Bulletin of Chemical Reaction Engineering & Catalysis
2018: BCREC Volume 13 Issue 1 Year 2018 (April 2018)

Effect of Drying Conditions on the Catalytic Performance, Structure, and Reaction Rates over the Fe-Co-Mn/MgO Catalyst for Production of Light Olefins

Majid Abdouss (Department of Chemistry, Amirkabir University of Technology, Hafez Ave, Tehran)
Maryam Arsalanfar (Department of Chemistry, Amirkabir University of Technology, Hafez Ave, Tehran)
Nima Mirzaei (Department of Chemical and Petroleum Engineering, Sharif University of Technology, Azadi Avenue, P.O. Box 11365-9465, Tehran)
Yahya Zamani (Research Institute of Petroleum Industry of the National Iranian Oil Company, Gas Research Division, P.O. Box 18745-4163, Tehran)



Article Info

Publish Date
02 Apr 2018

Abstract

The MgO-supported Fe-Co-Mn catalysts, prepared using co-precipitation procedure, were tested for production of light olefins via CO hydrogenation reaction. The effect of a range of drying conditions including drying temperature and drying time on the structure and catalytic performance of Fe-Co-Mn/MgO catalyst for Fischer-Tropsch synthesis was investigated in a fixed bed micro-reactor under the same operational conditions of T = 350 °C, P = 1 bar, H2/CO = 2/1, and GHSV = 4500 h-1. It was found that the catalyst dried at 120 °C for 16 h has shown the best catalytic performance for CO hydrogenation. Furthermore, the effect of drying conditions on different surface reaction rates was also investigated and it was found that the precursors drying conditions influenced the rates of different surface reactions. Characterization of catalyst precursors and calcined samples (fresh and used) was carried out using powder X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), Brunauer-Emmett-Teller (BET) measurements, Temperature Programmed Reduction (TPR), Thermal Gravimetric Analysis (TGA), and Differential Scanning Calorimetry (DSC). Characterization results showed that different investigated variables (drying conditions) influenced the structure, morphology and catalytic performance of the ternary catalysts. 

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Journal Info

Abbrev

bcrec

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis, a reputable international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics, and chemical reaction engineering. Scientific articles dealing with the following topics in ...