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DESAIN ADSORBER MENGGUNAKAN BAHAN ISIAN RESIN PENUKAR ANION BASA KUAT UNTUK PEMURNIAN BIOGAS Muntari, Anies; ., Wiratni; Mindaryani, Aswati; ., Surasno
Jurnal Riset Industri Vol 7, No 2 (2013): Pengembangan Energi Baru dan Terbarukan Mendukung Ketahanan Energi Nasional
Publisher : Badan Penelitian dan Pengembangan Industri

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (9103.775 KB)

Biogas sebagai sumber energi terbarukan mempunyai kandungan metana (CH4) Â sekitar 50-75% sebagai bahan bakar utama. Untuk dapat menggunakan biogas sebagai sumber energi yang lebih luas perlu dilakukan proses pemurnian biogas dari Â pengotornya seperti CO2.Â Â Perancangan alat pemurnian biogas skala pilot plant telah dilakukan berdasarkan data-data percobaan laboratorium. Oesain alat yang dirancang beroperasi pada tekanan atmosferis dan suhu lingkungan dengan kapasitas 75 Liter resin dan laju alir gas 0,8 L/menit.Â Â Bahan isian adsorber yang digunakan adalah resin berjenis penukar anion basa kuat dan air dengan perbandigan 3: 1. Oimensi alat adsorber yang dirancang yaitu, tinggi 1350 mm dan diameter Â 254 mm. Hasil unjuk kerja alat skala pilot plant yang telah dilakukan menunjukkan bahwa C02 mampu utuk dihilangkan hingga 100% dalam waktu 15 menit. Setelah 15 menit resin harus diregenarasi menggunakan larutan NaCI 2% untuk mengembalikan unjuk kerja resin seperti sedia kala. Hasil analisa ekonomi terhadap keberlangsungan proses tersebut memberikan hasil ROI 24,91%, Â POT 2,86 tahun, OCFRR 31,12%, BEP 42,29% dan SOP 26,50%. Â Hasil analisis parameterÂ parameter ekonomi tersebut menunjukkan bahwa proses ini layak untuk dijalankan.

DESAIN ADSORBER MENGGUNAKAN BAHAN ISIAN RESIN PENUKAR ANION BASA KUAT UNTUK PEMURNIAN BIOGAS Muntari, Anies; ., Wiratni; Mindaryani, Aswati; ., Surasno
Jurnal Riset Industri Vol 7, No 2 (2013): Pengembangan Energi Baru dan Terbarukan Mendukung Ketahanan Energi Nasional
Publisher : Badan Penelitian dan Pengembangan Industri

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (9103.775 KB)

Biogas sebagai sumber energi terbarukan mempunyai kandungan metana (CH4) Â sekitar 50-75% sebagai bahan bakar utama. Untuk dapat menggunakan biogas sebagai sumber energi yang lebih luas perlu dilakukan proses pemurnian biogas dari Â pengotornya seperti CO2.Â Â Perancangan alat pemurnian biogas skala pilot plant telah dilakukan berdasarkan data-data percobaan laboratorium. Oesain alat yang dirancang beroperasi pada tekanan atmosferis dan suhu lingkungan dengan kapasitas 75 Liter resin dan laju alir gas 0,8 L/menit.Â Â Bahan isian adsorber yang digunakan adalah resin berjenis penukar anion basa kuat dan air dengan perbandigan 3: 1. Oimensi alat adsorber yang dirancang yaitu, tinggi 1350 mm dan diameter Â 254 mm. Hasil unjuk kerja alat skala pilot plant yang telah dilakukan menunjukkan bahwa C02 mampu utuk dihilangkan hingga 100% dalam waktu 15 menit. Setelah 15 menit resin harus diregenarasi menggunakan larutan NaCI 2% untuk mengembalikan unjuk kerja resin seperti sedia kala. Hasil analisa ekonomi terhadap keberlangsungan proses tersebut memberikan hasil ROI 24,91%, Â POT 2,86 tahun, OCFRR 31,12%, BEP 42,29% dan SOP 26,50%. Â Hasil analisis parameterÂ parameter ekonomi tersebut menunjukkan bahwa proses ini layak untuk dijalankan.

