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NOOR HUBDRYAWATI
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Jurnal Kimia Mulawarman
Published by Universitas Mulawarman
ISSN : 16935616     EISSN : 24769258     DOI : DOI: https://doi.org/10.30872/jkm
Core Subject : Science,
Chemistry
Journal of Kimia Mulawarman is a peer-reviewed, open access journal that publishes original research articles, review articles, as well as short communication in all areas of chemistry, including educational chemistry and applied chemistry.
Arjuna Subject : Kimia(semua kategori) - Kimia (Lain-Lain)
Articles 202 Documents
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PEMANFAATAN ABU DAUN JAGUNG (Zea Mays) SEBAGAI SUMBER SILIKA PADA PEMBUATAN KATALIS Na/ SBA- 15 UNTUK REAKSI TRANSESTERIFIKASI MINYAK JELANTAH Drajat Bangun Utomo; R R Dirgarini Julia Nurlianti Subagyono; Rahmat GUnawan
JURNAL KIMIA MULAWARMAN Vol 16 No 1 (2018)
Publisher : Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30872/jkm.v16i1.621

Abstract

Preparation of Na / SBA-15 from corn leaves ash (Zea mays) as a substitute for TEOS (Tetraethyl Orthosilicate) applied as a heterogeneous catalyst in the transesterification reaction of used palm oil and methanol has been performed. The preparation of SBA-15 was conducted by surfactant template method and modification with Na was conducted by impregnation method. SBA-15 from corn leaves ash has a pore size ranging from 4.9 nm to 9.3 nm, a surface area of ​​595 m2/ g, a pore diameter of 3.95 nm and a pore volume of 0.99 cm3/ g. The yeild obtained from the first transesterification process was 96.46% with the free fatty acid content of the product 0.16 mg KOH/ g. The two most prominent methyl ester based on the chromatogram of the transesterification product, the two most prominent methyl ester in the product were methyl palmitate (36,32%) and methyl oleat (36,15%). Keywords : Maize, SBA-15, TEOS (Tetraethyl Orthosilicate), Transesterification of used palm oil
AKTIVITAS ANTIOKSIDAN SENYAWA FLAVONOID DARI Macaranga pearsonii Merr. Eva Marliana; Tjitjik Srie Tjahjandarie; Mulyadi Tanjung
JURNAL KIMIA MULAWARMAN Vol 13 No 2 (2016)
Publisher : Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman

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Abstract

Tiga senyawa flavanon , 4’-O-metil-8-isoprenileriodiktiol (1), 4’-O-metil-8-isoprenilnaringenin (2) and Lonkokarpol A (3) , telah diisolasi dari ekstrak metanol daun Macaranga pearsonii Merr. Elusidasi struktur senyawa berdasarkan data spektroskopi UV, 1D and 2D NMR, and HREISMS. Senyawa 1 – 3 ditentukan aktivitas antioksidannya terhadap peredaman radikal bebas 2,2-diphenyl-1-picrylhydrazyl (DPPH), dengan nilai IC50 adalah 536,89 μM, 1226,11 μM dan 426,43 μM.
STUDI DOCKING MOLEKULAR SENYAWA ASAM SINAMAT DAN DERIVATNYA SEBAGAI INHIBITOR PROTEIN 1J4X PADA SEL KANKER SERVIKS Susmi Ferwadi; Rahmat Gunawan; Winni Astuti
JURNAL KIMIA MULAWARMAN Vol 14 No 2 (2017)
Publisher : Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman

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Abstract

Molecular docking of cinnamate acid compound and its derivatives as protein 1J4X inhibitor to cervical cancer cell has been done. The result showed that the docking energies on mode 1 of inhibitor molecules are -5.7 kcal/mol for cinnamate acid, -6.0 kcal/mol for phenyl cinnamate, -4.7 kcal/mol for methyl cinnamate and -7.5 kcal/mol for 4-phenylchroman-2-on. The inhibitor molecules were interacted with the amino acids of the cervical cancer cell by forming hydrogen bondings. Cinnamate acid formed hydrogen bondings with amino acids of serine 124, glycine 127, tyrosine 128, serine 129 and arginine 130. Phenyl cinnamate formed hydrogen bonding with amino acid of serine 129. Methyl cinnamate formed hydrogen bonding with amino acid of serine 129. 4-phenylchroman-2-on formed hydrogen bondings with amino acids of serine 124, serine 129 and arginine 130. Cinnamate acid is more potential as anticancer drug than phenyl cinnamate, methyl cinnamate and 4-phenylchroman-2-on
ANALISIS KAFEIN DALAM KOPI ROBUSTA (TORAJA) DAN KOPI ARABIKA (JAWA) DENGAN VARIASI SIKLUS PADA SOKLETASI Tria Annisa Rizky; Chairul Saleh; Alimuddin -
JURNAL KIMIA MULAWARMAN Vol 13 No 1 (2015)
Publisher : Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman

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Abstract

The research about analysis of caffeine content on coffee Robusta (Toraja) and coffee Arabika (Jawa) with cycle variations using spectrophotometer UV has been done. Coffee extract obtained throughsoxhletation with ethanol 96 % and variation cycles used is 3, 6, 9, 12 and 15, tested with spectrophotometer UV at a wavelength of 272 nm. The result of this research was obtained the caffeine content in coffee Robusta (Toraja) for 3, 6, 9, 12, 15 cycles consecutive is 1.439 mg/L, 2.158 mg/L, 2.695 mg/L, 2.887 mg/L and 3.700 mg/L. The caffeine content obtained coffee Arabika (Jawa) for 3, 6, 9, 12, 15 cycles consecutive is 0.474 mg/L, 0.478 mg/L, 1.056 mg/L, 1.540 mg/L and 1.926 mg/L respectively.Keywords: Coffee Robusta, Coffee Arabika, Ethanol 96 %, Soxhletation, Caffeine, Spectrophotometer UV
ANALISIS TOTAL SULFUR TERHADAP SAMPEL FEED GAS DENGAN MEMBANDINGKAN STANDAR GAS DAN STANDAR LIQUID MENGGUNAKAN METODE TS-100V Eko Haryanto; Rahmat Gunawan; Chairul Saleh
JURNAL KIMIA MULAWARMAN Vol 12 No 1 (2014)
Publisher : Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman

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Abstract

The total sulfur analysis in the feed gas sample by using standard gas and liquid has been researched. The concentration of total sulfur obtained from a calibration curve by using standard gas or liquid by TS - 100V. Based on the analysis of measurement linearity, by making curve a linearity from a standard gas H 2 S was 0.999 and standard liquid dibutyl sulfide was 0.998, where both the standard curve can be as a calibration curve because each the value of the correlation coefficient (r) having worth >0.995. Based on the analysis of measurement precision namely repeatability by measuring a feed gas sample train G as many as 5 times been gained. RSD value was 4.17 in standard gas and 4.70 in standard liquid. Both the calibration curve has been accepted because the relative standard deviation values less than 0.67 from Horwitz and still into get allowed range values from 7.3 to 11%. Based on the analysis of accuracy’s measurement is percent recovery for the standard gas was 100.578% and for standard liquid was 104.380%. Both of them has been accepted because it still fit in the allowed range values 80-110%.Keywords : Total Sulfur, H 2 S Standard Gas, Standard Liquid Dibutyl Sulphites and TS-100V
PENGARUH KANDUNGAN ASAM LEMAK BEBAS (ALB) TERHADAP PERUBAHAN DENSITAS CRUDE PALM OIL (CPO) ALIYAH FAHMI
JURNAL KIMIA MULAWARMAN Vol 17 No 2 (2020)
Publisher : Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30872/jkm.v17i2.622

Abstract

Density are a physical parameter of Crude Palm Oil (CPO) quality determination which done by gravimetric method (weighing sample in a picnometer 50 mL, g/mL). Density is affected by the temperature. High temperature in CPO may cause the density become less by a little. But if we get them in lower temperature will make them in solid form and this situation is undesirable in trade industry. High temperature may cause hydrolysis reaction that add free fatty acid (FFA) content. The density changing was made with variation temperature (450C, 500C, 550C, 600C dan 650C) and FFA concentration (2%,3%,4%,5% and 6%). The result in this research was high concentration of FFA will make CPO density decreased with inreasing temperature. The linier relationship happened in same temperature (450C), the CPO density with free fatty acid content were 2%, 3%, 4%, 5% and 6% were ?= 0,8934; 0,8391; 0,8926; 0,8921 and 0,8920), so did the temperature at 500C, 550C, 600C dan 650C Keywords: Density, CPO, FFA, Temperature
PROFIL KIMIA ARTOCARPUS Erwin -
JURNAL KIMIA MULAWARMAN Vol 8 No 1 (2010)
Publisher : Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman

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Abstract

Artocarpus, one of the main genus of  Moraceae is known as a rich source of phenolic compounds especially prenylated flavonoids with a variety of structural types. From the literature review we obtained some phenolic compounds such as  calkon, flavane, flavone, Santon, stilben and Adduct Diels-Alder Type. Keywords: Artocarpus, phenolic, flavon
Uji Fitokimia, Toksisitas dan Aktivitas Antioksidan Fraksi n-heksan dan Etil Asetat terhadap Ekstrak Jahe Merah (Zingiber officinale var. amarum) Alpina Nora Kaban; Daniel Tarigan; Chairul Saleh
JURNAL KIMIA MULAWARMAN Vol 14 No 1 (2016)
Publisher : Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman

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Abstract

Has conducted research on the phytochemical test, toxicity test and test the antioxidant activity of the fraction of n-hexane and ethyl acetate to extract red ginger (Zingiber officinale amarum var.). The dried leaves weighing 382 grams, was macerated using methanol, filtered and concentrated by rotary evaporator. Then the total extract of red ginger in fractionation with n-hexane and ethyl acetate. Based on the test results of secondary metabolites phytochemical extracts of total red ginger (Zingiber officinale var amarum.) Are alkaloids, flavonoids, triterpenoids and phenolic. N-hexane fraction contains alkaloids, flavonoids, steroids, triterpenoids and phenolic. Ethyl acetate fractions contain alkaloids, flavonoids, triterpenoids and phenolic. Toxicity test showed the mortality rate of shrimp larvae Artemia salina Leach using Probit Analysis SAS (Statistical Analysis System) to determine the value of 50% Lethal Concentration (LC50), showed that the fraction of n-hexane toxicity with LC50 values of 63.8130 ppm; extracts of total was 71.0121 ppm and ethyl acetate was 3821.89 ppm. Test the antioxidant activity using DPPH free radical reduction in the spectrophotometer and IC50 values obtained on a total extract was 32.19 ppm; n-hexane was fraction 35.63 ppm; and ethyl acetate fraction was 25.69 ppm.
ANALISIS PERUBAHAN KADAR LOGAM TEMBAGA (Cu) PADA PENAMBAHAN ION PERAK (Ag) DENGAN METODE ELEKTROKOAGULASI Agustin Pratiwi; Bohari Yusuf; Rahmat Gunawan
JURNAL KIMIA MULAWARMAN Vol 13 No 1 (2015)
Publisher : Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman

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Abstract

The analysis of changes in levels of copper (Cu) on the addition of silver ions (Ag) with electrocoagulation method has been researched by using Atomic Absorption Spectrophotometer (AAS) as an instrument for the determination of levels. The addition of ionic silver (Ag) in a solution of copper (Cu) using varying concentrations of silver (Ag) 4, 6, 8, 10 and 12 ppm. The results showed that the effect of the addition of ionic silver (Ag) 4,6, 8, 10 and 12 resulted in changes in the levels of copper (Cu) are deposited successively in the ppm concentration is 9.375; 9.324; 9.272; 9.168; 9.142 and 9.116. Metalcontentof silver(Ag) in a medium containing copper (Cu) with a variety of metallic silver( Ag) differentat 4, 6, 8, 10 and 12ppm after the electrocoagulation metal contentof silver(Ag) depositedin the amount3.99; 5.99; 7.96; 9.91 and 11.88ppm.
UJI FITOKIMIA, TOKSISITAS DAN AKTIVITAS ANTIBAKTERI EKSTRAK BERBAGAI FRAKSI DAUN MARA (Macaranga tanarius (L.) M.A) TERHADAP BAKTERI Staphylococcus aureus dan Escherichia coli Ana Arum Sari; Chairul Saleh; Erwin -
JURNAL KIMIA MULAWARMAN Vol 12 No 2 (2015)
Publisher : Jurusan Kimia Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Mulawarman

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Abstract

Phytochemical, toxicity and antibacterial activity tests of total extract, fractions of n-heksana, ethyl acetate and ethanol-water from mara leaf (Macaranga tanarius (L.) M.A) from Samboja, East Kalimantan has been carried out. Based on the secondary metabolites phytochemical test of the (Macaranga tanarius (L.) M.A) leaf show that total extract is contain alkaloid, flavonoid, phenolic and steroid. n-hexane fraction is contain alkaloid, flavonoid and steroid. Ethyl acetate fraction is contain phenolic and triterpenoid. Ethanol-water fraction is contain alkaloid and phenolic. Brine shrimp lethality test values obtained Lethal Concentration 50 % (LC50) total extract 23.99 ppm , n-heksana fraction 13,93 ppm, ethyl acetate fraction 468,25 ppm and ethanol-water fraction 283,67 ppm. Antibacteria activity test of extracts for Staphylococcus aureus bacteria (positive Gram) and Escherichia coli (negative Gram) was carried out by paper disc method. The test showed that the most active were ethyl acetate fraction with minimum inhibitor consentration of 0,125- 0,5 % (b/v) which clear zone diameter was 7,25 mm on Staphylococcus aureus bacteria and 6,25 mm on Escherichia coli bacteria.

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