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All Journal CAKRA KIMIA (Indonesian E-Journal of Applied Chemistry) Jurnal Kimia (Journal of Chemistry) Alchemy : Journal of Chemistry Pharmaciana: Jurnal Kefarmasian CHEMICA Jurnal Teknik Kimia The Journal of Pure and Applied Chemistry Research Jurnal Kimia dan Kemasan JPM17: Jurnal Pengabdian Masyarakat EduChemia (Jurnal Kimia dan Pendidikan) CHEMPUBLISH JOURNAL ALCHEMY Jurnal Penelitian Kimia JMM (Jurnal Masyarakat Mandiri) Walisongo Journal of Chemistry Jurnal Pengabdian Al-Ikhlas Abdimas: Jurnal Pengabdian Masyarakat Universitas Merdeka Malang JAPI (Jurnal Akses Pengabdian Indonesia) Jurnal Kimia dan Kemasan Journal of Multidisciplinary Applied Natural Science JAPI: Jurnal Akses Pengabdian Indonesia Journal of Peat Science and Innovation (JPSI) Nanggroe: Journal Of Scholarly Service Jurnal Pengabdian Masyarakat Charitas Nanggroe: Journal of Scholarly Service

Alfanaar, Rokiy

Department Of Chemistry, Faculty Of Mathematic And Natural Sciences, Universitas Palangka Raya, Palangka Raya-73111 (Indonesia)

Author-ID : 755752

Religion Agriculture, Biological Sciences & Forestry Arts Humanities Biochemistry, Genetics & Molecular Biology Chemical Engineering, Chemistry & Bioengineering Chemistry Civil Engineering, Building, Construction & Architecture Computer Science & IT Decision Sciences, Operations Research & Management Economics, Econometrics & Finance Education Electrical & Electronics Engineering Energy Engineering Environmental Science Health Professions Immunology & microbiology Industrial & Manufacturing Engineering Languange, Linguistic, Communication & Media Law, Crime, Criminology & Criminal Justice Library & Information Science Materials Science & Nanotechnology Mathematics Medicine & Pharmacology Neuroscience Nursing Physics Public Health Social Sciences Other

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Cytotoxic effect of 2,3-dihydro-6-hydroxy-2-methylenenaphtho[1,2-b] furan-4,5-dione compound from the bark of faloak (Sterculia quadrifida R.Br) in breast cancer cells T47D Rollando, Rollando; Alfanaar, Rokiy
Pharmaciana Vol 7, No 2 (2017): Pharmaciana
Publisher : Universitas Ahmad Dahlan

Faloak (Sterculia quadrifida R.Br) is used empirically by residents of East Nusa Tenggara for drug plant. The information of the active compound contained in the faloak bark yet specifically published. This study aims to determine the active compound contained in the faloak bark that have cytotoxic activity to T47D breast cancer cells. Extraction process using maceration method, isolation process using gradien isolation method, elusidation using combination of information of IR spectra, 1D-NMR, 2D-NMR and LC-MS, and cytotoxic activity test on T47D breast cancer cells using MTT method. The isolation result obtained that isolate of naphthoquinone derivative compound is 2,3-dihydro-6-hydroxy-2-methylenenaphtho [1,2-b] furan-4,5-dione with IC50 value on T47D breast cancer cell was 9,88 Âµg/mL and with an index selectivity value was 30,23.Â

Penerapan Metode Sonikasi terhadap Adsorpsi Fe(III) pada Zeolit Alam Teraktivasi Rismiarti, Zuri; Yuniati, Yuyun; Alfanaar, Rokiy
ALCHEMY Vol 5, No 2 (2016): ALCHEMY
Publisher : Department of Chemistry, Faculty of Science and Technology UIN Maulana Malik Ibrahim Malan