EVALUATION OF THE EFFECT OF OPERATING PARAMETERS ON THE PERFORMANCE OF ORIFICE/POROUS PIPE TYPE MICRO-BUBBLE GENERATOR Pambudiarto, Benny Arif; Mindaryani, Aswati; Deendarlianto, D.; Budhijanto, Wiratni
Journal of Engineering and Technological Sciences Vol 52, No 2 (2020)
Publisher : Institute for Research and Community Services, Institut Teknologi Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/j.eng.technol.sci.2020.52.2.5

The micro-bubble generator (MBG) is a novel aeration technology utilizing the concept of fluid flow through an orifice, where air is sucked into the internal chamber of the MBG by the pressure difference created by the orifice and immediately pushed by the high-velocity flow of the fluid. This mechanism creates micro-size bubbles with a high dissolution rate. This study focused on studying the effect on the oxygen dissolution rate of the two most important operating parameters, i.e. the volumetric flow rate of the liquid (QL) and the volumetric flow rate of the air (QG). Various combinations of values for QL and QG were systematically compared by means of the oxygen mass transfer coefficient (kLa). The experiment was carried out in a transparent container of 2.8 m x 0.6 m x 0.4 m filled with tap water that was aerated using an orifice/porous-pipe type MBG. The dissolved oxygen (DO) values were measured at distances of 60 cm, 120 cm, and 180 cm from the MBG outlet. The experiment was designed with five different values for QL and QG respectively. The results showed that the value of kLa, which is proportional to the oxygen dissolution rate, increased asymptotically with increasing QL value, while the QG values did not significantly affect the kLa value.

Evaluation of the Effect of Operating Parameters on the Performance of Orifice/Porous Pipe Type Micro-bubble Generator Benny Arif Pambudiarto; Aswati Mindaryani; D. Deendarlianto; Wiratni Budhijanto
Journal of Engineering and Technological Sciences Vol. 52 No. 2 (2020)
Publisher : Institute for Research and Community Services, Institut Teknologi Bandung

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.5614/j.eng.technol.sci.2020.52.2.5

The micro-bubble generator (MBG) is a novel aeration technology utilizing the concept of fluid flow through an orifice, where air is sucked into the internal chamber of the MBG by the pressure difference created by the orifice and immediately pushed by the high-velocity flow of the fluid. This mechanism creates micro-size bubbles with a high dissolution rate. This study focused on studying the effect on the oxygen dissolution rate of the two most important operating parameters, i.e. the volumetric flow rate of the liquid (QL) and the volumetric flow rate of the air (QG). Various combinations of values for QL and QG were systematically compared by means of the oxygen mass transfer coefficient (kLa). The experiment was carried out in a transparent container of 2.8 m x 0.6 m x 0.4 m filled with tap water that was aerated using an orifice/porous-pipe type MBG. The dissolved oxygen (DO) values were measured at distances of 60 cm, 120 cm, and 180 cm from the MBG outlet. The experiment was designed with five different values for QL and QG respectively. The results showed that the value of kLa, which is proportional to the oxygen dissolution rate, increased asymptotically with increasing QL value, while the QG values did not significantly affect the kLa value.

Laju Reaksi Hidrolisis Herbisida Glifosat di Tanah Jenuh Air Edia Rahayuningsih; Aswati Mindaryani; Mukti Mukti; Bostang Radjagukguk
Forum Teknik Vol 30, No 2 (2006)
Publisher : Faculty of Engineering, Universitas Gadjah Mada

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The objectives of the research were to find out the parameters of the hydrolysis reaction rate (k,,) and partition coefficien (Kr) of glyphosate herbicide in saturated soil system, to identify the variables affecting those parameters, and to develop the empirical equations corelating those parameters to the pertinent variables.The experimental work or physical simulation in laboratory was conducted in a batch reactor. The sterilized soil 5 gram put into a 1000 cm3 of Erlenmeyer glass and 500 cm3 of glyphosate solution with 8 g/1 concentration was added. The Erlenmeyer mouth was covered with plastic film and the entire Erlenmeyer surface was covered with aluminium foil to minimize vaporization and photolysis reaction. The solution was mixed continuously with magnetic stirrer. At the initial time and selected time intervals, 5 cm3 of the samples were taken with syringe. The samples were centrifuged and filtered, 1 cm3 of the filtrate were analyzed its glyphosate concentration with UV- VIS. The experiments were conducted for various soil types, and the empirical correlation between the hydrolysis reaction rate (k,,) and partition coefficien (Kr) with the affecting variables can be developed.Based on the laboratory data and the simulation of mathematical model, it could be concluded that the empirical correlation between the Kr and kh values with the affecting variables could be represented in the equations:Kr =11.035 (%organic matter) + 0.25 (%clay mineral) mL gramkh =1.0810 (%organic matter) + 1.5310-5 (%clay mineral) min-1

