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Journal : Indonesian Journal of Pure and Applied Chemistry

EKSTRAKSI MINYAK KELAPA MURNI DENGAN METODE PENGADUKAN DAN COLD PRESSED Deni Pranata; Puji Ardiningsih; Winda Rahmalia; Nurlina Nurlina; Intan Syahbanu
Indonesian Journal of Pure and Applied Chemistry Vol 3, No 2 (2020)
Publisher : Tanjungpura University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (357.9 KB) | DOI: 10.26418/indonesian.v3i2.46349

Abstract

Virgin coconut oil (VCO) was prepared by stirring and cold-pressed methods. This research aimed to study the effectiveness of both methods on VCO extraction. The first method was carried out by high-speed stirring to broke the coconut milk emulsion, and the second method was using the freezing and thawing technique. The physical appearance of VCO from both ways was clear, with a specific odor and taste of fresh coconut oil. The density of the VCO obtained by the stirring and cold-pressed method was 936 kg/m3 and 933 kg/m3, respectively. Physicochemical characterization shows that the cold-pressed process produces better properties of VCO.
SEMIKONDUKTOR BERBASIS TiO2-N/KAOLIN TERKALSINASI UNTUK DYE SENSITIZED SOLAR CELL (DSSC) Sabrina Maulidya Amir; Titin Anita Zahara; Risya Sasri; Winda Rahmalia
Indonesian Journal of Pure and Applied Chemistry Vol 2, No 1 (2019)
Publisher : Tanjungpura University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (3697.056 KB) | DOI: 10.26418/indonesian.v2i1.36944

Abstract

Semikonduktor TiO2 sebagai anoda dalam dye sensitized solar cell (DSSC) memiliki kelemahan yaitu hanya aktif bekerja pada radiasi sinar UV karena energi celah pita (Eg) TiO2 yang relatif besar yaitu 3,2 eV. Pada penelitian ini, dilakukan modifikasi untuk mengubah struktur elektronik TiO2, agar dapat menurunkan Eg. Dalam penelitian ini, TiO2 didoping menggunakan atom N dari NH4OH dan kaolin terkalsinasi (KT) yang disintesis dari kaolin Capkala. Beberapa parameter yang dibahas yaitu karakteristik TiO2-N/KT hasil pendopingan, penurunan energi celah pita dari semikonduktor, dan hubungan antara Eg dari semikonduktor terhadap randemen konversi energi maksimum DSSC yang dihasilkan. Dye yang digunakan dalam penelitian ini adalah ekstrak kayu secang. Difraktogram XRD TiO2-N/KT menunjukkan posisi 2θ = 25,2790o yang menunjukkan keberadaan TiO2 dan 2θ = 26,6090oyang menunjukkankeberadaan SiO2 dari kaolin terkalsinasi. Analisis dengan FTIR menunjukkan penyerapan pada bilangan gelombang 680 cm-1 yang menunjukkan vibrasi ikatan Ti-N dan 1036,77 cm-1 yang menandakan bahwa adanya vibrasi regangan asimetris O-Si-O dan O-Al-O. Terjadi penurunan Eg dari 3,2 eV (TiO2 murni) menjadi  3,03 eV (TiO2-N/KT). Penurunan energi celah pita sebanding dengan besarnya randemen konversi energi maksimum dari sel surya yang dihasilkan yaitu sebesar 1,048 %, menunjukkan performansi lebih baik dibanding dengan DSSC dengan komponen anoda TiO2 murni (0,661%)
ADSORPSI ASAM LEMAK BEBAS PADA CRUDE PALM OIL MENGGUNAKAN ZEOLIT TERAKTIVASI K2CO3 Nia Dahlia; Winda Rahmalia; Thamrin Usman
Indonesian Journal of Pure and Applied Chemistry Vol 2, No 3 (2019)
Publisher : Tanjungpura University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (813.747 KB) | DOI: 10.26418/indonesian.v2i3.36892

