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KAJIAN ADSORPSI Ag(S2O3)23- DALAM LIMBAH FOTOGRAFI PADA ADSORBEN KITIN DAN ASAM HUMAT TERIMOBILISASI PADA KITIN Khoerunnisa, Fitri; Santosa, Sri Juari; Kunarti, Eko Sri
Jurnal Pengajaran Matematika dan Ilmu Pengetahuan Alam Vol 9, No 2 (2007): Jurnal Pengajaran MIPA
Publisher : Faculty of Mathematics and Science Education, Universitas Pendidikan Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.18269/jpmipa.v9i2.327

Abstract

This work was started with isolation of humic acid from peat soil and chitin from crab shell, immobilization of humic acid on chitin, and characterization of adsorbents of C and HAC. Optimum condition was studied by interacting the adsorbents with Ag(S2O3)23- in a synthetic solution on various  of pH from 2 to 10. Adsorption rate was studied by interacting the adsorbent with Ag(S2O3)23- in the synthetic solution on various time from 2 to 120 minutes. The determination of the energy and the capacity of adsorption were studied by interacting the adsorbent with Ag(S2O3)23- on various initial concentration from 2 to 75 ppm. Moreover, the mechanism of adsorption was studied by applying a sequential desorption using H2O, Na2EDTA 0.1 M, KSCN 0.5 M, and KOH 1 M. The adsorption of Ag(S2O3)23- in photography wastewater on C and on HAC were studied at the same condition as obtained for the synthetic solution. The result showed that pH 2 was the optimum adsorption condition for Ag(S2O3)23- in the synthetic solution on both C and HAC adsorbents. Ag(S2O3)23- in the synthetic solution was chemically adsorbed on C and on HAC, involving energy adsorption of 22.74–23.30 kJ/mole, respectively. Adsorption of Ag(S2O3)23- on C was faster than that on HAC with the rate constants for adsorbent C and HAC were 73 x 10-4 and 46 x 10-4 minute-1, respectively. Adsorption capacity of Ag(S2O3)23- on C and on HAC were 2.107 x 10-4 and 1.818 x 10-4 mole/g, respectively. The amount of Ag(S2O3)23- in photography wastewater that was adsorbed on C and on HAC were 13.52 and 12.47 mg/L, respectively. The hydrogen bonding and ion exchange were the dominant mechanism of adsorption.Key words: Ag(S2O3)23-, adsorption, chitin, immobilization, humic acid.
SINTESIS KALIKS[4]RESORSINARENA DARI MINYAK KAYUMANIS DAN PENGGUNAANNYA UNTUK EKSTRAKSI FASA PADAT LOGAM BERAT HG(II) DAN PB(II) Sardjono, Ratnaningsih E.; Dwiyanti, Gebi; Aisyah, Siti; Khoerunnisa, Fitri
Jurnal Pengajaran Matematika dan Ilmu Pengetahuan Alam Vol 12, No 1 (2008): Jurnal Pengajaran MIPA
Publisher : Faculty of Mathematics and Science Education, Universitas Pendidikan Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.18269/jpmipa.v12i1.318