Adsorpsi Air dari Campuran Uap Etanol-Air dengan Zeolit Sintetis 4A dalam Packed Bed dalam Rangka Produksi Fuel Grade Ethanol Handrian Handrian; Wahyudi Budi Sediawan; Aswati Mindaryani
Jurnal Rekayasa Proses Vol 11, No 2 (2017)
Publisher : Departemen Teknik Kimia Fakultas Teknik Universitas Gadjah Mada

Ethanol can be used as fuel if it has a purity of 99.5%, while ethanol distillation will stop at its azeotrop point, ie at 95.6%. Adsorption of molecular sieve is one of the methods to obtain ethanol with level above the azeotropic point. Adsorbent that serves as molecular sieve is synthetic zeolite 4A. The adsorbent has a pore diameter of 3.9 Ǻ, then water and ethanol each has a molecular diameter of 2.75 Ǻ and 4.4 Ǻ. Hence the adsorbent is selective against the ethanol-water mixture. The purpose of this research is to obtain ethanol above its azeotropic point and to study the relationship between the influence of flow rate (Vz) and temperature (T) to changes in the number of mass transfer coefficient (kc), radial diffusivity (Der) and henry constants (H') which can be used as parameters in the design of adsorption tools on a commercial scale.This experiment was conducting by weighing zeolite 4A as much as 100 grams, then compiled and measured the height on packed bed column adsorbent. The heating regulator is switched on and set to a constant temperature of 80, 85, 90, 95 and 100 0C. Ethanol 95.61% with 250 ml volume is put into three-neck flask, then heat to evaporate. Turn on the cooling back and adjust the amount of formed vapor rate by adjusting the faucet opening and the degree of voltage in the heating mantle. The magnitude of the vapor flow rate is set at 2, 4 and 6 liters / minute. The products is accomodated and samples were taken every minute to analyze the ethanol content.This adsorption process gives the highest yield of ethanol with 99.40% content. The steam flow rate of 2 lpm and the temperature of 800C is the optimum combination in this research because much of the water vapor adsorbed on the 4A zeolite grain is 7.93 grams. The numerical calculation provides the result that the value of Der in this experiment is 1.59.10-3 cm2 / men, and the relation of kc are the function of reynolds and H' the function of temperature are as follows: kc = 7,95.10^-3.(Re)^0,1639 and H' = 4,47.10^-3.exp(2565,26/T) ABSTRAKEtanol dapat digunakan sebagai bahan bakar jika memiliki kemurnian 99,5%, sedangkan dislitasi etanol akan terhenti pada titik azeotropnya, yaitu pada 95,6%. Adsorpsi molecular sieve adalah salah satu metode untuk memperoleh etanol dengan kadar diatas titik azeotrop. Adsorbent yang berfungsi sebagai molecular sieve adalah zeolit sintetis 4A. Adsorbent ini memiliki diameter pori sebesar 3,9 Ǻ, lalu air dan etanol masing-masing memiliki diameter molekul 2,75 Ǻ dan 4,4 Ǻ. Maka dari itu adsorbent bersifat selektif terhadap campuran etanol-air. Penelitian ini bertujuan untuk memperoleh etanol diatas titik azeotropnya serta mempelajari hubungan pengaruh laju alir (vz) dan suhu (T) terhadap perubahan harga koefisien transfer massa (kc), difusivitas radial (Der) dan konstanta henry (H’) yang bisa digunakan sebagai parameter dalam perancangan alat adsorpsi pada skala komersial. Percobaan ini dilakukan dengan cara menimbang zeolit 4A sebanyak 100 gram, lalu disusun dan diukur tingginya pada packed bed columnadsorbent. Regulator pemanas dinyalakan dan diatur suhunya sampai konstan pada 80, 85, 90, 95 dan 1000C. Etanol 95,61% dengan volum 250 ml dimasukkan ke labu leher tiga, lalu dipanaskan sampai menguap. Pendingin balik dinyalakan dan diatur besarnya laju uap yang terbentuk dengan mengatur bukaan kran dan derajat voltase pada heating mantle. Besarnya laju aliran uap diatur pada 2, 4 dan 6 liter/menit. Produk ditampung dan diambil tiap menit sebagai sampel untuk dianalisis kadar etanolnya. Proses adsorpsi ini memberikan hasil tertinggi berupa etanol dengan kadar 99,40%. Laju alir uap 2 lpm dan suhu 800C adalah kombinasi yang optimal dalam penelitian ini karena banyak uap air yang teradsorpsi pada butir zeolit 4A yaitu 7,93 gram. Perhitungan secara numeris memberikan hasil bahwa nilai Der pada percobaan ini adalah 1,59.10-3 cm2/men, serta hubungan kc fungsi reynolds dan H’ fungsi suhu berturut-turut adalah sebagai berikut:kc=7,95.10-3..vz.D0,1639dan H'=4,47.10-3.e2565,26T

