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All Journal CHEMISTRY PROGRESS Jurnal Matematika & Sains MAJALAH BIAM Indonesian Journal of Chemistry Biosel: Biologi Science and Education Chemistry Indonesian Journal of Chemical Research Molekul: Jurnal Ilmiah Kimia Fullerene Journal of Chemistry Molluca Journal of Chemistry Education (MJoCE) Biofaal Journal
Yusthinus T. Male
Patimura University
Agriculture, Biological Sciences & Forestry Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Education Energy Engineering Environmental Science Materials Science & Nanotechnology Mathematics Medicine & Pharmacology

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Analisis Kadar Logam Kadmium (Cd) dan Timbal (Pb) pada Sedimen Di Teluk Ambon Bagian Dalam Yusthinus T Male; Dominggus Malle; Catherina Manukpadang Bijang; Eirene Grace Fransina; Cecelia Anna Seumahu; Lois Mikhal Dolaitery; Sartika Landu; Nelson Gaspersz
Indonesian Journal of Chemical Research Vol 5 No 1 (2017): Edisi Bulan Juli (Edition For July)
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598//ijcr.2017.5-yus

Abstract

The research about analysis of cadmium (Cd) and lead (Pb) metal content on sediment inner part of Ambon Bay has been done. Sampling point located at Dermaga Ferry Poka, PLTD Poka, Kate-kate, Waiheru, Lateri III, Passo dan PLTD Galala. The results of analyzed of sediment particle size inside the Ambon Bay showed 3 components were sand, gravel, and sludge, but the sediments was dominated by sludge sand. Analysis of Cd content showed that at 7 stations in Ambon Bay detected Cd metal with the highest concentration at 4th station of Waiheru village was 0,6640 mg/Kg and the lowest concentration at 3th station of Kate-kate village was 0,0980 mg/Kg. Meanwhile, the highest Pb content was 20,075 mg/kg at 4th station and the lowest was 5,755 mg/kg at 2nd station of PLN Poka. The content of elements composition of sediment are SiO2, K2O, P2O5, Fe2, BaO, NiO and Ga2O3 but Cd and Pb metal was not detected.
Analysis of Mercury (Hg) Distribution In The Waeapo River Irrigation Area, Buru Regency, Maluku Province, Gold Mining Without Permission Result In Botak Mountain Area Febrian M. Salatutin; Chudeya Y. Batawi; Camellia Y. Lessil; Yusthinus T Male
Indonesian Journal of Chemical Research Vol 3 No 1 (2015): Edisi Bulan Juli (Edition For July)
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

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Abstract

The Waeapo River has 13 watersheds, which are irrigated area for thousand hectare of rice field in the District of Buru. Buru District is one of the area that can supply thousands of tons of rice. But, yields to be reduced by the presence of gold mining activities in the Botak Mountain. Gold mining activities not only impact for the decline in yields, but also impact on the quality of rice by mercury pollution generated by mining waste. This research aims to determine the accumulation of mercury in sediment of Waeapo river. The research method is used survey and analysis method. In this research, observations were done and field sampling with the laboratory analyze. The result showed that concentration of analyzed mercury at four point, one point has exceeded standard of mercury limits in the sediment, i.e 0.1 ppm
Computational Study Natural Color Essence (Dyes) As Active Material On Organic Solar Cell With Density Functional Theory (DFT) Yusthinus T Male; I Wayan Sutapa; Olivia M. Ranglalin
Indonesian Journal of Chemical Research Vol 2 No 2 (2015): Edisi Bulan Januari (Edition For January)
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

