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SYNTHESIS N-PHENYLAMINEDITHIOCARBAMATE AS CHELATING AGENT IN SOLVENT EXTRACTION Fatimah, Soja Siti; Musfiroh, Vera; Zackiyah, Zackiyah; Bahti, Husein H.; Hastiawan, Iwan; Permanasari, Anna
Chimica et Natura Acta Vol 2, No 3 (2014)
Publisher : Departemen Kimia

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (207.559 KB) | DOI: 10.24198/cna.v2.n3.9160

Abstract

Dithiocarbamate derivatives is a versatile ligand that contain two atoms of sulfur as a strong electron donor. It combines with metals. N-phenylaminedithiocarbamate has synthesized and applied in solvent exctration. Synthesis carried out with addition carbon disulphide to N-phenylamine and concentrated pottasium hydroxyde in metanol. The result was characterized by spectroscopy 1H-NMR, 13C-NMR, FTIR, Elemental Analysis, that showed molecular structure was significant. Applied N-Phenylaminedithiocarbamate in solvent extraction showed precent of result Cu(II), Co(II), Cr(III) and Ni (II) were 90.45% - 99.99% at pH 4-9.