PREPARASI KARBON TEREMBAN OKSIDA COBALT DARI LIMBAH KULIT MANGGIS SEBAGAI ADSORBEN PENJERAP ETILEN UNTUK PENGAWETAN BUAH Nur Indah Fajar Mukti; Imam Prasetyo; Aswati Mindaryani
Reaktor Volume 15 No.3 April 2015
Publisher : Dept. of Chemical Engineering, Diponegoro University

Ethylene is a compound produced naturally by fruit that can accelerate the maturity of the fruit. Controlling ethylene gas as a product of metabolism of fruit during storage will prolong the shelf life of the fruit. Controlling ethylene gas is carried out by adsorption process using carbon-impregnated cobalt oxide. In this study, carbon as a support made by pyrolysis of extraction waste of mangosteen peel at a temperature of 850°C for 15 minutes. Furthermore, the process of impregnating of cobalt oxide into the carbon pore network was carried out by using the incipient wetness impregnation method by adding a cobalt salt solution into the carbon pore network, followed by heating at a temperature of 110oC for 8 hours and calcination at a temperature of 200oC for 6 hours. Ethylene adsorption test performed at 30°C using a static volumetric test. While Cavendish banana fruit preservation process was carried out at ambient temperature (20-32oC) by observing the changing of skin color from day to day. Adsorption test results showed that the ethylene uptake increased with the increasing of the composition of cobalt oxide on the carbon surface. The highest ethylene uptake of 6.094 mmol/(gram of adsorbent) was obtained from adsorption of ethylene using carbon-impregnated 30% cobalt oxide. Fruit preservation process indicated that the increasing of amount of adsorbent can improve the shelf life of bananas Cavendish. The highest result was obtained from the addition of 15 grams of carbon-impregnated cobalt oxide and silica gel that can extend the shelf life of bananas Cavendish for 15 days. Keywords: adsorption; carbon; cobalt oxide; ethylene; impregnation Abstrak Etilen merupakan senyawa yang dihasilkan secara alami oleh buah yang dapat mempercepat kematangan pada buah. Pengontrolan gas etilen sebagai produk metabolisme buah selama penyimpanan akan memperpanjang masa simpan buah tersebut. Pengontrolan gas etilen dilakukan dengan proses adsorpsi menggunakan karbon teremban oksida cobalt. Pada penelitian ini, karbon sebagai pengemban dibuat dari pirolisis limbah kulit manggis sisa ekstraksi pada suhu 850oC selama 15 menit. Selanjutnya, proses pengembanan oksida cobalt pada permukaan karbon dibuat melalui proses impregnasi dengan incipient wetness method yang dilakukan dengan menambahkan larutan garam cobalt ke dalam jaringan pori karbon yang dilanjutkan dengan pemanasan pada suhu 110oC selama 8 jam dan kalsinasi pada suhu 200oC selama 6 jam. Uji adsorpsi etilen dilakukan pada suhu 30oC menggunakan alat uji static volumetric. Sedangkan proses pengawetan buah pisang Cavendish dilakukan pada suhu lingkungan (20 – 32oC) dengan mengamati perubahan warna kulitnya dari hari ke hari. Hasil uji adsorpsi menunjukkan bahwa semakin banyak komposisi oksida cobalt pada permukaan karbon akan meningkatkan kapasitas penjerapan terhadap etilen. Hasil tertinggi sebesar 6,094 mmol/(gram adsorben) diperoleh dari adsorpsi etilen menggunakan karbon teremban 30% oksida cobalt. Dari proses pengawetan buah menunjukkan bahwa jumlah karbon teremban oksida cobalt yang semakin meningkat dapat meningkatkan umur simpan dari buah pisang Cavendish. Hasil tertinggi diperoleh dari penambahan 15 gram karbon teremban cobalt dan silica gel dapat memperpanjang umur simpan buah pisang Cavendish selama 15 hari. Kata kunci: adsorpsi; karbon; oksida cobalt; etilen; impregnasi

