Indonesian Journal of Pure and Applied Chemistry
Vol 2, No 3 (2019)

KARAKTERISASI SENYAWA FENOLIK DARI BIJI BUAH RAMBUTAN (Nephelium lappaceum L.)

Eka Pebri Malinda (Program Studi Kimia, Fakultas MIPA, Universitas Tanjungpura)
Rudiyansyah Rudiyansyah (Program Studi Kimia, Fakultas MIPA, Universitas Tanjungpura)
Ajuk Sapar (Program Studi Kimia, Fakultas MIPA, Universitas Tanjungpura)



Article Info

Publish Date
10 Oct 2019

Abstract

Rambutan seeds are one of the waste produced from rambutan that is potential to be used in the food and pharmaceutical fields because it is rich in nutrients and secondary metabolites. This research was carried out to characterize phenolic compounds from the ethyl acetate fraction by using chromatographic methods, phytochemical tests, and 1H-NMR analysis. The isolate was obtained as white powder with 6.2 mg and gave positive sign for phenolic by phytochemical test. 1H-NMR spectrum data (CD3OD, 500 MHz) showed the chemical shift characteristic of coumarin compounds at δH (ppm): 7.82 (1H, d, J= 8.3 Hz), 7.39 (1H, d, J= 7.55 Hz), 6.73 (1H, d, J= 8.05 Hz), and 5.61 (1H, d, J= 7.55 Hz), an anomeric proton at δH 4.8-5 ppm, the characteristics of the methyl group of L-rhamnose sugar at δH 1.29 ppm and other sugar protons at δH 3-4 ppm. Based on the 1H-NMR analysis and comparison with literature, a phenolic compound obtained from rambutan (Nephelium lappaceum L.) seeds is                            7-O-β-L-rhamnose-8-hydroxycoumarin or 8-O-β-L-rhamnose-7-hydroxycoumarin.

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Journal Info

Abbrev

IJoPAC

Publisher

Subject

Biochemistry, Genetics & Molecular Biology Chemistry

Description

Indonesian Journal of Pure and Applied Chemistry (IJoPAC) was first established in 2018 as a scientific journal that accommodates researchers and education practitioners to publish scientific work and research results which are the results of experiments or literature studies in the field of ...