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All Journal Microbiology Indonesia Jurnal Kimia Terapan Indonesia Seminar Nasional Lahan Suboptimal METRIK SERIAL TEKNOLOGI DAN SAINS
Rofiq Sunaryanto
Center of Biotechnology, Puspiptek, Serpong, Tangerang Selatan, Banten 15340, Indonesia
Agriculture, Biological Sciences & Forestry Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Energy Engineering Immunology & microbiology Materials Science & Nanotechnology Medicine & Pharmacology Physics Other

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Journal : Jurnal Kimia Terapan Indonesia

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SINTESIS POLI (GLIKOLIDA-CO-LAKTIDA) DAN UJI BIODEGRADABILITASNYA Rofiq Sunaryanto; Hardaning Pranamuda
Jurnal Kimia Terapan Indonesia Vol 17, No 2 (2015)
Publisher : Research Center for Chemistry - LIPI

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (546.527 KB) | DOI: 10.14203/jkti.v17i2.27

Abstract

Polylactide and polyglycolide are important aliphatic polyester consist of lactide and glycolide repeats unit. It is considered as green polymer due to it is produced from renewable agricultural resources. The development of biodegradable plastics based on agricultural resources is still important to be done. Copolymerization of glycolide with D-lactide, L-lactide, and DL-lactide using a Sn(Oct)2 as catalyst had been carried out. Polymerization was conducted by ring-opening of lactide and glycolide without the solvents but melting polymerization. Polymerization were conducted at 130 °C for 130 hours. Result of this study showed that polymerization of glycolide with D-lactide produce polymers with an average molecular weight of 8.2x103 and a yield of 72 %. Polymerization of glycolide with L-lactide produce polymer with an average molecular weight of 2.8x103 and a yield of 36 %. Polymerization glycolide with DL-lactide produce polymer with an average molecular weight of 2.5x103 with a 48 % yield. The burial test for 28 days showed poly (glycolide-co-Llaktida) degraded faster than other polymers, namely degraded 32 %. While poly (glycolide-co-DL-lactide) and poly (glycolide-co-D-lactide) showed similar degradation that is equal to 20 %. Compared with PHB (polyhydroxybutyrate), poly (glycolide-co-lactide) degraded more slowly.Keywords: Glycolide, lactide, copolymerization, biodegradable plastic
Co-Authors ASEP RISWOKO BAMBANG MARWOTO Diana Nurani Hardaning Pranamuda Khaswar Syamsu Liesbetini Hartoto Nurhayati Nurhayati Selvi Ayu Sari Siti Nabilah Tun Tedja Irawadi Zainal Alim Mas'ud