Abstract

Sintesis C-sinamal kaliks[4]resorsinarena (CSKR) dari minyak kayumanis dan penggunanannya untuk ekstraksi fasa padat logam berat Pb(II) dan Hg(II) telah dilakukan. CSKR diperoleh sebanyak 75% sebagai produk reaksi resorsinol dan sinamaldehida pada 77oC selama 24 jam. Isolasi sinamaldehida dari minyak kayumanis melalui metode bisulfit menghasilkan sinamaldehida sebanyak 79% dengan kemurnian 99,5%. Ekstraksi fasa padat Pb(II) dan Hg(II) oleh CSKR dilakukan dalam sistem batch pada berbagai pH, waktu interaksi, dan konsentrasi logam. Ekstraksi fasa padat Pb(II) berlangsung optimum pada pH 4, waktu interaksi 180 menit, dan konsentrasi awal 6,6 mg/L, mengikuti model kinetika pseudo orde dua, mengikuti model isoterm Langmuir, serta memberikan kapasitas ekstraksi sebesar 1,986 mol/g atau 37,2%. Sementara itu, ekstraksi fasa padat Hg(II) berlangsung optimum pada pH 5, waktu interaksi 180 menit, dan konsentrasi awal 0,36 mg/L, mengikuti model kinetika pseudo orde dua, mengikuti model isoterm Freundlich, serta memberikan kapasitas ekstraksi sebesar 0,71 mol/g atau 79,1%.Kata kunci :  Ekstraksi Fasa Padat, Kaliks[4]resorsinarena, Minyak Kayumanis, Hg(II), Pb(II)  
SINTESIS KALIKS[4]RESORSINARENA DARI MINYAK KAYUMANIS DAN PENGGUNAANNYA UNTUK EKSTRAKSI FASA PADAT LOGAM BERAT HG(II) DAN PB(II) Sardjono, Ratnaningsih E.; Dwiyanti, Gebi; Aisyah, Siti; Khoerunnisa, Fitri
Jurnal Pengajaran MIPA Vol 12, No 2 (2008): JPMIPA: Volume 12, Issue 2, 2008
Publisher : Faculty of Mathematics and Science Education, Universitas Pendidikan Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.18269/jpmipa.v12i2.35776

Abstract

Sintesis C-sinamal kaliks[4]resorsinarena (CSKR) dari minyak kayumanis dan penggunanannya untuk ekstraksi fasa padat logam berat Pb(II) dan Hg(II) telah dilakukan. CSKR diperoleh sebanyak 75% sebagai produk reaksi resorsinol dan sinamaldehida pada 77oC selama 24 jam. Isolasi sinamaldehida dari minyak kayumanis melalui metode bisulfit menghasilkan sinamaldehida sebanyak 79% dengan kemurnian 99,5%. Ekstraksi fasa padat Pb(II) dan Hg(II) oleh CSKR dilakukan dalam sistem batch pada berbagai pH, waktu interaksi, dan konsentrasi logam. Ekstraksi fasa padat Pb(II) berlangsung optimum pada pH 4, waktu interaksi 180 menit, dan konsentrasi awal 6,6 mg/L, mengikuti model kinetika pseudo orde dua, mengikuti model isoterm Langmuir, serta memberikan kapasitas ekstraksi sebesar 1,986 mol/g atau 37,2%. Sementara itu, ekstraksi fasa padat Hg(II) berlangsung optimum pada pH 5, waktu interaksi 180 menit, dan konsentrasi awal 0,36 mg/L, mengikuti model kinetika pseudo orde dua, mengikuti model isoterm Freundlich, serta memberikan kapasitas ekstraksi sebesar 0,71 mol/g atau 79,1%.
KAJIAN ADSORPSI Ag(S2O3)2 3- DALAM LIMBAH FOTOGRAFI PADA ADSORBEN KITIN DAN ASAM HUMAT TERIMOBILISASI PADA KITIN Khoerunnisa, Fitri; Santosa, Sri Juari; Kunarti, Eko Sri
Jurnal Pengajaran MIPA Vol 9, No 2 (2007): JPMIPA: Volume 9, Issue 2, 2007
Publisher : Faculty of Mathematics and Science Education, Universitas Pendidikan Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.18269/jpmipa.v9i2.35754