Iron (III) (Fe (III)) is widely used in the industry such us water treatment, the sugar cane, the concrete industry and coal mining. Industrial activity using Fe(III) has potential impact to environmental pollution problems due to that industry produces Fe waste that one of hazardous waste. Fe content excess might toxic effect to human health and the environment. Zeolite as adsorbent has been evaluated extensively for Fe and other heavy metal. Sonication method has been widely developed in polymer preparation. The method is more effective in operation time because the reaction rate increased and also more efficient on the usage of chemical reagens. The optimization of reaction time, the ratio of Fe(III) with activated zeolite, the influence of pH, and temperature has been assessed for Fe(III) adsorption with an activated zeolite by sonication technique. The formation of Fe(III)-SCN complex assay was used for determination of Fe(III) adsorbed by the activated zeolite with using spectrophotometer. The results showed a relatively short operation time (15 minutes), at pH of 4, temperature ofÂ 30 Â°C with the ratio of 1:50 (weight/volume) for the activated zeolite and Fe(III).Â

Sintesis Senyawa Koordinasi Astaxanthin Dengan Bantuan Gelombang Ultrasonik Rokiy Alfanaar; Dion Notario
Jurnal Kimia dan Kemasan Vol. 41 No. 2 Oktober 2019
Publisher : Balai Besar Kimia dan Kemasan

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.24817/jkk.v41i2.3366

Astaxanthin merupakan senyawa turunan karotenoid xantofil yang sangat potensial dalam pengobatan kanker. Salah satu upaya meningkatkan aktivitas anti kanker dari astaxanthin adalah dengan menggabungkan senyawa astaxanthin dengan ion logam. Upaya sintesis senyawa koordinasi astaxanthin dengan ion logam Fe3+, Mn2+, dan Zn2+ telah dilakukan dengan bantuan gelombang ultrasonik. Panjang gelombang maksimal senyawa kompleks Mn(II)-Astaxanthin adalah 473 nm, Fe(III)-Astaxanthin adalah 355 nm, dan Zn(II)-Astaxanthin adalah 473 nm. Hasil FTIR menunjukan munculnya gugus fungsi khas astaxanthin pada semua kompleks dan munculnya serapan pada 535 cm-1, untuk kompleks Mn(II)-Astaxanthin, 397 cm-1 untuk Fe(III)-Astaxanthin, dan 535 cm-1 untuk Zn(II)-Astaxanthin yang mengindikasikan adanya ikatan logam dengan atom donor dari Astaxanthin.

Physical Properties Investigation on Sunscreens with Colloidal Gold and Moringa oleifera Extract Ruth Febriana Kesuma; Eva Monica; Rokiy Alfanaar
The Journal of Pure and Applied Chemistry Research Vol 9, No 1 (2020): Edition January-April 2020
Publisher : Chemistry Department, The University of Brawijaya

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.21776/jpacr.ub.2020.009.01.464

Botanicals were known as active ingredients in sunscreens due to their dermal protecting. Gold in colloidal form has a completely unique property for the reason that it may be used as photoaging material. The exposure of UV radiation to skin can cause erythema and skin cancer. The aim of this study was to determine the physical properties of the sunscreens made from Au/ZnO and antioxidant from Moringa oleifera extract such as the sun protection factor (SPF), pH, spreadability, and adhesion. The Moringa oleifera were extracted by maceration. Maceration with 70% ethanol of dried leaves exhibited DPPH scavenging activity (EC50 235.01 μg/mL). Diffuse reflectance UV-Vis spectra of ZnO and Au/ZnO revealed absorption at λex of 385 nm which were equivalent to a bandgap energy of 3.22 eV. Au/ZnO posed a localized state at λex of 385 (3.65 eV). The sunscreens with formulations F1, F2, F3, and F4 showed high SPF number of 20.1479, 21.0008, 22.3872, and18.4631. Kruskal-Wallis test showed significant differences between sunscreen formulations.

