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Synthesis and Characterization of Zeolitic Imidazolate Framework-8 (ZIF-8)/Al2O3 Composite Aulia, Wulan; Ahnaf, Ahnaf; Irianto, Mochammad Yusuf; Ediati, Ratna; Iqbal, Rendy Muhamad; Rachman, Rahadian Abdul; Martia, Ulva Tri Ita
IPTEK The Journal for Technology and Science Vol 31, No 1 (2020)
Publisher : IPTEK, LPPM, Institut Teknologi Sepuluh Nopember

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (929.525 KB) | DOI: 10.12962/j20882033.v31i1.5511

Abstract

Metal-organic framework (MOF) such as ZIF-8 is the tremendous porous material applied in many fields due to high specific surface area and excellent regularity of pores. One technique to improve the physical properties of ZIF-8 with the formation of a composite between a metal oxide and MOF. ZIF-8 and ZIF-8/Al2O3 were successfully synthesized by the solvothermal method with an Al variation of 19%, 38%, and 76%. The ZIF-8/Al2O3 were characterized by XRD, FTIR, SEM, and N2 Physisorption. The diffractogram shows that the appearing of ZIF-8’s peak on 2θ = 7.26; 10.41, 12.66, 16.41, and 17.95°. The morphological of ZIF-8 crystals had a cubic shape. Then the ZIF-8/Al2O3 had different shapes with ZIF-8. Based on the FTIR result, the Zn-N peak appears on 420 cm−1, which indicates the bonding between metal and organic ligand for ZIF-8/Al2O3 has an additional spike on 825 cm−1 due to the vibration of Al−O− Al.
Synthesis, Characterization, and Performance of TiO2-N as Filler in Polyethersulfone Membranes for Laundry Waste Treatment Alvin Romadhoni Putra Hidayat; Vina Rizky Andina; Ahnaf Ahnaf; Nurul Widiastuti; Rendy Muhamad Iqbal
Jurnal Sains dan Seni ITS Vol 8, No 2 (2019)
Publisher : Lembaga Penelitian dan Pengabdian Kepada Masyarakat (LPPM), ITS

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (539.259 KB) | DOI: 10.12962/j23373520.v8i2.49806

Abstract

Sintesis TiO2-N telah dilakukan dengan metode sol gel. Pada hasil karakterisasi XRD doping TiO2 tidak dapat menghancurkan struktur anatase karena difraktogram TiO2-N mewakili puncak yang serupa dengan TiO2. Intensitas puncak spektra FTIR yang kuat berasal dari gugus hidroksil dalam N-TiO2, dibandingkan dengan TiO2 tanpa doping. Dari hasil pengolahan data hasil karakterisasi UV-DRS didapatkan nilai energi bandgap TiO2 3,33 eV, sedangkan pada fotokatalis TiO2-N energi band gap yang dihasilkan yaitu 3,08 eV. Hasil BET menyebutkan TiO2 memiliki luas permukaan yang lebih tinggi dibandingkan dengan TiO2-N. Pada penelitian ini, hasil nilai fluks air murni dan fluks limbah laundry yang paling tinggi terdapat pada membran PES/PEG/TiO2-N yaitu 116,91 L/m2jam pada 2 menit pertama untuk fluks air murni dan 98,636 L/m2jam pada 2 menit pertama untuk fluks limbah dan rejeksi yang dihasilkan mencapai 84,328% untuk nilai penurunan COD dan 82,75% untuk nilai penurunan BOD sehingga penambahan TiO2-N pada membran dapat meningkatkan kinerja membran saat ultrafiltrasi.
GAYA HIDUP BERSIH DENGAN MENCUCI TANGAN SEBAGAI UPAYA UNTUK MENCEGAHAN PENULARAN COVID 19 DI KOMUNITAS MUSLIMAH KOTA PALANGKA RAYA Erwin Prasetya Toepak; Rendy Muhamad Iqbal; Dyah Ayu Pramoda Wardani; Sari Namarito Simamarta; Elda Alyatikah
LOGISTA - Jurnal Ilmiah Pengabdian kepada Masyarakat Vol 4 No 2 (2020)
Publisher : Department of Agricultural Product Technology, Faculty of Agricultural Technology, Universitas Andalas Kampus Limau Manis - Padang, Sumatera Barat Indonesia-25163

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.25077/logista.4.2.611-614.2020