Abstract

This work was started with isolation of humic acid from peat soil and chitin from crab shell, immobilization of humic acid on chitin, and characterization of adsorbents of C and HAC. Optimum condition was studied by interacting the adsorbents with Ag(S2O3)2 3- in a synthetic solution on various of pH from 2 to 10. Adsorption rate was studied by interacting the adsorbent with Ag(S2O3)2 3- in the synthetic solution on various time from 2 to 120 minutes. The determination of the energy and the capacity of adsorption were studied by interacting the adsorbent with Ag(S2O3)2 3- on various initial concentration from 2 to 75 ppm. Moreover, the mechanism of adsorption was studied by applying a sequential desorption using H2O, Na2EDTA 0.1 M, KSCN 0.5 M, and KOH 1 M. The adsorption of Ag(S2O3)2 3- in photography wastewater on C and on HAC were studied at the same condition as obtained for the synthetic solution. The result showed that pH 2 was the optimum adsorption condition for Ag(S2O3)2 3- in the synthetic solution on both C and HAC adsorbents. Ag(S2O3)2 3- in the synthetic solution was chemically adsorbed on C and on HAC, involving energy adsorption of 22.74–23.30 kJ/mole, respectively. Adsorption of Ag(S2O3)2 3- on C was faster than that on HAC with the rate constants for adsorbent C and HAC were 73 x 10-4 and 46 x 10-4 minute-1 , respectively. Adsorption capacity of Ag(S2O3)2 3- on C and on HAC were 2.107 x 10-4 and 1.818 x 10-4 mole/g, respectively. The amount of Ag(S2O3)2 3- in photography wastewater that was adsorbed on C and on HAC were 13.52 and 12.47 mg/L, respectively. The hydrogen bonding and ion exchange were the dominant mechanism of adsorption.
BIODEGRADASI SIFAT TOKSIK LOGAM BERAT KROM DALAM LIMBAH CAIR INDUSTRI Nahadi, Nahadi; Hernani, Hernani; Khoerunnisa, Fitri
Jurnal Pengajaran MIPA Vol 6, No 2 (2005): JPMIPA: Volume 6, Issue 2, 2005
Publisher : Faculty of Mathematics and Science Education, Universitas Pendidikan Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.18269/jpmipa.v6i2.34995

Abstract

Telah dilakukan penelitian degradasi sifat toksik logam berat krom oleh bakteri melalui rekasi enzimatik yang mengubah krom(VI) toksik menjadi krom(III) yang kurang toksik. Penelitian dilakukan dengan memvariasikan pengaruh beberapa parameter terhadap reaksi enzimatik ini yaitu; jumlah bakteri, tingkat keasaman dan konsentrasi krom(VI).Untuk menentukan konsentrasi krom(VI) yang tereduksi menjadi krom(III) digunakan teknik spektrofotometri UV-Vis. Jumlah krom(VI) yang tereduksi menjadi krom(III) ditentukan dengan menghitung selisih antara jumlah krom(VI) sebelum dan sesudah proses transformasi.Hasil analisis menunjukkan bahwa efektivitas transformasi krom(VI) menjadi krom(III) dipengaruhi oleh parameter-parameter di atas. Transformasi krom(VI) menjadi krom(III)  sangat dipengaruhi oleh pH larutan. Kondisi keasaman optimum untuk terjadinya transformasi krom(VI) menjadi krom(III) adalah pada pH = 7.  Proses transformasi ini  meningkat secara linear sebagai fungsi konsentrasi awal, dengan konsentrasi maksimum 30 ppm. Transformasi ini juga berlangsung efektif pada jumlah bakteri satu ose. Tingkat transformasi pada kondisi optimum mencapai 88,4%.
Geothermal: From Education to a New Solution for Renewable Energy Fauziah, Naila Raima; Maoludin, Surya Alfin; Ramadhan, Wildan Septi; Wafi, Wulanda; Khoerunnisa, Fitri; Winarno, Nanang
Indonesian Journal of Multidiciplinary Research Vol 1, No 1 (2021): IJOMR: VOLUME 1, ISSUE 1, 2021
Publisher : Universitas Pendidikan Indonesia (UPI)

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1385.344 KB) | DOI: 10.17509/ijomr.v1i1.33785

