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Penentuan Suhu Dan Waktu Optimum Pada Tahap D0 (Delignifikasi Pertama) Proses Bleaching Pembuatan Pulp Silaban, Kardiman; Chairul, Chairul; Sembiring, Maria Peratenta
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 2, No 2 (2015): Wisuda Oktober Tahun 2015
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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PT. Riau Andalan Pulp and Paper (RAPP) is a company has produced pulp and paper with Elemental Clorine Free (ECF) system in bleaching pulp stage. PT. RAPP used four process bleaching stage of pulp that’s D0 – EP - D1 – D2. Using clorine dioxide (ClO2) as bleaching pruff but EP stage were lignin extract process using oxygen and sodium dioxide (NaOH). One of the important thing in bleaching pulp is D0 stage process. For producing high quality pulp, one of important pruff must be recheck is temperature and time of bleaching pulp. The purpose of research was knowing effect of temperature in cooking timeof the first bleaching pulp stage process with accasia to quality pulp and economic value. Result of research to be used with get variation bleaching time 60, 70, 80, 90, 100 and 120 minutes and get variation bleaching temperature 65, 75, 80, and 90 (0C). in 650C and 60 minutes brightness was produced higher than else that is 66.42% ISO.

PEMBUATAN KOMPOS DARI LIMBAH PADAT (SLUDGE) PABRIK PULP DAN PAPER Sembiring, Maria Peratenta; Irianty, Rozanna Sri
Jurnal Riset Kimia Vol 5, No 2 (2012): March
Publisher : Universitas Andalas

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.25077/jrk.v5i2.213

One of the method to use pulp and paper mill sludge was convert it become a compost. This research result showed that time variation of compost have different physical and organic matter properties. In physical properties, 3 months of compost had 12.57% moisture content, while organic matter contain 10.56% carbon, 1.07% nitrogen, and 9.87 C/N ratio. For 4 months compost had 6.79% moisture content, 11.88% carbon, 0.91% nitrogen, and 13.05 C/N ratio. Nutrients content from both composts appropriate with the standard value of National Standarisation Body.

PENGARUH KONSENTRASI INHIBITOR EKSTRAK DAUN GAMBIR DENGAN PELARUT ETANOL-AIR TERHADAP LAJU KOROSI BESI PADA AIR LAUT Irianty, Rozanna Sri; Sembiring, Maria Peratenta
Jurnal Riset Kimia Vol 5, No 2 (2012): March
Publisher : Universitas Andalas

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.25077/jrk.v5i2.218

The important properties to overcome the corrosion are safe, available, biodegradable, low cost, and environmental friendly. Gambier leaves extract is one of the inhibitor that have environmental friendly properties. This study aims to determine the effectiveness of extract using ethanol-water to reduce the corrosion rate. Soaking of ferrous iron plate samples in seawater media have done for corrosion test. Agitator and aerator motors at turn-on and conducted a series of immersion with varying contact time 5, 10, 15, and 20 days. After the time up next ferrous iron plate samples were cleaned, dried, and weighed. Experiment was repeated by adding a inhibitor heavy leaves gambier extract with varying leaves gambier extract, 1000, 3000, and 5000 ppm. Soaking iron plate samples performed at varying pH at 3(acid), 6 (netral), and 9 (alkaline). Calculation is then performed and the rate of corrosion inhibition efficiency gambier leaves extract with ethanol-water solvent. On the immersion of iron plate without inhibitor, the result that the longer the contact time, the weight of the iron plate was reduced. The results showed the addition of inhibitors of leaves extract gambier with ethanol-water solvent into the corrosive media can reduce the rate of corrosion. Inhibitor of leaves extract gambier using ethanol-water solvent effective to reduce the rate of corrosion inhibitor at a concentration of 5000 ppm and contact time of 20 days with the lowest value of the corrosion rate is 0.000503 g/cm2 days in seawater media at initial pH 7.9. Gambier extracts gave greatest inhibition efficiency about 60.345% obtained at a concentration of 5000 ppm inhibitor and 20 days contact time.