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Abstract

Computational calculation has been done for anthocyanin, tocoferol and they derivatives. The computational calculation was conduct to know the compound potential of anthocyanin, tocoferol and they derivatives as active material on organic solar cell. Computational calculation was done by used Gaussian 03 for windows with ab inito alternative electron structure theory namely Density Functional Theory (DFT) with B3LYP method at basis set 6-31G (d). Computational calculation obtains that the structure of anthocyanin, tocoferol and they derivatives were symmetrical. There were two compounds of anthocyanin (A1 and A5) and two compounds of tocoferol (T3 and T4) which more stable than the others compounds. The compounds had lowest energy gap were consist of A1= 0.12629 eV, A5= 0.12570 eV, T3= 0.19334 eV and T4= 0.19231 eV. The moment dipole from compound of anthocyanin, tocoferol and they derivatives had highest value, they were A1 and T1 while the total energy had lowest value they A2 and T1. The Substituent methoxy and hydroxy were added the density load of C atom was substituted so it would increase the activity of the phenyl ring on anthocyanin and they derivatives, while substituent methyl and hydroxy were added the density load of C atom was substituted so it was increase the activity of the phenyl ring on tocoferol and they derivatives. For compounds of anthocyanin main orbital populations showed that there were load transfer only from middle chain (ether) and compounds of tocoferol main orbital populations showed that there was load transfer only from phenyl ring. The method of density functional B3LYP/6-31G(d) would be applied to structure prediction and electronic characteristic of anthocyanin, tocoferol compounds and they derivatives before synthetic.
Introduction Analysis Of Several Levels Of The Mercury (Hg) In Shells Yusthinus T Male; Alberth Ch. Nanlohy; Asriningsih Asriningsih
Indonesian Journal of Chemical Research Vol 2 No 1 (2014): Edisi Bulan Juli (Edition For July)
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

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Abstract

Water pollution by metallic mercury (Hg) in Buru island as a result of mining activity people are very dangerous for marine life, firstly for Mollusca that was consumed by local communities. Therefore, it is needed to measure the levels of pollution Hg of shells. The research has been done on several types of shells, taken at several different points, those are: at the Namlea market, Arumbae market, and Latuhalat beach. The research’s method used Cold Vapour Atomic Absorption Spectrophotometry (CV-AAS). The results obtained by the concentration of metals Hg in Polla shells (Telebraria sulcata) 0.19240 mg/kg; Manis shells (Ruditapes variegatus) 0.27171 mg/kg; Ciput shells (Nerita polita) 0.31387 mg/kg; Keong shells (Thais aculeata) 0.05556 mg/kg; Tudung shells (Cellana radiata) 0.05922 mg/kg and Bapaco shells (Telescopium telescopium) 0.00183 mg/kg. Based on the results of this research, the mercury (Hg) concentrations of several types of shells which contain levels of Hg that low enough and has not exceeded the threshold set by WHO as big as 0.5 mg/kg. Even that there was small concentrations of metals, it can be acumulated in human’s body and can be fatal to the health of humans who consume shells.
Analisys Of Lead (Pb) And Chromium (Cr) Content In The Roots Of Seagrass (Enhalus Acoroides) In Waters Of Waai And Tulehu Village Central Maluku Regency Yusthinus T Male; Sunarti Sunarti; Neti Nunumete
Indonesian Journal of Chemical Research Vol 1 No 2 (2014): Edisi Bulan Januari (Edition For January)
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

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Abstract

The research has been done with the aim to determine the content of heavy metals Pb and Cr on the roots of seagrasses (Enhalus acoroides) by using Spektrofotometry Atomic Absorption (SSA). Samples have been taken from the waters of Waai and Tulehu village. The result show that the content of Pb on the roots of seagrasses in the waters of Waai village and Tulehu village is 26,262 mg/Kg; 18,491mg/Kg; 16,272 mg/Kg dan 12,272 mg/Kg. While the content of Cr on the roots of seagrasses in the waters of Waai village ang Tulehu village 33,066 mg/Kg; 7,752 mg/Kg; 109,535 mg/Kg; 22,464 mg/Kg. The result of this study can be used as a reference for the claim that the roots of seagrasses in the Waters of Waai village and Tulehu village contain metals Pb and Cr quite high.
Synthesis of Binuclear Complex Compound of {[Fe(L)(NCS)¬2]2oks} (L = 1,10-phenantrolin and 2,2’-bypiridine) Yusthinus T Male; Helna Tehubijuluw; Paulina M. Pelata
Indonesian Journal of Chemical Research Vol 1 No 1 (2013): Edisi Pertama (First Edition)
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