Pemodelan Matematis Dan Penyelesaian Numeris Pada Absorpsi CO2 Dalam Biogas Menggunakan Kolom Bahan Isian Dengan Larutan Methyldiethanolamine (MDEA) Sari Sekar Ningrum; Aswati Mindaryani; Muslikhin Hidayat; Syafrima Wahyu
Jurnal Teknologi Vol 7, No 1 (2019): Jurnal Teknologi
Publisher : Universitas Jayabaya

Biogas merupakan energi terbarukan yang dikembangkan untuk mensubtitusi energi yang berasal dari fosil. Keberadaan CO2 yang tinggi dapat menghambat efisiensi biogas. Oleh sebab itu, dibutuhkan pemurnian biogas dengan melakukan pengurangan kadar CO2 pada biogas. Pengurangan kadar CO2 pada biogas dapat dilakukan dengan cara absorpsi menggunakan MDEA pada kolom bahan isian. Percobaan absorpsi CO2 dilakukan secara kontinyu di dalam kolom absorpsi dengan diameter 6 cm dan panjang 75 cm, bahan isian berupa spiral tembaga dan laju alir cairan 0,15 L/menit. Variasi laju alir gas yang digunakan pada penelitian ini adalah 1 LPM, 1,5 LPM dan 1,8 LPM. Variasi larutan MDEA yang digunakan adalah 20 % dan 35,31 %. Konsentrasi gas CO2 yang keluar dari bagian atas kolom dicatat sebagai fungsi waktu. Data yang diperoleh dimasukkan ke dalam model matematis sehingga kemudian diperoleh nilai KGa dan k2. Pada laju alir gas 1 L/menit; 1,5 L/menit dan 1,8 L/menit dengan konsentrasi MDEA 20% berat diperoleh koefisien transfer massa gas (KGa) kisaran 0,0170 mol/min.atm.L hingga 0,0210 mol/min.atm.L dan konstanta kecepatan reaksi sebesar 450 L/mol.min sedangkan pada konsetrasi MDEA 35,35% berat diperoleh koefisien transfer massa gas (KGa) kisaran 0,0190 mol/min.atm.L hingga 0,0215 mol/min.atm.L dan konstanta kecepatan reaksi sebesar 450 L/mol.min.

Adsorpsi Air dari Campuran Uap Etanol-Air dengan Zeolit Sintetis 4A dalam Packed Bed dalam Rangka Produksi Fuel Grade Ethanol Handrian Handrian; Wahyudi Budi Sediawan; Aswati Mindaryani
Jurnal Rekayasa Proses Vol 11, No 2 (2017)
Publisher : Departemen Teknik Kimia Fakultas Teknik Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/jrekpros.30344