Abstract

Fossil energy is still the main contributor in Indonesia. In fact, based on a study it is stated that fossil fuels will only last 50-70 years. For this reason, it is necessary to increase the role of geothermal energy as renewable energy. Geothermal energy is very good if it is developed into a new and renewable energy source because it has a good impact on the environment. Geothermal energy also does not damage the local conditions such as mining activities so that biodiversity is preserved. Then, the operation period of the Geothermal Power Generation (known as PLTP) can be more than 30 years and does not require fuel. Geothermal energy is environmentally friendly, and its potential impact on pollution is minimal. Thus, geothermal energy is the right solution to overcome dependence on fossil energy that is not renewable and is expected to run out in the near future.
Eco Cooler for Cooler House without Electricity for Educational Purposes Antonio, Alvito; Hasanah, Maulidah; Damayanti, Novita; Devina, Oryza Aprilia; Khoerunnisa, Fitri; Winarno, Nanang
Indonesian Journal of Multidiciplinary Research Vol 1, No 1 (2021): IJOMR: VOLUME 1, ISSUE 1, 2021
Publisher : Universitas Pendidikan Indonesia (UPI)

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1436.007 KB) | DOI: 10.17509/ijomr.v1i1.33775

Abstract

The earth's temperature from 1981 to February 2021 has relatively increased. The increase in temperature on earth has made many people choose to use air conditioning so that the temperature in their homes is not too cold. The energy demand from air conditioning worldwide will be three times as much by 2050. Bangladesh has created a system called the Eco-Cooler as an alternative to lowering room temperature without using large electrical energy so as to save energy and costs. The eco-cooler can reduce temperatures from 1-3˚C in a room with a size of 4.2 × 4.2 × 3.3 m3 using an Eco-cooler with a bottle diameter of 6 cm and a board area of 48 × 48 cm2. This can be a good educational point for being applied in Indonesia. The advantage of using the Eco-Cooler is that it is easy to maintain, easy to use, the air is more humid, and it saves energy.
The Efficient Implementation of Hybrid Power Plants in Indonesia Perdiansyah, Farhan; Fitriana, Eka Tiara Nur; Aziema, Nur; Maharani, Permata Putri; Khoerunnisa, Fitri; Winarno, Nanang
Indonesian Journal of Multidiciplinary Research Vol 1, No 1 (2021): IJOMR: VOLUME 1, ISSUE 1, 2021
Publisher : Universitas Pendidikan Indonesia (UPI)

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (1339.42 KB) | DOI: 10.17509/ijomr.v1i1.33772

Abstract

The energy crisis is a serious issue that all countries around the world are dealing with, particularly the energy sources used to generate electricity. There are numerous alternative energy sources available in nature, such as solar energy, wind energy, and so on. Wind and solar energy as hybrid energy sources are thought to be promising in electric generation technology. Hybrid Power Plants can also be used to address the issue of limited electrical energy supply in Indonesia's remote areas. The purpose of this study is to describe the effectiveness of the hybrid power plants implementation in Indonesia. The study was conducted using the narrative literature review method. It can be inferred that the purpose of developing this hybrid technology, among others, is to obtain more efficient electrical energy generation by combining the advantages of two or more types of power generation systems that work in an integrated manner as a compact system. The produced electric energy can be stored in the battery. In terms of use, the produced direct current (DC) is converted into alternating current (AC) using the inverter system prior to distribution to consumers. Therefore, this hybrid power plant is suitable to be implemented in Indonesia.
Co-Authors Antonio, Alvito Aziema, Nur Devina, Oryza Aprilia Eko Sri Kunarti Fauziah, Naila Raima Fitriana, Eka Tiara Nur Gebi Dwiyanti Hasanah, Maulidah HERNANI - Maharani, Permata Putri Maoludin, Surya Alfin Nahadi Nanang Winarno Novita Damayanti Perdiansyah, Farhan Ramadhan, Wildan Septi Ratnaningsih E. Sardjono Siti Aisyah Sri Juari Santosa Wafi, Wulanda