ANALISA UNSUR HARA MIKRO DARI FLY ASH LIMBAH INDUSTRI PULP DAN KERTAS Maria Peratenta Sembiring; Chairul Chairul; Zulfansyah Zulfansyah
Jurnal Analis Laboratorium Medik Vol 6 No 1 (2021): JURNAL ANALIS LABORATORIUM MEDIK
Publisher : UNIVERSITAS SARI MUTIARA INDONESIA

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.51544/jalm.v6i1.1929

The pulp and paper industry continues to grow and produces large amounts of fly ash waste from the biomass combustion process. Alternative waste management besides landfills needs to be developed so that the use of fly ash can be ecologically and economically acceptable, such as for land applications in industrial plantations, especially on peat soils. This paper presents the results of the analysis of micro nutrients from fly ash from pulp and paper mill waste that can be used for agriculture and forestry. The elemental content of boron (B) and zinc (Zn) can be detected in fly ash samples both by lauryl amine extraction and stearyl amine extraction, where the optimum amount is obtained using 15 gram of fatty amine and n-hexane solvent with a processing time of 4 hours. Stearyl amine gives a higher yield than lauryl amine because it has a longer saturated carbon chain.

PEMBUATAN KOMPOS DARI LIMBAH PADAT (SLUDGE) PABRIK PULP DAN PAPER Maria Peratenta Sembiring; Rozanna Sri Irianty
Jurnal Riset Kimia Vol. 5 No. 2 (2012): March
Publisher : Universitas Andalas

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.25077/jrk.v5i2.213

One of the method to use pulp and paper mill sludge was convert it become a compost. This research result showed that time variation of compost have different physical and organic matter properties. In physical properties, 3 months of compost had 12.57% moisture content, while organic matter contain 10.56% carbon, 1.07% nitrogen, and 9.87 C/N ratio. For 4 months compost had 6.79% moisture content, 11.88% carbon, 0.91% nitrogen, and 13.05 C/N ratio. Nutrients content from both composts appropriate with the standard value of National Standarisation Body.

PENGARUH KONSENTRASI INHIBITOR EKSTRAK DAUN GAMBIR DENGAN PELARUT ETANOL-AIR TERHADAP LAJU KOROSI BESI PADA AIR LAUT Rozanna Sri Irianty; Maria Peratenta Sembiring
Jurnal Riset Kimia Vol. 5 No. 2 (2012): March
Publisher : Universitas Andalas

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.25077/jrk.v5i2.218

The important properties to overcome the corrosion are safe, available, biodegradable, low cost, and environmental friendly. Gambier leaves extract is one of the inhibitor that have environmental friendly properties. This study aims to determine the effectiveness of extract using ethanol-water to reduce the corrosion rate. Soaking of ferrous iron plate samples in seawater media have done for corrosion test. Agitator and aerator motors at turn-on and conducted a series of immersion with varying contact time 5, 10, 15, and 20 days. After the time up next ferrous iron plate samples were cleaned, dried, and weighed. Experiment was repeated by adding a inhibitor heavy leaves gambier extract with varying leaves gambier extract, 1000, 3000, and 5000 ppm. Soaking iron plate samples performed at varying pH at 3(acid), 6 (netral), and 9 (alkaline). Calculation is then performed and the rate of corrosion inhibition efficiency gambier leaves extract with ethanol-water solvent. On the immersion of iron plate without inhibitor, the result that the longer the contact time, the weight of the iron plate was reduced. The results showed the addition of inhibitors of leaves extract gambier with ethanol-water solvent into the corrosive media can reduce the rate of corrosion. Inhibitor of leaves extract gambier using ethanol-water solvent effective to reduce the rate of corrosion inhibitor at a concentration of 5000 ppm and contact time of 20 days with the lowest value of the corrosion rate is 0.000503 g/cm2 days in seawater media at initial pH 7.9. Gambier extracts gave greatest inhibition efficiency about 60.345% obtained at a concentration of 5000 ppm inhibitor and 20 days contact time.

Pembuatan Bioetanol Dari Nira Aren Secara Fermentasi Menggunakan Yeast Saccharomyces Cerevisiae Dengan Variasi Konsentrasi Inokulum Dan Waktu Fermentasi Elia Simanjuntak; Chairul Chairul; Maria Peratenta Sembiring
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 2, No 1 (2015): Wisuda Februari Tahun 2015
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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Bioethanol is one of the alternative energy source that can replace fossil energy sources. Bioethanol is biochemistry fluid from fermentation process of sugar by using microorganisms. One material which has potential as raw material for bioethanol production is a palm juice which is economically valuable products of the sugar plant. Palm juice is used as raw material for ethanol because it contains sugar which is large enough around 12.04%. This research aimed to produce bioethanol with various concentration of inoculum 10%, 12.5%, 15% and 17.5% and fermentation time 24, 48, 72 and 96 hours at pH optimum 5. The process of fermentation using Saccharomyces cerevisiae yeast. The sample analysed by using alcoholmeter. From the research results, obtained the highest ethanol concentration of 8% (v/v) at 17.5% inoculum concentration variation with fermentation time 72 hours.Keyword: Bioethanol, Fermentation, Palm Juice, Saccharomyces cerevisiae

