Reaktor
Volume 21 No.4 December 2021

Valorisation of Shrimp Waste into Chitosan/Montmorillonite-Sulfosuccinic Acid Composite Membrane for DMFC Application

Shalahudin Nur Ayyubi (Universitas Diponegoro)
Lukman Atmaja (Institut Teknologi Sepuluh Nopember)
Aprilina Purbasari (Universitas Diponegoro)



Article Info

Publish Date
24 Feb 2022

Abstract

Composite membranes have been synthesized from biopolymer chitosan (CS) and nanosized montmorillonite (MMT) filler crosslinked with sulfosuccinic acid (SSA) as an alternative membrane electrolyte for direct methanol fuel cell (DMFC) application. All prepared membranes were obtained by solution casting technique. Prepared membranes were systematically characterized in terms of water uptake, methanol uptake, and methanol permeability as membrane performance parameter for DMFC applications. Fourier transform infrared spectroscopy was used to confirm the structures of the CS/MMT-SSA composite electrolyte membranes. The addition of sulfosuccinic acid evidently decreased the value of methanol permeability with the lowest value of 2.9973 × 10-7 cm2/s was obtained from CS/MMT-SSA 16% membrane. The addition of sulfosuccinic acid also decreased the absorption of methanol with the lowest value of 45.9459% while the water absorption of 53.6424% occurred in the membrane with the addition of 16% sulfosuccinic acid. As a result, the CS/MMT-SSA composite membrane appears to be a potential candidate for the DMFC applications.Keywords: direct methanol fuel cell; proton exchange membrane; methanol permeability; chitosan

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Journal Info

Abbrev

reaktor

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Control & Systems Engineering Energy Materials Science & Nanotechnology

Description

Reaktor invites contributions of original and novel fundamental research. Reaktor publishes scientific study/ research papers, industrial problem solving related to Chemical Engineering field as well as review papers. The journal presents paper dealing with the topic related to Chemical Engineering ...