Bulletin of Chemical Reaction Engineering & Catalysis
2024: BCREC Volume 19 Issue 1 Year 2024 (April 2024)

Synthesis of Metal-Organic Framework (MOF) Cr-PTC-HIna for Heavy Metal Ion Adsorption

Nurhasni Nurhasni (Department of Chemistry, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412)
Adawiah Adawiah (Integrated Laboratory Centre, Faculty of Science and Technology UIN Syarif Hidayatullah Jakarta)
Wahyudin Wahyudin (Research Center for Advanced Materials, National Research and Innovation Agency, KST BJ Habibie, South Tangerang 15314, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412)
Rizka Hadriyani (Department of Chemistry, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412)
Leni Andriyani (Department of Chemistry, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412)
Rizkha Fadhilla (Department of Chemistry, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412)
Agustino Zulys (Department of Chemistry, Faculty of Mathematics and Natural Sciences, University of Indonesia, Jl. Lingkar Kampus Raya, Pondok Cina, Beji, Depok, Jawa Barat 16424)
Dede Sukandar (Department of Chemistry, Faculty of Science and Technology, UIN Syarif Hidayatullah Jakarta, Jl. Ir. H. Juanda No. 95 Ciputat Tangerang Selatan 15412)

Article Info

Publish Date
30 Apr 2024

Abstract

As an adsorbent material, Metal-Organic Framework (MOF) provides several advantages, such as large surface area and pore volume, as well as stability in aqueous systems both in acidic, basic, and neutral conditions. The research successfully made a metal organic framework (MOF) from chromium and perylene that was modulated by isonicotinic acid. This was done using three different methods: hydrothermal (Cr-PTC-HIna-HT), solvothermal (Cr-PTC-HIna-ST), and sonochemical (Cr-PTC-HIna-SC). The Cr-PTC-HIna-SC showed the greatest Pb2+ ion adsorption capacity. The optimum adsorption of Pb2+ ions occurred at 150 ppm Pb2+ ion concentration, pH 5, 90 minutes of contact time, and an adsorption capacity of 149.95 mg/g at 35 °C. The dominant adsorption isotherm model is the Langmuir isotherm model with R2 = 0.9867 and follows the pseudo-second-order. The selectivity test showed that Cr-PTC-HIna-SC MOF could adsorb more Cd2+ ions than Pb2+ ions, with 250 mg/g being the best amount.

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Journal Info
Bulletin of Chemical Reaction Engineering & Catalysis
Website

Abbrev

bcrec

Publisher

Masyarakat Katalis Indonesia - Indonesian Catalyst Society

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis, a reputable international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics, and chemical reaction engineering. Scientific articles dealing with the following topics in ...