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Energy Conversion of Industrial Wastewater on Microbial Fuel Cell (MFC)-Based with Biocatalysts and Pretreatments: A Review Suryawan, I Wayan Koko; Septiariva, Iva Yenis; Sarwono, Ariyanti
Indonesian Journal of Environmental Management and Sustainability Vol. 4 No. 4 (2020): December
Publisher : Research Centre of Inorganic Materials and Complexs

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/ijems.2020.4.4.102-109

Abstract

The purpose of this review is to provide current information regarding industrial wastewater treatment with MFC technology with the addition of biocatalysts and pretreatments. Moreover, this review also updates industrial waste treatment technology with MFC technology in Indonesia. Waste could be generated from domestic activities as well as non-domestic activities, such as industries. Industries produce waste with quite high organic content. This organic material is not easily degraded in biological treatment. Wastewater treatment, currently, aims only to meet standards quality and not to reuse. In Indonesia, the reuse processes, one of which is still rarely found in the form of energy. Industries that can process and convert wastewater energy can help the government realize sustainable development in the energy sector. One of the technologies is the Microbial Fuel Cell (MFC). Previous MFC research that had been carried out was limited to laboratory scale with a volume of less than 1 L and, among them, used mixed or artificial waste. MFC processing uses anode in wastewater as a substrate source and generates electrons under anaerobic conditions. Electron formation could be accelerated by adding biocatalysts such as enzymes and specific microorganisms. The processing occurred in an anaerobic anode that could be increased by increasing the substrate's biodegradability value in the waste. The biodegradability value can be increased by pretreatment with ozone or ultrasonic technology. In Indonesia, research on industrial wastewater treatment with MFC as well as biocatalyst and pretreatment is still relatively minimal.
Reactive Black 5 (RB5): Pengolahan Air Limbah Tekstil dengan Adsorbsi Menggunakan Powdered Karbon Aktif Septiariva, Iva Yenis; Suryawan, I Wayan Koko; Sarwono, Ariyanti
Jurnal Teknologi Lingkungan Vol. 22 No. 2 (2021)
Publisher : Center for Environmental Technology - Agency for Assessment and Application of Technology

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (436.847 KB) | DOI: 10.29122/jtl.v22i2.4523

