Bulletin of Chemical Reaction Engineering & Catalysis
2019: BCREC Volume 14 Issue 3 Year 2019 (December 2019)

Basicity Optimization of KF/Ca-MgO Catalyst using Impregnation Method

Didi Dwi Anggoro (Department of Chemical Engineering, Diponegoro University)
Luqman Buchori (Department of Chemical Engineering, Diponegoro University)
Setia Budi Sasongko (Department of Chemical Engineering, Diponegoro University)
Herawati Oktavianty (Department of Chemical Engineering, Diponegoro University)



Article Info

Publish Date
01 Dec 2019

Abstract

This research aimed at determining the optimum value between calcination temperature (X1), calcination time (X2) and %wt KF (X3) toward optimum basicity of KF/Ca-MgO catalyst. Approximately 2-4%wt KF was added to the KF/Ca-MgO catalyst using the impregnation method to assist the Ca-MgO, at 450-550 ºC and a calcination time of 2-4 hours. Furthermore, its basicity was analyzed using Tanabe's titration method. The use of Variance Analysis (ANOVA), indicated that calcination temperature (X1) factor achieved the highest basicity of KF/Ca-MgO catalyst, as indicated by its high F-value (16.46262) and low p-value (0.0067). The correlation between each operating variables and the responses were shown in a mathematical equation. The optimization value is estimated by limiting the calcination temperature from 415.9 to 584.1 ºC, with a calcination time ranging from 1.32 to 4.68 hours, and %wt KF of 1.3182 to 4.6818 % that obtained 1.18 mmol/g for the optimal catalyst basicity. 

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Journal Info

Abbrev

bcrec

Publisher

Subject

Chemical Engineering, Chemistry & Bioengineering Chemistry

Description

Bulletin of Chemical Reaction Engineering & Catalysis (e-ISSN: 1978-2993), an international journal, provides a forum for publishing the novel technologies related to the catalyst, catalysis, chemical reactor, kinetics studies, and chemical reaction ...