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Abstract

The paramagnetic complex {[Fe(fen)(NCS)2]2oks} have been synthesized in methanol solution using 1-10 phenantrolin, 2,2 '-bipyridine, NCS- ligands and oxalate as bridging ligand. Synthesis of Fe (II) with ligands phenantrolin produced three complexes is paramagnetic compounds each with a value of magnetic moment (μ) of 5.98 BM, 7.34 BM and 6.00 BM, respectively. For complexes with bipyridine ligand complexes obtained two diamagnetic compounds with the magnetic moment (μ) was 3.57 BM and 3.50 BM, respectively. It could concluded that the field strength of bipyridine ligand cannot be reduced by NCS- ligand. Analysis results showing that the synthesized compound is a binuclear complex with {[Fe(fen)(NCS)2]2oks} molecular formula. This conclusion was supported by the measurement of conductivity, magnetic moment, IR spectroscopy and XRD analysis.
Analisis Kadar Merkuri (Hg) Pada Rambut Penduduk Desa Kayeli, Akibat Penambangan Emas Tanpa Ijin di Areal Gunung Botak , Kab. Buru-Provinsi Maluku Hadijah Rumatoras; Muhammad I. Taipabu; Lewi Lesiela; Yusthinus T Male
Indonesian Journal of Chemical Research Vol 3 No 2 (2016): Edisi Bulan Januari (Edition For January)
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

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Abstract

In November 2011, the gold mining activities in Botak Mountain, Buru island more increase and it has used mercury as a main ingredient in the extraction process. The use of mercury in the gold mining on Botak Mountain is done freely by the miners (people), allowing mercury waste wasted together distributed to the environment. With the distribution of gold mining in the area of waste water, then allow mercury can accumulate in human through the food chain. This research aims to determine accumulation of mercury at hair of Kayeli Villagers. The research method is used survey and analyze. In this research, were used observation, field sampling and laboratory analyze. The result showed that concentration of mercury analyzed at villagers’s hair is 0.10-3.25 ppm. Based on the result, concentration of mercury analyzed at villagers’s hair has exceeded standard of mercury limits, i.e 0.05 ppm.
Isolasi Mikroba Dari Air Asam Tambang Pada Area Pertambangan Tembaga Di Pulau Wetar, Provinsi Maluku Yusthinus T. Male; Deddy W.S. Modok; Cecilia A. Seumahu; Dominggus Malle
Indonesian Journal of Chemical Research Vol 6 No 2 (2019): Edisi Bulan Januari (Edition For January)
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598//ijcr.2019.6-thi

Abstract

This research was conducted to find bacteria from the genus Acidithiobacillus ferrooxidans which isolated from mine acid water in the copper mining area on Wetar Island, Maluku Province. This bacterium will be utilized in the biohidrometallurgical process (bioleaching) for copper extraction in mining area. The results of this study indicate that bacteria can be isolated from mine acid water samples by enrichment method that was use liquid media from Leathen which is optimized using Trypton Soya Broth (TSB) and bacterial growth on solid media. The presence of Thiobacillussp bacteria was confirmed by the results of gene analysis using a 16S rRNA sequence showing the presence of mixed bacterial colonies but not a single colony.
Bioremediation of Pb and Cd Metal from Inner Ambon Bay Sediment Which Contaminated With Heavy Metal Using Aspergillus niger Yusthinus T Male; Cecillia Anna Seumahu; Dominggus Malle
Indonesian Journal of Chemical Research Vol 7 No 2 (2020): Edisi Bulan Januari (Edition for January)
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598//ijcr.2020.7-yus

