Indonesian Journal of Chemistry
Vol 21, No 4 (2021)

The Origin, Physicochemical Properties, and Removal Technology of Metallic Porphyrins from Crude Oils

Jumina Jumina (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Yehezkiel Steven Kurniawan (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia Ma Chung Research Center for Photosynthetic Pigments, Universitas Ma Chung, Malang 65151, Indonesia)
Dwi Siswanta (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Bambang Purwono (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Abdul Karim Zulkarnain (Department of Pharmaceutical Technology, Faculty of Pharmacy, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Agustinus Winarno (Department of Mechanical Engineering, Vocational College, Universitas Gadjah Mada, Sekip Utara, Yogyakarta 55281, Indonesia)
Joko Waluyo (Department of Mechanical and Industrial Engineering, Faculty of Engineering, Universitas Gadjah Mada, Jl. Grafika No. 2 UGM Campus, Yogyakarta 55281, Indonesia)
Johan Syafri Mahathir Ahmad (Department of Civil and Environmental Engineering, Faculty of Engineering, Universitas Gadjah Mada, Jl. Grafika No. 2 UGM Campus, Yogyakarta 55281, Indonesia)



Article Info

Publish Date
07 May 2021

Abstract

Crude oil is an indispensable energy feedstock for daily activities, although some amounts of metallic porphyrins components with undesired characteristics have been identified. These constituents are assumed to originate from the geochemical process of chlorophyll and heme derivatives. In addition, their chemical structures have been thoroughly characterized using spectroscopy techniques, while several analytical methods were adopted in the detection and concentration quantification in the crude oils. The metallic porphyrins have several demerits, including the deactivation of used catalysts, contamination of the treated petrochemical products, and corrosion of the industrial equipment. Also, the removal process is considered challenging due to the strong interaction with the asphaltene fraction of crude oil. This review article, therefore, provides brief information on the origin, physicochemical properties, and possible removal technology of metallic porphyrins from crude oil samples. Besides, a better understanding of chemistry contributes a useful insight towards the development and establishment of better futuristic processing technology.

Copyrights © 2021






Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...