Abstract

Virus Corona menyebabkan infeksi gangguan pernafasan serius yang dapat menyebabkan kematian. Berdasarkan data yang dipublikasikan oleh Kementerian Kesehatan Republik Indonesia, Kota Palangka Raya merupakan wilayah dengan kasus pasien terkonfirmasi positif terbesar sebanyak 145 orang dengan jumlah kematian sebesar 8 orang pertanggal 5 Juni 2020. Penyebaran virus, termasuk virus korona, sebesar 98% bersumber dari tangan. Oleh sebab itulah dengan rajin mencucui tangan maka dapart mencegah dan memutus rantai penyebaran virus korona. Jikalau tidak terdapat sabun dan air mengalir, maka dapat menggunakan hand sanitizer seperti yang dianjurkan oleh Centers for Disease Control and Prevention (CDC) Amerika Serikat. Berdasarkan hal itu, maka kegiatan mempromosikan penggunaan hand sanitizer perlu dilakukan. Kegiatan masyarakat yang telah dilaksanakan ini dilakukan melalui pemberian hand sanitizer dan informasi ringkas tentang kebiasaan mencuci tangan yang praktis pada komunitas muslimah Kota Palangka Raya. Hasil dari kegiatan ini diharapkan dapat memberikan sumbangsih mencegah infeksi COVID 19. Kata kunci: COVID 19, Hand Sanitizer, Palangka Raya, Hidup Bersih, Komunitas Muslimah ABSTRACT Corona virus causes serious respiratory infections that can lead to death. Based on data published by the Ministry of Health of the Republic of Indonesia, Palangka Raya City is the region with the largest positive confirmed cases of 145 people with 8 deaths as of June 5, 2020. The spread of viruses, including the corona virus, is 98% sourced from hands. That is why diligently washing hands can prevent and break the chain of spreading the corona virus. If soap and running water are not available, a hand sanitizer can be used as recommended by the US Centers for Disease Control and Prevention (CDC). Based on this, activities to promote the use of hand sanitizers need to be carried out. This activity that has been carried out is carried out through the provision of hand sanitizers and brief information about practical hand washing habits in the Muslim community of Palangka Raya City. It is hoped that the results of this activity can contribute to preventing COVID 19 infection. Keywords: COVID 19, Hand sanitizer, Palangka Raya, Clean living, Muslimah community
Photocatalytic Activity and Kinetic Study of Methylene Blue Degradation using N-Doped TiO2 with Zeolite-NaY Indri Susanti; Rendy Muhamad Iqbal; Rahadian Abdul Rachman; Tri Agusta Pradana
CHEESA: Chemical Engineering Research Articles Vol 4, No 2 (2021)
Publisher : Universitas PGRI Madiun

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.25273/cheesa.v4i2.7646.75-81

Abstract

Methylene blue is the most widely used dye in the industry and it is difficult to be degraded by the microorganism. This research aims to investigate the photocatalytic activity and effects of contact time on the photocatalytic degradation rate of methylene blue by TiO2/Zeolite-NaY and TiO2-N/Zeolite-NaY material based on the kinetic study. The Advanced Oxidative Process (AOP) method was used to degrade methylene blue. Furthermore, the AOP is a degradation process that uses semiconductor material such as TiO2 or modification catalyst of TiO2 to be TiO2/Zeolite-NaY and TiO2-N/Zeolite-NaY. The degradation of methylene blue with catalyst TiO2/Zeolite-NaY and TiO2-N/Zeolite-NaY were tested under UV light for 5, 20, 30, 40, and 50 minutes. The result showed that TiO2/Zeolite-NaY and TiO2-N/Zeolite-NaY had an excellent activity for degrading the dye, which reached up to 99% after 20 and 30 minutes reaction, respectively. Also, a kinetic study of methylene blue degradation on TiO2/Zeolite-NaY and TiO2-N/Zeolite-NaY showed the kinetic models were according to pseudo-second-order.
REVIEW: PENGEMBANGAN MIXED MATRIX MEMBRANE UNTUK PEMISAHAN GAS CO2/CH4 Rendy Muhamad Iqbal; Sari Namarito Simarmata; Elfrida Roulina Simanjuntak; Wahyu Nugroho; Lilis Rosmainar Tambunan
Jurnal Sains dan Terapan Kimia Vol 14, No 2 (2020)
Publisher : Program Studi Kimia, Universitas Lambung Mangkurat

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (521.86 KB) | DOI: 10.20527/jstk.v14i2.8048

Abstract

Teknologi pemisahan gas telah banyak dilakukan menggunakan membran. Mixed matrix membran (MMMs) telah banyak dikembangkan dengan mengkombinasikan polimer organik dan filler anorganik. Pemisahan gas dengan mixed matrix membrane telah banyak dikembangkan dan menghasilkan kinerja yang sangat baik. Pada pemisahan gas CO 2 /CH 4, satu hal yang diutamakan dan diperhatikan adalah permeabilitas yang tinggi. Umumnya semakin tinggi permeabilitas suatu gas dalam membran, maka semakin rendah pula selektivitasnya dan begitu pula sebaliknya. Beberapa filler yang baik digunakan untuk mixed matrix membrane yaitu dengan filler material silika, nanopartikel NiO, grafena oksida dan metal organic frameworks (MOF).Kata Kunci: Mixed matrix membrane, pemisahan gas
The Ecofriendly Biosorbent of Methylene Blue Using Banana Peels Waste Indri Susanti; Rendy Muhamad Iqbal; Novia Amalia Sholeha; Khusnul Fatimah Putri
Indonesian Journal of Chemical Research Vol 10 No 2 (2022): Edition for September 2022
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598//ijcr.2022.10-ind