ISOLASI SENYAWA TURUNAN NAPTOKUINON DARI KULIT BATANG FALOAK (Sterculia quadrifida R.BR) DAN UJI AKTIVITAS ANTIKANKER PADA SEL KANKER PAYUDARA JENIS T47D Rollando Rollando; Rokiy Alfanaar
CAKRA KIMIA (Indonesian E-Journal of Applied Chemistry) Vol 5 No 1 (2017)
Publisher : Magister Program of Applied Chemistry, Udayana University, Bali-INDONESIA

ABSTRAK: Faloak (Sterculia quadrifida R.Br) digunakan secara empiris oleh penduduk Nusa Tenggara Timur untuk mengobati hepatitis, tifus, maag, dan pemulih stamina. Informasi senyawa aktif yang terkandung didalam kulit faloak secara spesifik belum dipublikasi. Penelitian ini bertujuan untuk mengetahui senyawa aktif yang terdapat didalam kulit faloak sebagai antikanker. Ekstraksi menggunakan metode maserasi, isolasi menggunakan metode isolasi bertingkat, elusidasi menggunakan penggabungan informasi dari spektra IR, 1D-NMR, 2D-NMR dan LC-MS, dan uji aktivitas antikanker pada sel kanker payudara T47D menggunakan metode MTT. Hasil isolasi diperoleh isolat turunan senyawa naptokuinon yaitu 2,3-dihydro-6-hydroxy-2-methylenenaphtho[1,2-b]furan-4,5-dione yang aktif sebagai antikanker dengan nilai IC50 pada sel kanker payudara sebesar 9,88 µg/mL dan dengan nilai selektivitas indeks sebesar 30,23. ABSTRACT: Faloak (Sterculia quadrifida R.Br) is used empirically by residents of East Nusa Tenggara to treat hepatitis, typhoid, ulcers, and stamina restorers. The information of the active compounds contained in the faloak skin is not specifically published. This study aims to determine the active compounds contained in the bark of faloak as anticancer. The extraction was conducted with maceration method followed by a multilevel isolation method. The elucidation was carried out using information of IR spectra, 1D-NMR, 2D-NMR and LC-MS. The anticancer activity test on T47D breast cancer cells was also conducted using MTT method. Based on the results obtained, the active compound is naphthoquinone derivative compound which is 2,3-dihydro-6-hydroxy-2-methylenenaphtho [1,2-b] furan-4,5-dione that has anticancer activity on breast cancer cell (T47D) with IC50 value of 9.88 µg/mL and index selectivity value of 30.23.

Cytotoxic effect of 2,3-dihydro-6-hydroxy-2-methylenenaphtho[1,2-b] furan-4,5-dione compound from the bark of faloak (Sterculia quadrifida R.Br) in breast cancer cells T47D Rollando Rollando; Rokiy Alfanaar
Pharmaciana Vol 7, No 2 (2017): Pharmaciana
Publisher : Universitas Ahmad Dahlan

STUDI KINETIKA DAN ISOTERM ADSORPSI BESI(III) PADA ZEOLIT ALAM DENGAN BANTUAN GELOMBANG SONIKASI Rokiy Alfanaar; Yuyun Yuniati; Zuri Rismiarti
EduChemia (Jurnal Kimia dan Pendidikan) Vol 2, No 1 (2017): Available Online in January 2017
Publisher : Department of Chemical Education Faculty of Teacher Training and Education Universitas Su

Abstract: Fe3+ ion is one type of heavy metal waste that is often encountered from the rest of the industrial processes and laboratory education. Adsorption using natural zeolite is one way of reducing the content of Fe3+ ions. Sonication waves can influence the adsorption process that happens. Adsorption of Fe3+ by sonication assisted natural zeolite follows 1st order kinetics base on Santosa equation with R2 value =0.928. Isothermal adsorption of this study follow Freundlich equation with R2 value = 0.948, n= 1.789 and KF = 1.832.Abstrak: Ion Fe3+ adalah salah satu jenis limbah logam berat yang sering dijumpai dari sisa proses industri dan laboratorium pendidikan. Adsorpsi menggunakan zeolit alam adalah salah satu cara mengurangi kandungan ion Fe3+.Gelombang sonikasi dapat mempengaruhi proses adsorpsi yang terjadi. Adsorpsi Fe3+ zeolit alam dengan bantuan gelombang sonikasi mengikuti kinetika orde 1 berdasarkan persamaan Santosa dengan nilai R2 = 0.928. Isoterm adsorpsi pada penelitian ini mengikuti isoterm Freundlich dengan nilai R2 = 0.948, n = 1.789, dan KF = 1.832.