Ethanol can be used as fuel if it has a purity of 99.5%, while ethanol distillation will stop at its azeotrop point, ie at 95.6%. Adsorption of molecular sieve is one of the methods to obtain ethanol with level above the azeotropic point. Adsorbent that serves as molecular sieve is synthetic zeolite 4A. The adsorbent has a pore diameter of 3.9 Ǻ, then water and ethanol each has a molecular diameter of 2.75 Ǻ and 4.4 Ǻ. Hence the adsorbent is selective against the ethanol-water mixture. The purpose of this research is to obtain ethanol above its azeotropic point and to study the relationship between the influence of flow rate (Vz) and temperature (T) to changes in the number of mass transfer coefficient (kc), radial diffusivity (Der) and henry constants (H') which can be used as parameters in the design of adsorption tools on a commercial scale.This experiment was conducting by weighing zeolite 4A as much as 100 grams, then compiled and measured the height on packed bed column adsorbent. The heating regulator is switched on and set to a constant temperature of 80, 85, 90, 95 and 100 0C. Ethanol 95.61% with 250 ml volume is put into three-neck flask, then heat to evaporate. Turn on the cooling back and adjust the amount of formed vapor rate by adjusting the faucet opening and the degree of voltage in the heating mantle. The magnitude of the vapor flow rate is set at 2, 4 and 6 liters / minute. The products is accomodated and samples were taken every minute to analyze the ethanol content.This adsorption process gives the highest yield of ethanol with 99.40% content. The steam flow rate of 2 lpm and the temperature of 800C is the optimum combination in this research because much of the water vapor adsorbed on the 4A zeolite grain is 7.93 grams. The numerical calculation provides the result that the value of Der in this experiment is 1.59.10-3 cm2 / men, and the relation of kc are the function of reynolds and H' the function of temperature are as follows: kc = 7,95.10^-3.(Re)^0,1639 and H' = 4,47.10^-3.exp(2565,26/T) ABSTRAKEtanol dapat digunakan sebagai bahan bakar jika memiliki kemurnian 99,5%, sedangkan dislitasi etanol akan terhenti pada titik azeotropnya, yaitu pada 95,6%. Adsorpsi molecular sieve adalah salah satu metode untuk memperoleh etanol dengan kadar diatas titik azeotrop. Adsorbent yang berfungsi sebagai molecular sieve adalah zeolit sintetis 4A. Adsorbent ini memiliki diameter pori sebesar 3,9 Ǻ, lalu air dan etanol masing-masing memiliki diameter molekul 2,75 Ǻ dan 4,4 Ǻ. Maka dari itu adsorbent bersifat selektif terhadap campuran etanol-air. Penelitian ini bertujuan untuk memperoleh etanol diatas titik azeotropnya serta mempelajari hubungan pengaruh laju alir (vz) dan suhu (T) terhadap perubahan harga koefisien transfer massa (kc), difusivitas radial (Der) dan konstanta henry (H’) yang bisa digunakan sebagai parameter dalam perancangan alat adsorpsi pada skala komersial. Percobaan ini dilakukan dengan cara menimbang zeolit 4A sebanyak 100 gram, lalu disusun dan diukur tingginya pada packed bed columnadsorbent. Regulator pemanas dinyalakan dan diatur suhunya sampai konstan pada 80, 85, 90, 95 dan 1000C. Etanol 95,61% dengan volum 250 ml dimasukkan ke labu leher tiga, lalu dipanaskan sampai menguap. Pendingin balik dinyalakan dan diatur besarnya laju uap yang terbentuk dengan mengatur bukaan kran dan derajat voltase pada heating mantle. Besarnya laju aliran uap diatur pada 2, 4 dan 6 liter/menit. Produk ditampung dan diambil tiap menit sebagai sampel untuk dianalisis kadar etanolnya. Proses adsorpsi ini memberikan hasil tertinggi berupa etanol dengan kadar 99,40%. Laju alir uap 2 lpm dan suhu 800C adalah kombinasi yang optimal dalam penelitian ini karena banyak uap air yang teradsorpsi pada butir zeolit 4A yaitu 7,93 gram. Perhitungan secara numeris memberikan hasil bahwa nilai Der pada percobaan ini adalah 1,59.10-3 cm2/men, serta hubungan kc fungsi reynolds dan H’ fungsi suhu berturut-turut adalah sebagai berikut:kc=7,95.10-3..vz.D0,1639dan H'=4,47.10-3.e2565,26T

Surface Modification of Multi-Walled Carbon Nanotubes with Polysaccharides Francisca Larasati; Yuni Kusumastuti; Aswati Mindaryani; Rochmadi Rochmadi; Murni Handayani
ASEAN Journal of Chemical Engineering Vol 22, No 1 (2022)
Publisher : Department of Chemical Engineering, Universitas Gadjah Mada

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.22146/ajche.69866

Multi-walled carbon nanotubes (MWCNTs) are known as efficient drug carriers. To improve their interaction with other materials, surface modification of MWCNTs is necessary. In this work, MWCNTs were functionalized with acid and polysaccharides (chitosan and gelatin). The functionalization process was done via modification with acid solutions of nitric acid, sulfuric acid, and a mixture of nitric acid-sulfuric acid first, followed by functionalization with chitosan and gelatin. To achieve the optimum condition of MWCNTs functionalization, the reaction time, temperature, and acid ratio were varied. Furthermore, the effect of chitosan and gelatin addition into MWCNTs was studied at various mass ratios. The synthesized materials were characterized by Fourier transform infrared spectrophotometer, Boehm titration, and dispersion test. The Boehm titration results showed that the acid functional groups had been attached successfully to MWCNTs surface. The amount of acid functional groups increased along with reaction time. The highest amount of acidic group obtained from the data was 2.33 mmol/g. It was achieved when MWCNTs reacted with nitric acid for 24 hours. Temperature and acid ratio variations on the MWCNTs functionalization did not provide significant results. From the FTIR data, sharp peaks at 3480 cm-1 and 1040 cm-1 indicates a -CONH bond, which shows that chitosan and gelatin have been successfully grafted onto MWCNTs surface via an amide linkage. Moreover, the dispersion test showed that the functionalized materials were stable for 48 hours.

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