Abstract

This research aimed to synthesize and characterize the properties of green banana peel waste to be used as adsorbent material. The green banana peel waste was prepared by sieved to be banana powder and then characterized by XRD, FTIR, XRF, and TGA. The adsorption capacity of methylene blue was tested using a simple method, the “batch method”, with further analysis by spectrophotometry UV-Vis. The XRF results of green banana peel showed that most of the composition is potassium and phosphorus. The methylene blue adsorption capacity of banana peel material is up to 75.10% with 0.5 grams of adsorbent, which is more significant than in the banana peel, which is 68.04% with 0.2 grams.
Fabrication and characterization of fly ash-based geopolymer and its performance for immobilization of heavy metal cations Rendy Muhamad Iqbal; Warih Supriadi; R.Y. Perry Burhan; Silvana Dwi Nurherdiana; Ririn Eva Hidayati; Subaer Subaer; Ridho Bayuaji; Hamzah Fansuri
Communications in Science and Technology Vol 7 No 2 (2022)
Publisher : Komunitas Ilmuwan dan Profesional Muslim Indonesia

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21924/cst.7.2.2022.868

Abstract

In this study, the geopolymer from fly ash as based-raw material has been examined on the ability of several heavy metal ions immobilization. The fly ash has been provided from PT IPMOMI which firstly analyzed the physical and chemical properties. Fly ash and heavy metals were mixed with an activator base until homogeneous, then cast into a cylindrical shape mold following ASTM C 39-86 and left for 7 days. After that, the geopolymer was characterized by SEM, FTIR, XRD, compressive strength test and TCLP. The diffractogram of PT. IPMOMI fly ash exhibited the existence of mullite, alumina and iron oxide phase, which were suitable with XRF result. From FTIR spectra, the vibration on finger print area appeared indicating the vibration of T-O-T from geopolymer network. The observation revealed that the addition of Pb2+ cations caused microcracking from SEM image and affected the compressive strength of the geopolymer. Sr2+ was an ion that was very easilyleached compared to other three ions, and it caused a weak interaction between Sr2+ and geopolymer network. The higher amount of metal ions into the geopolymer network reduced the compressive strength of geopolymer. Sr2+-geopolymer had a lower compressive strength compared to Pb2+, Cd2+, and Co2+.
A Review: Development of Photocatalyst Materials and Its Performance for Humic Acid Removal in Peatwater Siti Unvaresi Misonia Beladona; Riandy Putra; Rokiy Alfanaar; Miranti Maya Sylvani; Elda Alyatikah; Riaa Safitri; Indri Susanti; Rendy Muhamad Iqbal
Journal of Peat Science and Innovation Vol. 1 No. 1 (2022): Journal of Peat Science and Innovation: June 2022
Publisher : Center for Development of Science, Technology and Peatland Innovation (PPIIG), University of Palangka Raya

Show Abstract | Download Original | Original Source | Check in Google Scholar | Full PDF (758.565 KB) | DOI: 10.59032/jpsi.v1i1.5380

Abstract

Peat is a wetland region in Indonesia with a very high water storage capacity. However, the amount of humic compounds obtained from the accumulation of organic substances in peat makes the water unable to be used for daily purposes. Peat water treatment with several methods has been carried out, such as coagulation, electrocoagulation, flocculation, and filtration. However, the result of clumping or filtering in such a way raises new environmental problems. One method which effective and efficient used in peat water treatment is photocatalytic. Several materials based-semiconductor was developed as a photocatalyst, another modification of photocatalyst is combining the adsorbent as a porous supporting photocatalyst which can improve its performance.
Chitosan/Rice Husk-Derived Silica Mixed Matrix Membrane as Potential Separator for Peatwater Purification Siti Unvaresi Misonia Beladona; Artha Karunia Gresiana Siregar; Midun Efendi Patar Sihombing; Fakhrotun Nisa; Rendy Muhamad Iqbal
Journal of Peat Science and Innovation Vol. 2 No. 1 (2023): Journal of Peat Science and Innovation: June 2023
Publisher : Center for Development of Science, Technology and Peatland Innovation (PPIIG), University of Palangka Raya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.59032/jpsi.v2i1.10686

Abstract

Indonesia has the largest distribution of peatlands worldwide and is spread over Sumatra, Kalimantan, and Papua islands. Peatland is one of the land resources with a hydrological function and can store water in the form of peatwater. Peatwater is brownish-red due to high dissolved organic matter, especially in the form of humic acid and its derivatives, high organic matter content, low pH, and low cation content. Peatwater is classified as polluted water, unsuitable for consumption, and cannot be used directly as drinking, bathing, or washing water. The Mixed Matrix Membrane Fabrication method is expected to be used for peatwater purification by adding silica filler from rice husk ash. Rice husk has a high silica filler content of >90%. The higher the silica level, the better the material absorbs harmful chemical compounds in peatwater, one of which is humic acid.