removal efficiency with variations in biogas flow rates (100 mL/minute, 300 mL/minute, and 500 mL/minute) and variations in the type of adsorbent pellets (particle size, activation time, calcination time, and dealumination activation treatment). Determination of the percentage of CO2 removal is carried out by flowing the biogas into the column and contacting it with the adsorbent continuously for 30 minutes and the output gas is collected in a gas collector to analyze the remaining CO2 content. The results showed that the best CO2 removal was 97.7% using an adsorbent with a particle size of 140 mesh, 4 hours of calcination, 90 minutes of activation time, and dealumination activation at a flow rate of 100 mL/minute. The breakthrough characteristic curve presents the characteristic “S” profile at constant flow rate (100 mL/minute).
Karakteristik Sifat Fisik Membran Elektrolit Polimer Berbasis Kitosan Larva Black Soldier Fly/Polivinil Alkohol/Poliakrilonitril dengan Penambahan Ammonium Klorida Muhammad Thoriq Al Fath; Dalimunthe, Nisaul Fadilah; Sidabutar, Rivaldi; Michael; Samosir, Rosma Natalia; Thiodorus Marvin Tjandra
Jurnal Teknik Kimia USU Vol. 13 No. 1 (2024): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jtk.v13i1.15595

Abstract

Black soldier fly larvae shells/BSF-based chitosan can be utilized as polymer electrolyte membrane. This research aims to analyze the physical characteristics of BSF chitosan/PVA/PAN/NH4Cl by varying amount of chitosan and ratio of PVA: PAN. Membrane was fabricated using the phase inversion method. Polymer electrolyte with a mixture of 1.20 g of PVA/PAN with ratio variations of 10:90 and 20:80 and chitosan variations of 2.4 g; 2.8 g; and 3.2 g. Chitosan was also FTIR-characterized. Density and wáter absorption of polymer electrolyte with chitosan composition of 2.4 g; 2.8 g; 3.2 g and PVA/PAN ratio of 10:90 were 0.824 g/mL; 1 g/mL and 1.51 g/mL and water absorption 28.571%; 38.333%; and 46.154%, respectively; and at PVA/PAN ratio of 20:80 were 0.734 g/mL; 1.03 g/mL and 1.096 g/mL and water absorption 62.5%; 66.667% dan 100%, respectively. Best physical property was obtained with the incorporation of 2.4 g of chitosan and 10:90 PVA/PAN ratio.
Pengurangan Nilai COD pada Effluent Fermentor Biogas UASB-HCPB dengan Memanfaatkan Mikroalga Chlorella vulgaris Sidabutar, Rivaldi; Trisakti, Bambang; Irvan; Bani, Okta; Nasution, Juan Akmal
Jurnal Teknik Kimia USU Vol. 13 No. 2 (2024): Jurnal Teknik Kimia USU
Publisher : Talenta Publisher (Universitas Sumatera Utara)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.32734/jtk.v13i2.16161

Abstract

Palm oil mill effluent (POME) is the main waste generated from the palm oil industry. LCPKS has a COD level of 57,000-60,400 mg/L. High levels of COD can harm the environment. LCPKS treatment techniques generally use a combination of anaerobic and aerobic waste treatment methods. The anaerobic process has been conducted using a UASB-HCPB reactor. But, the COD levels of anaerobic results have not reached the quality standards so that further processing is needed. Microalgae have the potential to reduce contaminant levels in wastewater. Chlorella vulgaris microalgae is a microalgae that is widely used in wastewater treatment. This study utilized Chorella vulgaris in reducing the COD levels of the effluent of the UASB-HCPB biogas fermentor with variations in lighting intensity and variations in the ratio of effluent to microalgae. It was found that the lighting intensity of light:dark (24:0) hours provided optimal microalgae growth so as to provide the best COD reduction with a COD reduction efficiency of 87.5%. The ratio of microalgae to effluent of 1000 mL: 500 mL showed the best COD reduction with an efficiency of 93.75%.