Abstract

ABSTRAK Umumnya, industri tekstil menggunakan berbagai pewarna sintetis yang menghasilkan air limbah yang sangat berwarna. Oleh karenaitu, air limbah tekstil ini harus diolah sebelum dibuang ke lingkungan. Penelitian ini bertujuan untuk mengetahui penyisihan warna dengan teknik adsorpsi menggunakan karbon aktif. Metode ini dianggap sebagai teknologi berbiaya rendah dan perawatan yang mudah untuk pengolahan air limbah. Proses adsorpsi batch dilakukan dengan waktu kontak yang berbeda yaitu 5–60 menit dan variasi konsentrasi awal yang mengandung Reactive Black 5 (RB-5) sebesar 5 mg/L; 10 mg/L; 15 mg/L; dan 20 mg/L. Azo-Reactive Black-5 adalah material pewarna yang digunakan untuk membuat air limbah artifisial. Hasil penelitian menunjukkan bahwa proses adsorpsi menurunkan kadar konsentrasi warna masing-masing sebesar 86,21%, 85,21%, 84,29%, dan 71,07% selama 60 menit. Peningkatan konsentrasi zat warna dalam air limbah menyebabkan efisiensi penghilangan warna yang rendah. Selain itu, penelitian mengevaluasi efektivitas adsorpsi batch oleh karbon aktif karena efisiensi penghilangan warna dapat mencapai lebih dari 50% setelah waktu kontak 30 menit. Hal ini terlihat pada konsentrasi awal 5 mg/L dan 20 mg/L dengan efisiensi penyisihan sebesar 66,18% dan 53,97%. Kinetika adsorpsi yang sesuai untuk pendekatan pemodelan pada penelitian ini adalah Langmuir isotherm dengan nilai r2 yang lebih besar dan mendekati nilai 1 yaitu 0,9756. Estimasi kapasitas adsorpsi maksimum yang diperoleh dari model sebesar 4,353 mg/g. Kata kunci: Air limbah tekstil, warna, adsorpsi, efisiensi penyisihan   ABSTRACT Generally, the textile industry uses various synthetic dyes that produced a large amount of highly colored wastewater. This research aims to investigate the color removal by adsorption using powdered activated carbon. This method is considered viable due to cost effective and ease of maintenance for wastewater treatment. The batch adsorption process was carried out at different contact times of 5–60 minutes and varied initial dye concentration containing azo-Reactive Black 5 (RB-5) of 5 mg/L; 10 mg/L; 15 mg/L; and 20 mg/L. A synthetic RB-5 was prepared  as the artificial wastewater to simulate the actual wastewater. The adsorption  proceeded initially with higher rates and gradually slowed down until reached a constant value due to the carbon surface's saturation with increasing contact time.The results showed that, at different initial dye concentration, the adsorption process decreased color concentration for 60 minutes by 86.21%, 85.21%, 84.29%, and 71.07% respectively. The increase of initial dye concentration lowers color removal efficiency. Besides, the effectiveness of adsorption by activated carbon was found more than 50% after 30 minute of contact time. The efficiency removal presented initial concentration of 5 mg/ and 20 mg/L was 66.18% and 53.97%, respectively. Langmuir and Freundlich isotherm were also plotted to assess the kinetics of adsorption. Langmuir isotherm gave the best modelling approach for adsorption kinetics as indicated by higher coefficient of determination (r2) of 0.9756. An estimated maximum adsorption capacity obtained from the model was 4.353 mg/g. Keywords: Textile wastewater, color, adsorption, removal efficiency
Textile Dye Reactive Black 5 (RB5) Bio-Sorption with Moving Bed Biofilm Reactor and Activated Sludge Suryawan, I Wayan Koko; Helmy, Qomarudin; Notodarmojo, Suprihanto; Pratiwi, Riska; Septiariva, Iva Yenis
Indonesian Journal of Environmental Management and Sustainability Vol. 5 No. 2 (2021): June
Publisher : Research Centre of Inorganic Materials and Complexs

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26554/ijems.2021.5.2.67-71

Abstract

Reactive Black 5 (RB5) is one of the dyes used in textile industries in Indonesia. However, the high color content can interfere with the condition of water bodies if not treated. This waste treatment process is usually treated with biological treatment processes. Biological processing often used is the MBBR unit and activated sludge. This study aims to determine the RB5 dye’s bio-sorption efficiency using MBBR processing and activated sludge. MBBR processing and activated sludge consist of seeding, acclimatization, and running stages. This research was carried out using a real textile wastewater approach by adding 100 mg/L RB5 and adding 1000 mg/L starch solution. The processing results of the seeding stage indicate increasing in biomass. The acclimatization stage with 50% and 75% of wastewater indicates increased biomass and color removal. The RB5 color removal efficiency results in the MBBR unit and activated sludge show 41% and 84% values. The MBBR processing shows fluctuations each time where the desorption process occurs in the color removal. For this reason, the ozone pre-treatment process is conducted in the MBBR unit. The integrated pre-treatment with MBBR results show the same fluctuation as the previous processing with a color removal efficiency of 43% with a color removal efficiency of 43%.
Potential of Energy Municipal Solid Waste (MSW) to Become Refuse Derived Fuel (RDF) in Bali Province, Indonesia Suryawan, I Wayan Koko; Wijaya, I Made Wahyu; Sari, Novi Kartika; Septiariva, Iva Yenis; Zahra, Nurulbaiti Listyendah
Jurnal Bahan Alam Terbarukan Vol 10, No 1 (2021): June 2021 [Nationally Accredited - SINTA 2]
Publisher : Universitas Negeri Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15294/jbat.v10i1.29804

