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Silalahi, Lambok Hlarius
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Energy

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ANALISIS KEUNGGULAN LIMONIT SOROAKO SEBAGAI KATALIS PENCAIRAN BATUBARA (DIRECT LIQUEFACTION) Hidayat, Herman; Silalahi, Lambok Hlarius
Jurnal Energi dan Lingkungan (Enerlink) Vol 3, No 1 (2007)
Publisher : Jurnal Energi dan Lingkungan (Enerlink)

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Abstract

An investigation of catalytic activities of Soroako limonite ore using 1liter autoclavewas carried out. The comparison of the results with other iron catalysts forliquefaction of Banko coal was also performed to find out the best catalyst forBanko coal liquefaction. Much efforts to improve brown coal liquefaction processefficiency has been conducted at BPPT since 1994 through the design of highlyactive catalysts along with design of good hydrogen donor solvents. Someprevious studies have shown that limonite ore has several superior characteristicscompared to pyrite (FeS2) when used as catalyst in coal liquefaction process. Onemain reason is that limonite ore contains both iron and nickel compound asFeOOH, FeNi2OOH, FeCr2OOH that found to be responsible of high distillate.The use of natural ore for catalyst will implies that the production of industrialcatalyst for coal liquefaction could be obtained with low production cost. Theresults suggest that catalytic activity of Soroako limonite could be achieved at lowtemperature around 300 oC or less changing its crystallite form to pyrrhotite (Fe1-xS) species. Such phenomenon is similar to that of highly active Yandi Yellowcatalyst. Moreover, Soroako limonite catalyst also gives higher oil yield withsmaller amount of hydrogen consumption compare to pyrite and Yandi yellowcatalysts. So it concludes that Soroako limonite has high catalytic activity, and itssoft physical nature makes it possible to be pulverized into sub-micron particlesize easily and economically. Soroako limonite, therefore, can be recommendedas one of the most suitable catalysts for commercial coal liquefaction plant to beconstructed in the future.Kata kunci: coal liquefaction, soroako limonite, -FeOOH, pyrrhotite, limonitecatalyst
KARAKTERISASI SECARA RINCI SENYAWA HETEROATOM DALAM FRAKSI RINGAN MINYAK BATUBARA TANITO HARUM DAN PRODUK MINYAK HASIL HYDROTREATMENT Murti, Sri Djangkung Sumbogo; Silalahi, Lambok Hlarius
Jurnal Energi dan Lingkungan (Enerlink) Vol 3, No 2 (2007)
Publisher : Jurnal Energi dan Lingkungan (Enerlink)

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Heteroatom compounds contained in coal oil Tanito Harum both before and afterhydrotreatment were identified using a gas feed chromatography with atomicemission detector (GC AED). Alkylated dibenzothiophenes benzothiophenes andsulfur compounds were found to be dominant in the original faction, his wholesuccessfully removed through hydrotreatment process on the condition of 350oC,10 MPa, and 60 min. Alkylated anilines, quinoline, indoles, and carbazoles foundin the original oil as nitrogen compounds. Two types of specific nitrogencompounds persist for hydrotreatment process underway and identifiedrespectively as C11H20N and C14H23N, based on the ratio of the element iscalibrated by GC-AED and the molecular weight was measured by GC-MS (massspectrometry). The empirical formula is very similar to such C11H19N andC14H23N, were detected by MS and NMR after concentrated by extraction. Somesulfur compounds present in non-aromatic fraction, while all nitrogen compoundsare completely concentrated in the aromatic fraction after separation byconventional chromatographic columns. There was also alkylated phenols,benzofurans and dibenzofurans were found as typical oxygen compounds in theoil.Kata Kunci: limonite catalyst; coal liquefaction, catalytic hydrotreating, liquefiedcoal oil, gas oil fraction, cetane index, octaen number
RISET REAKTIFITAS LIMONIT SOROAKO SEBAGAI KATALIS PADA PENCAIRAN BATUBARA DENGAN GAS FLOW TYPE REACTOR Hidayat, Herman; Silalahi, Lambok Hlarius
Jurnal Energi dan Lingkungan (Enerlink) Vol 2, No 2 (2006)
Publisher : Jurnal Energi dan Lingkungan (Enerlink)

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Abstract

B r o w n Coal Liquefaction (BCL) process had been developed through theconstruction and the operation of 50 T/D pilot plant Ill Australia (1985-1990) byKOBE STEEL Group. After the successful completion of the Pilot Plant Project,newly Improved BCL process has been developed1). The feasibility study onthe commercialization of coal liquefaction plant in Indonesia has also beencarried out under the cooperation with BPPT supported by NEDO Limonitore (α-FeOOH) can be used as an industrial catalyst for direct coal liquefactionwith its high activity and low production cost. In this paper, the catalytic activitiesof Indonesian limonit ore, Soroako Limonit were examined using a gas flow typeautoclave comparing with the other iron catalysts for the liquefaction ofIndonesian brows coal. It appeared that the Soroako limonit has a highcatalystic activity while finely pulverizing to sub-micron particle size can bedone economically. It can be concluded that Soroako limonit is one of mostsuitable catalysts for the coal liquefaction plant constricted in Indonesia in thefut-ure.Kata kunci: direct liquefaction, soroako limonit, iron catalyst, phyrrotite, bankocoal
FUNDAMENTAL STUDY ON LIQUEFACTION OF KALIMANTAN BROWN COALS Hartiniati, Hartiniati; Silalahi, Lambok Hlarius
Jurnal Energi dan Lingkungan (Enerlink) Vol 3, No 2 (2007)
Publisher : Jurnal Energi dan Lingkungan (Enerlink)

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Abstract

Efek karakateristik batubara terhadap yield produk pencairan batubaradiinvetigasi menggunakan sampel batubara dari Berau (Lati dan Kelai), Mulia,Wara dan Kideco. Batubara Banko dari Tanjung Enim, Sumatera Selatan,digunakan sebagai batubara rujukan. Pengujian pencairandilaksanakanmenggunakan gas-flow type autoclave (5L) dengan umpanbatubara 2002 (daf), pelarut batubara turunan (b.p.300-420oC) 400g, katalis Fe1.0-3.0 wt% (daf), elemen sulfur (rasio atom S/Fe 2.,0) pada tekanan 14.7MPa,suhu 450oC selama 60menit. Sampel limonit dari Soroako Indonesia dan YandiYellow dari Australia, yang terutama terdiri dari α-FeOOH, digunakan sebagaibahan katalis pada pengujian pencairan batubara. Studi ini merekomendasikanbertambahnya minyak yield akibat peningkatan kandungan oksigen dalambatubara, rasio atom H/C dan kandungan besi dalam batubara, mengingat besidalam batubara dapat berfungsi sebagai katalis dalam pencairan batubara.Limonit Soroako medium grade (MGL) menunjukkan aktifitas lebih tinggidibandingkan Yandi Yellow (YY) karena sifat transformasinya membentuk kristalkristalpyrrhotite (Fe1-XS), fase aktif dalam pencairan batubara. Sejumlahsenyawa nitrogen dan sulfur dalam minyak batubara telah berhasil dihilangkanmelalui proses hydrotreatment selanjutnya memperbaiki mutu produk.Keywords: pencairan, batubara berau, limonit, pyrrhotite, soroako,hydrotreatment
Co-Authors Hartiniati Hartiniati Herman Hidayat, Herman Murti, Sri Djangkung Sumbogo