Indonesian Journal of Chemistry
Vol 21, No 4 (2021)

Optimization of Polyurethane Membrane Physical Characteristics of Red Seaweed Biomass Using a Box-Behnken Design

Salfauqi Nurman (Graduate School of Mathematics and Applied Sciences, Syiah Kuala University, Banda Aceh 23111, Indonesia Department of Agricultural Industrial Engineering, Faculty of Agricultural Technology, Universitas Serambi Mekkah, Banda Aceh 23245, Indonesia Ma)
Saiful Saiful (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia)
Binawati Ginting (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia)
Rahmi Rahmi (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia)
Marlina Marlina (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia)



Article Info

Publish Date
17 May 2021

Abstract

The polyurethane membrane is used as a separator either by filtration or adsorption, and this process is significantly affected by its strength and physical condition. We synthesized polyurethane membranes using red seaweed with Gracilaria sp as a hydroxyl source. The Box-Behnken Design of the Response Surface Methodology (RSM) using Software Design Expert Version 10.0.3.0 with three factors (TRL, TDI, and Glycerin). The F-value of 0.42 suggests that the membrane is less fit, while the P-value of 75.10% indicates that the quadratic design model is suitable for data analysis of physical characteristics. The optimal physical characteristics were obtained at a composition of 0.233 g TRL, 2.675 g TDI, and 0.254 g glycerin with a physical point of 6.5 (strong and elastic). Optimal polyurethane membrane has good thermal and mechanical properties at temperatures of Tg 58 °C, Tm 322 °C, and Td 534 °C, as well as stress and nominal strain values of 69.3 MPa and 5.74%. Polyurethane membrane synthesized from red seaweed has good physical properties. The result of this research is the basis for the development of polyurethane membrane applications from red seaweed.

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Journal Info

Abbrev

ijc

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Indonesian Journal of Chemistry is an International, peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry including applied chemistry. The journal is accredited by The Ministry of Research, Technology ...