Abstract

The generation of municipal solid waste (MSW) in Bali has various environmental impacts. One of the updates on sustainable waste processing is the RDF treatment plant processing. Before carrying out the processing, MSW characterization is needed because each region has a diverse composition. The processing of MSW into RDF provides benefits for achieving MSW reduction targets, renewable energy use, and the reduction of greenhouse gas (GHG) emissions. For this reason, this study was conducted to determine the potential of MSW in Bali as an alternative to renewable fuel and its potential to reduce GHG. MSW's potential calorific value as a raw material for RDF in Bali can reach 9.58 - 17.71 MJ/kg. The implementation of processing waste into RDF in pellets has shown a calorific value of ± 3904 - 4945 kkcal/kg. Implementing MSW processing into RDF in Bali can reduce GHG by 178 - 330 times compared to open dumping.
Potential of Energy Municipal Solid Waste (MSW) to Become Refuse Derived Fuel (RDF) in Bali Province, Indonesia Suryawan, I Wayan Koko; Wijaya, I Made Wahyu; Sari, Novi Kartika; Septiariva, Iva Yenis; Zahra, Nurulbaiti Listyendah
Jurnal Bahan Alam Terbarukan Vol 10, No 1 (2021): June 2021 [Nationally Accredited - Sinta 2]
Publisher : Universitas Negeri Semarang

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.15294/jbat.v10i1.29804

Abstract

The generation of municipal solid waste (MSW) in Bali has various environmental impacts. One of the updates on sustainable waste processing is the RDF treatment plant processing. Before carrying out the processing, MSW characterization is needed because each region has a diverse composition. The processing of MSW into RDF provides benefits for achieving MSW reduction targets, renewable energy use, and the reduction of greenhouse gas (GHG) emissions. For this reason, this study was conducted to determine the potential of MSW in Bali as an alternative to renewable fuel and its potential to reduce GHG. MSW's potential calorific value as a raw material for RDF in Bali can reach 9.58 - 17.71 MJ/kg. The implementation of processing waste into RDF in pellets has shown a calorific value of ± 3904 - 4945 kkcal/kg. Implementing MSW processing into RDF in Bali can reduce GHG by 178 - 330 times compared to open dumping.
Substitution Garden and Polyethylene Terephthalate (PET) Plastic Waste as Refused Derived Fuel (RDF) Zahra, Nurulbaiti Listyendah; Septiariva, Iva Yenis; Sarwono, Ariyanti; Qonitan, Fatimah Dinan; Sari, Mega Mutiara; Gaina, Pratiwi Claudia; Ummatin, Kuntum Khoiro; Arifianti, Qurrotin Ayunina Maulida Okta; Faria, Niswatun; Lim, Jun-Wei; Suhardono, Sapta; Suryawan, I Wayan Koko
International Journal of Renewable Energy Development Vol 11, No 2 (2022): May 2022
Publisher : Center of Biomass & Renewable Energy, Diponegoro University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.14710/ijred.2022.44328

Abstract

The generation of polyethylene terephthalate (PET) plastic and garden waste must be recycled to support the circular economy. An alternative way to reduce the plastics waste is to reduce this waste by converting it into energy such as Refused Derived Fuel (RDF) as an alternative for processing waste. Substitution of plastic and garden waste is an opportunity to be analyzed. Hence, This study aimed to investigate the potential for converting material substitution from PET and garden waste into RDF. The RDF characterized test method was carried out by proximate, water content, ash content, and analysis. At the same time, the calorific value. was tested by bomb calorimetry. Substitution of the mixture of plastic and garden waste affects each parameter of RDF pellet quality including water, ash, and caloric value (sig.< 0.05). The increase of plastic waste in pellets consistently increases the calorific value of RDF from 18.94 until 25.04 MJ/kg. The RDF pellet water and ash content also invariably affect the rate of increase in the calorific value of RDF in the multilinearity model (sig.<0.05; R2 is 0.935). The thermal stability of the pellets occurred at a temperature of 5000C decomposition of hemicellulose, cellulose, and lignin in mixed garden waste with plastic in RDF pellets. The decrease in the decomposition of PET into terephthalic acid monomer from the thermal stability of raw materials and waste PET plastic pellets occurs at a temperature of 4500ËšC. This potential finding can be used as a basis for consideration in regions or countries that have the generation of garden waste and plastic, especially the type of PET to be used as an environmentally friendly fuel.