Abstract

Bioremediation is a method that use microorganism to extract heavy metal from contaminated waste. In this research Aspergillus niger was used to extract heavy metal such as Pb and Cd of marine sediment from Waiheru shore, Inner part of Ambon Bay, which was detected as significantly high heavy metal contaminated site among seven sites. Bioremediation were done using Aspergillus nigers to extract Pb and Cd metal from sediment, then their solubility being measured in filtrate media. Result shows that Cd metal were only detected 15 days after incubation while Pb were detected since the first day incubation. This result also showing the fluctuating solubility of Pb metal. It is suspected that this occurs due to biosorption ability of the fungi that being used which triggers metal accumulation in the cell structure. It is therefore can be concluded that Aspergillus niger can be used in bioremediation of sediment that are being contaminated by Pb and Cd heavy metals.
Biokonsentrasi dan Bioakumulasi Mercury (Hg) Pada Lamun Enhalus Acoroides Di Teluk Kayeli Kabupaten Buru Provinsi Maluku Fahrul R. Fakaubun; Yusthinus T Male; Debby A. J. Selanno
Indonesian Journal of Chemical Research Vol 8 No 2 (2020): Edisi Bulan September (Edition for September)
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598//ijcr.2020.8-frf

Abstract

Gold reserves on Gunung Botak (Bald Mountain), Buru Island, were discovered in 2011. Since then, thousands of illegal miners have used amalgamation methods to extract gold in the areas of Gunung Botak and Gogrea, Buru Island. The resulting waste is disposed of into the environment directly without any treatment process so it is very dangerous for humans and the environment. This research was conducted to determine the ability of the Enhalus acoroides type of seagrass to accumulate heavy metal mercury (Hg) in the aquatic environment. This research shows that the heavy metal mercury has been distributed in the water sediments along Kayeli Bay. Mercury bio-concentration (accumulation) Gunung Botak, Kayeli Bay, Mercury (Hg), bioconcenstration, Seagrass, Enhalus acoroides, Kayeli Baywas found in Enhalus acoroides seagrass, in leaves (0.0243-0.0373 mg/Kg), and in rhizomes (0.0453-0.0663 mg/Kg). This result shows that the Kayeli Bay ecosystem has been contaminated with mercury.
Co-Authors Abraham Mariwy Alberth Ch. Nanlohy Anjarnita Haupea Asriningsih Asriningsih Camellia Y. Lessil Catherina M. Bijang Cecelia Anna Seumahu Cecilia A. Seumahu Cecillia Anna Seumahu Ch I Tupan Chudeya Y. Batawi Claudia F Talaud Deddy W.S. Modok Dewi H Rumakat Djulia Onggo Djulia Onggo DOMINGGUS MALLE Eirene G Fransina Eirene Grace Fransina Fahrul R. Fakaubun Febrian M. Salatutin Hadijah Rumatoras Helna Tehubijuluw I Wayan Sutapa IRSAN . Ismunandar Ismunandar Ismunandar Jusuf Wattimury Jusuph J Wattimury Letsoin, Lina I Lewi Lesiela Lina I Letsoin Lois Mikhal Dolaitery Maahury, Mirella Fonda Matheis F.J.D.P anasale Matheis F.J.D.P. Tanasale Muhamad A. Martoprawiro Muhamad Abdulkadir Martoprawiro Muhamad Abdulkadir Martoprawiro Muhammad I. Taipabu Nelson Gaspersz Neti Nunumete Netty A Siahaya Nina B Garium NUR ALIM NATSIR Olivia M. Ranglalin Paulina M. Pelata Pieter J. Kunu Pusung, Yulian A. D. Sartika Landu Selanno, Debby A J Siahaya, Netty A Sunarti Sunarti Yeanchon H Dulanlebit