Logic : Jurnal Rancang Bangun dan Teknologi
Vol 19 No 2 (2019): July

Modification of CaO Catalyst with Impregnation Method Using KoH in Biodiesel Synthesis from Waste Cooking Oil

Syarifuddin Oko (Politeknik Negeri Samarinda)
Andri Kurniawan (Politeknik Negeri Samarinda)



Article Info

Publish Date
29 Jul 2019

Abstract

Chicken eggshells can be used as raw material in the manufacture of CaO catalysts. Increased CaO catalyst activity can be done by the impregnation method. The purpose of this study was to determine the effect of %K on the wet impregnation of CaO catalyst using KOH and to find out the impregnation catalyst (CaO / K2O) on the biodiesel yield. Prepared chicken egg shells were calcined at 900oC for 3 hours. Then the CaO obtained was impregnated using KOH with a variation of % K (5%, 7%, 9% and 12% (w / w)) while heated at 85oC. The impregnation product was calcined at 600oC for 5 hours. The impregnation catalyst (CaO K2O) was applied to the biodiesel synthesis through a transesterification reaction with a mole ratio of 1:12 waste cooking oil: methanol, the amount of catalyst was 1.5% at a reaction temperature of 70°C for 2.5 hours. Based on the results of SEM-EDS analysis, the highest K2O at 7% K was 21.99%), while the highest CaO content was at 9% K by 81.53%. For the highest surface area analysis at 7% K with a surface area of 71.22 m2 / g, alkalinity was 2.59 mmol / g. The best biodiesel was obtained with a yield of 87.17%, kinematic viscosity of 2.89 cSt, water content of 0.032%, density of 0.819 g/ml, methyl ester level of 99.39%.

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Journal Info

Abbrev

LOGIC

Publisher

Subject

Computer Science & IT Education

Description

Logic : Jurnal Rancang Bangun dan Teknologi is a peer-reviewed research journal aiming at promoting and publishing original high quality research in all disciplines of engineering and applied technology. All research articles submitted to Logic should be original in nature, never previously ...