Menentukan pH Optimum Di DO Stage Untuk Mengurangi Konsumsi CIO2 Pada Proses Pulp Bleaching Di PT. RAPP Winarto Tarigan; Chairul Chairul; Maria Peratenta Sembiring
Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains Vol 2, No 2 (2015): Wisuda Oktober Tahun 2015
Publisher : Jurnal Online Mahasiswa (JOM) Bidang Teknik dan Sains

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The process of bleaching is a chemical process that is used on chemically treated pulp and mechanical pulp aimed at increasing degrees of brightness according to the expected target. The purpose of the bleaching process are: increasing the brightness, maintaining brightness stability, removing dirt and unwanted components and maintain the physical strength of the pulp. Pulp bleaching process has several stages of the first delignification (D0), Extraction Peroxide (EP), and Last Delignification (D stage). There are few process variables having an effect on the bleaching process, one of which is pH. At first delignification process (D0) with the kappa factor 0.25, the process temperature about 75 oC for 1 hour, the expected optimum end pH is 3.5 to 4.0. In these conditions will produce pulp with 65.42% ISO brightness, and after going through the process of extraction Peroxide (EP) for 90 minutes will produce a pulp with a kappa number a low of 2.63. So after going through the process in Last Delignification (Dstage) will have the lowest consumption of chlorine dioxide. Overall pulp with a final pH Do stage 3.5 to 4.0 Chlorine dioxide is consumed as much as 133.6 ml. Keywords: pH, Bleaching, Chlorine Dioxide

EKSTRAKSI UNSUR FERRUM DARI LIMBAH PADAT PABRIK PULP DAN KERTAS Maria Peratenta Sembiring; Desi Heltina; Chairul Chairul; Zulfansyah Zulfansyah
JURNAL KIMIA SAINTEK DAN PENDIDIKAN Vol 6 No 1 (2022): JURNAL KIMIA SAINTEK DAN PENDIDIKAN
Publisher : Program Studi Kimia - Universitas Sari Mutiara Indonesia

Functioning industrial waste as raw material or as a product is an achievement that will continue to be optimized, especially in industries where the amount of waste is significant. Pulp and paper mills produce waste in the form of solid, sludge, liquid and gas. The objective of this research is to extract the element ferrum contained in one of the solid wastes in pulp and paper mills. By using two fatty amine extractor, lauryl amine and stearyl amine with ethanol and n-hexane as solvents. The results showed that the use of stearyl amine as an extractor and n-hexane as a solvent with operating conditions of 4 hours and a dose of 5 grams gave the best results with an extraction yield of 10,964 mg/kg.

ANALISA UNSUR HARA MIKRO DARI FLY ASH LIMBAH INDUSTRI PULP DAN KERTAS Maria Peratenta Sembiring; Chairul Chairul; Zulfansyah Zulfansyah
Jurnal Analis Laboratorium Medik Vol 6 No 1 (2021): JURNAL ANALIS LABORATORIUM MEDIK
Publisher : UNIVERSITAS SARI MUTIARA INDONESIA

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.51544/jalm.v6i1.1929

The pulp and paper industry continues to grow and produces large amounts of fly ash waste from the biomass combustion process. Alternative waste management besides landfills needs to be developed so that the use of fly ash can be ecologically and economically acceptable, such as for land applications in industrial plantations, especially on peat soils. This paper presents the results of the analysis of micro nutrients from fly ash from pulp and paper mill waste that can be used for agriculture and forestry. The elemental content of boron (B) and zinc (Zn) can be detected in fly ash samples both by lauryl amine extraction and stearyl amine extraction, where the optimum amount is obtained using 15 gram of fatty amine and n-hexane solvent with a processing time of 4 hours. Stearyl amine gives a higher yield than lauryl amine because it has a longer saturated carbon chain.

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