Bulletin of Chemical Reaction Engineering & Catalysis
2019: BCREC Volume 14 Issue 1 Year 2019 (April 2019)

Kinetic of Adsorption Process of Sulfonated Carbon-derived from Eichhornia crassipes in the Adsorption of Methylene Blue Dye from Aqueous Solution

Mukhamad Nurhadi (Department of Chemical Education, Universitas Mulawarman, Kampus Gunung Kelua, Samarinda, 75123, East Kalimantan)
Iis Intan Widiyowati (Department of Chemical Education, Universitas Mulawarman, Kampus Gunung Kelua, Samarinda, 75123, East Kalimantan)
Wirhanuddin Wirhanuddin (Department of Chemical Education, Universitas Mulawarman, Kampus Gunung Kelua, Samarinda, 75123, East Kalimantan)
Sheela Chandren (Department of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, 81310 Johor Bahru, Johor|Malaysia Centre for Sustainable Nanomaterials, Ibnu Sina Institute for Scientific and Industrial Research, Universiti Teknologi Malaysia, 81310 Johor)



Article Info

Publish Date
15 Apr 2019

Abstract

The evaluation of kinetic adsorption process of sulfonated carbon-derived from Eichhornia crassipes in the adsorption of methylene blue dye from aqueous solution has been carried out. The sulfonated carbon-derived from E. crassipes (EGS-600) was prepared by carbonation of E. crassipes powder at 600 °C for 1 h, followed by sulfonation with concentrated sulfuric acid for 3 h. The physical properties of the adsorbents were characterized by using Fourier transform infrared spectroscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), and nitrogen adsorption-desorption studies. Adsorption study using methylene blue dye was carried out by varying the contact time and initial dye concentration for investigated kinetics adsorption models. The effect of varying temperature was used to determine the thermodynamic parameter value of ΔG, ΔH, and ΔS. The results showed that the equilibrium adsorption capacity was 98% when EGS-600 is used as an adsorbent. The methylene blue dye adsorption onto adsorbent takes place spontaneity and follows a pseudo-second-order adsorption kinetic model. 

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Journal Info

Abbrev

bcrec

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis, a reputable international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics, and chemical reaction engineering. Scientific articles dealing with the following topics in ...