Abstract

Research on the use of K2CO3-activated zeolite as an adsorbent for free fatty acid (FFA) adsorption on crude palm oil (CPO) has been done. CPO is one of the mainstay products of Indonesian plantations which are used as raw material for cooking oil. The aim of this study to determine the adsorption capacity of activated zeolites against free fatty acid of CPO. The results showed that the iodium uptake capacity of zeolites before activation was 495.6%, activated zeolites were 527.1% and impregnated zeolites were 642.6%. The number of zeolites with the best absorption was 2 grams and ALB was absorbed 4.079% for activated zeolites (ZAA), 4.98% for impregnated zeolites (ZAI), and the water content and impurities were still below SNI standards. The CPO adsorption process with zeolites shows the Langmuir model with a correlation value (R2) of 0.9999 for ZAA and (R2) of 0.9976 for ZAI. The results showed that activated zeolites had lower absorption than impregnated zeolites.
PENGARUH JENIS MINYAK TERHADAP SIFAT FISIK D AN KIMIA BATH BOMB (THE EFFECT OF THE TYPE OIL ON THE PHYSICAL AND CHEMICAL PROPERTIES OF BATH BOMB) Annisa Bella Maharani; Lia Destiarti; Nurlina Nurlina; Intan Syahbanu; Winda Rahmalia
Indonesian Journal of Pure and Applied Chemistry Vol 3, No 1 (2020)
Publisher : Tanjungpura University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (158.439 KB) | DOI: 10.26418/indonesian.v3i1.46547

Abstract

Bath bombs were produced with ten different types of oil to determine the effect of the oil used on their physical and chemical properties. Bath bombs were prepared by mixing the dry ingredients first (citron, cornstarch, baking soda) and stirring until all the ingredients were well blended. Then, mixed the wet ingredients (water, oil, perfume ore, food coloring) into the beaker. After that, the wet ingredients were poured gradually into the dry dough, and this step was done until all the wet ingredients run out, and the texture of the bath bomb dough was slightly moist so that it can be put in the mold. Finally, the bath bomb is printed and tested in a laboratory. The result showed that the difference in essential oils used in the manufacture of bath bombs does not affect the pH of the bath bomb but affects the stability of the resulting foam. The acceptability test results showed that the resulting bath bomb provided a sensation of freshness and relaxation and did not cause allergies. Based on the SWOT analysis results, these bath bombs can advance and develop by implementing a vertical integration strategy
UJI KELARUTAN LOGAM DARI TAILING TIMAH MENGGUNAKAN PELARUT EUTEKTIK BERBASIS KOLIN KLORIDA DAN ASAM p-TOLUENASULFONAT Nimas Ade Kusdayanti; Winda Rahmalia; Thamrin Usman
Indonesian Journal of Pure and Applied Chemistry Vol 2, No 2 (2019)
Publisher : Tanjungpura University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (2571.673 KB) | DOI: 10.26418/indonesian.v2i2.36906

Abstract

Deep eutectic solvents (DES) are defined as combinations of two or three components which are able to establish hydrogen bond interactions with each other to form an eutectic mixture, that have a melting point lower than that of the each individual component. This study aims to determine the characteristics of DES based on choline chloride (ChCl) as quaternary ammonium salts and p-toluenasulfonic acid (PTSA) as hydrogen bond donors and to investigate their selectivity for dissolving metals in tin tailings. Synthesis of DES was carried out by mixing ChCl and PTSA with variations of the mole fraction, then stirring at 80 oC for 15 minutes. Resulted products were characterized their freezing point, density, viscosity, conductivity and functional groups. Mixture with a mole fraction of ChCl 0.6 formed homogeny clear liquid. It has a freezing point of 8 oC, density of 1.207 g/mL, viscosity of 4.663 cP, and conductivity of 182.4 mS/cm. Based on fourier transform infrared (FTIR) analysis, the interaction between ChCl and PTSA was due to the formation of hydrogen bonds between the O atoms of PTSA and the H atoms of ChCl. Inductively coupled plasma atomic emission spectroscopy (ICP-AES) analysis showed the presence of 1962 ppm of Fe metal dissolved in DES. This value was significant greater than the presence of other metals in the DES.
ADSORPSI ASAM LEMAK BEBAS DALAM MINYAK SAWIT MENTAH MENGGUNAKAN ADSORBEN ABU TANDAN KOSONG SAWIT M Syahwandi; Winda Rahmalia; Titin Anita Zahara; Thamrin Usman
Indonesian Journal of Pure and Applied Chemistry Vol 2, No 3 (2019)
Publisher : Tanjungpura University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (697.167 KB) | DOI: 10.26418/indonesian.v2i3.36894

