Molekul: Jurnal Ilmiah Kimia
Vol 16, No 1 (2021)

The Influence of ZnCl2 Activation on Macronutrient NPK Adsorption Simultaneously Using Coconut Shell Biochar for Soil Fertility Improvement

Candra Purnawan (Department of Chemistry Mathematics and Natural Sciences Sebelas Maret University (UNS), Surakarta, Central Java, Indonesia)
Christina Candra Dewi (Department of Chemistry Mathematics and Natural Sciences Sebelas Maret University (UNS), Surakarta, Central Java, Indonesia)
Syafrudin syafrudin (Department of Environmental Engineering, Faculty of Engineering, Diponegoro University (UNDIP), Semarang, Central Java, Indonesia)
Bimastyaji Surya Ramadan (Department of Environmental Engineering, Faculty of Engineering, Diponegoro University (UNDIP), Semarang, Central Java, Indonesia)
Mochamad Arief Budihardjo (Department of Environmental Engineering, Faculty of Engineering, Diponegoro University (UNDIP), Semarang, Central Java, Indonesia)
Agus Jatnika Effendi (Department of Environmental Engineering, Faculty of Engineering, Bandung Institute of Technology, Bandung, West Java, Indonesia)
Syarif Hidayat (Department of Environmental Engineering, Faculty of Engineering, Bandung Institute of Technology, Bandung, West Java, Indonesia)



Article Info

Publish Date
28 Mar 2021

Abstract

The influence of ZnCl2 activation on macronutrient Nitrogen, Phosphor, Potassium (NPK) adsorption simultaneously using Coconut Shell Biochar for soil fertility improvement has been conducted. Biochar formation is carried out at temperature up to 500 oC using variation in the concentration of ZnCl2 0,5; 1,0; 1,5; 2,0; dan 2,5 M. The biochar formed was characterized using Fourier Transform InfraRed (FTIR) spectroscopy and Surface Area Analyzer (SAA). Whereas NPK analysis has used the Indonesian standard method (SNI 7763: 2018). Based on this research, it was concluded that the greater the concentration of ZnCl2 activator, indicated that the higher intensity of the spectra of –OH and –NH2 at wave number 3400 cm-1 and 1600 cm-1. It showed that biochar activation was higher and a more active functional group was opened. Increasing the concentration of ZnCl2 activator has increased Biochar adsorption of NPK macronutrients. The optimum condition for activation of coconut shell Biochar was activation with ZnCl2 2.5 M. The addition of activated Biochar was increased soil adsorption on NPK macronutrients. Biochar addition had increased Nitrogen (N) adsorption up to 23.53%, Phosphor (P) up to 200%, and Potassium (K) up to 41.24%.

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Journal Info

Abbrev

jm

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

MOLEKUL is a peer-reviewed journal of chemistry published by the Department of Chemistry, Faculty of Mathematics and Natural Sciences, Jenderal Soedirman University, Indonesia. Publishing frequency 2 issues per year, on May and November. This Journal encompasses all branches of chemistry and its ...