Abstract

Research on the use of the oil palm empty fruit bunch (OPEFB) as an adsorbent for free fatty acid (FFA) adsorption on Crude Palm Oil (CPO) has been done. CPO is the main raw material in the manufacture of food products. The results of OPEFB adsorbent characteristics showed the amount of water content and ash content of 0,067% and 0,175%, XRF analysis obtained the greatest content of OPEFB in the form potassium metal as much as 44,24%, FTIR analysis identified that there were CO3 compounds in wave number 1648 cm-1 and SEM analysis indicates there are no pores in OPEFB. The result showed that the number of OPEFB with the best adsorption was 0,1 gram with 60 minute optimum contact time. The CPO adsorption process with OPEFB shows the Langmuir model with a correlation value (R2) of 0,8845 and the adsorptions kinetics follows the pseudo order 2 adsorption kinetics model with a correlation value (R2) of 0,9857. The results of this study showed the characteristics of CPO before and after adsorbed using 0,1 g of adsorbent OPEFB showed the amount of FFA level of 7,321% to 6,297%, water content of 0,0025% to 0,00119% and impurities content of 0,8847% to 0,8408%.
ADSORPTION OF Pb(II) BY POLYANILINE/SILICA GEL COMPOSITE: KINETICS AND ISOTHERM STUDIES Mas Inda Putrinesia; Nurlina Nurlina; Winda Rahmalia
Indonesian Journal of Pure and Applied Chemistry Vol 1, No 3 (2018)
Publisher : Tanjungpura University

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (547.632 KB) | DOI: 10.26418/indonesian.v1i3.34196

Abstract

Research on the study of kinetics and isotherm adsorption of Pb(II) by polyaniline/silica gel (PANI/SiO2) composite from glass waste has successfully been done. The polymerization of silica gel was prepared by sol-gel process. Meanwhile, PANI/SiO2 composite was prepared using sulfuric acid (H2SO4) as its dopants and hydrogen peroxide (H2O2) for oxidation process. Composition of oxide compound in PANI/SiO2 composite was analyzed by X-Ray Fluorosence (XRF) and Gas Sorption Analyzer (GSA). Adsorption of Pb(II) was carried out by contacting PANI/SiO2 with Pb(NO3)2 solution for 20, 40, 60 and 80 minutes, with concentrations of 150, 200, 250, 300, 350 and 400 mg/L. The optimum contact time was reached at 40 minutes. This adsorption followed pseudo-second order model with R2= 0.996. The first optimum adsorption capacity was reached in the concentration of 250 mg/L. Isotherm adsorption followed Langmuir models with R2= 0.954 (monolayer capacity= 51.02 mg/g).
SINTESIS GEOPOLIMER DENGAN BAHAN DASAR KAOLIN CAPKALA SEBAGAI ADSORBEN ION Pb(II) DALAM LARUTAN (SYNTHESIS OF GEOPOLYMERS WITH BASE MATERIALS KAOLIN CAPKALA AS ADSORBENT ION Pb(II) IN SOLUTION) Nur Ridha An Nisa; Intan Syahbanu; Winda Rahmalia; Nurlina Nurlina
Indonesian Journal of Pure and Applied Chemistry Vol 6, No 2 (2023)
Publisher : Tanjungpura University

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.26418/indonesian.v6i2.62731

Abstract

Geopolymer synthesis was carried out using kaolin, for the adsorption of Pb (II) ions in solutions. Kaolin is used by Kaolin Capkala from Bengkayang Regency, West Kalimantan. This kaolin was first modified into metakaolin. The scaling up of geopolymers is carried out by making an activating solution, namely by mixing NaOH and Na2SiO3. The activating solution is mixed into metakaolin. The mass composition of each component in the geopolymer: metakaolin of 94,5 grams, Na2SiO3 of 57 grams, NaOH of 12 grams, and H2O of 30 grams. The formed geopolymers are tested for their adsorption ability against Pb(II) ions. The research results show the success of geopolymer formation as indicated by FTIR and XRD characterization results. Based on the FTIR results, several indications of successful geopolymer formation are seen in the shift and widening of the Si-O absorption peak at wave number 1109 cm-1 for kaolin to 1058 cm-1 for metakaolin and 1016 cm-1 for geopolymer; the appearance of O-C-O bond absorption in CO32- at 1362 cm-1 in geopolymer; and a shift in absorption of Al-O (Al (VI), wherein kaolin it is indicated by a wave number of 536 cm-1 while in metakaolin it is characterized by a wave number of 544 cm-1 and for geopolymer a wave number of 553 cm-1 indicates it. XRD diffractogram of the formation hump's appearance shows the amorphous characteristics of metakaolin and geopolymer at around 2θ 26o-35o. The application of geopolymer for Pb adsorption shows that Pb(II) can be adsorbed well in geopolymers with the maximum adsorption capacity of 2.77 mg/ g obtained at various concentrations of 40 ppm.