PELATIHAN DAN PEMBUATAN INFOGRAFIK PENGUKURAN KUALITAS TANAH DI DESA GONDOWANGI Rokiy Alfanaar; Ruth Febriana Kesuma; Rollando ,
JPM17: Jurnal Pengabdian Masyarakat Vol 5 No 01 (2020)
Publisher : Lembaga Penelitian dan Pengabdian kepada Masyarakat

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30996/jpm17.v5i01.3256

Desa Gondowangi adalah salah satu desa yang sebagian penduduknya mengandalkan sektor pertanian. Pada umumnya, petani di Desa Gondowangi mengalami masalah bedanya hasil pertanian dari berbagai lahan yang dimiliki. Pengabdian masyarakat ini dilaksanakan dengan metode pelatihan pengukuran kualitas tanah dan pembuatan infografik kualitas tanah. Kegiatan pengabdian dilaksanaan dengan cara pelatihan secara langsung di lahan milik para petani. Pelatihan pengukuran dilaksanakan secara langsung oleh petani pemilik lahan sehingga petani terbiasa menggunakan soil meter. Berdasarkan hasil pengabdian didapatkan berbagai lahan memiliki kualitas tanah yang berbeda dari segi pH dan kandungan unsur hara.

Pelarutan Selektif Tembaga dari Limbah Printed Circuit Board dengan Hidrogen Peroksida Gatut Ari Wardani; Rokiy Alfanaar; Sri Juari Santosa
ALCHEMY Jurnal Penelitian Kimia Vol 14, No 1 (2018): March
Publisher : UNIVERSITAS SEBELAS MARET (UNS)

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.20961/alchemy.14.1.11168.51-59

Pelarutan selektif tembaga dari limbah printed circuit board (PCB) telah berhasil dilakukan. Logam tembaga yang terkandung di dalam papan PCB dapat dipisahkan menggunakan campuran hidrogen peroksida dan asam sulfat dengan variasi perbandingan volume 0 : 1, 1 : 1, 2 : 1, 3 : 1, 4 : 1, dan 5 : 1. Pemisahan optimal dilakukan dengan sistem perendaman selama 3 hari dengan campuran H2O2/H2SO4 = 3 : 1 (v/v). Jumlah tembaga yang terkandung di dalam papan PCB dianalisis menggunakan X-ray fluorescense. Tembaga yang terkandung di dalam PCB sebesar 57,7%. Pelarutan selektif dapat menurunkan kadar tembaga sehingga tembaga yang masih tersisa adalah sebesar 7,7 x 10-4 %. Penurunan kadar tembaga yang terkandung di dalam PCB mencapai 99,999%. Analisis spektrometri serapan atom dilakukan untuk mengetahui jumlah tembaga yang terlarut yaitu sebesar 25,415 mg/kg PCB.Leaching of Copper from Printed Circuit Board Waste with Hydrogen Peroxide. Leaching of copper from printed circuit board (PCB) waste has been successfully performed. The copper metal contained in the PCB can be separated using a mixture of hydrogen peroxide and sulfuric acid with a variation of volume ratio is 0 : 1, 1 : 1, 2 : 1, 3 : 1, 4 : 1, and 5 : 1. Optimal separation is carried out by the immersion system for 3 days using H2O2/H2SO4 = 3:1 (v/v). The amount of copper contained in the PCB was analyzed using X-ray fluorescence. The copper contained in the printed circuit board is 57.7%. The leaching process can decrease the copper content so that the remaining copper is 7.7 x 10-4%. The decrease of copper content contained in PCB reaches 99.999%. Analysis of atomic absorption spectrometry was conducted to determine the amount of dissolved copper that is 25.415 mg/kg PCB.

Co-Authors Arif Cahyo Imawan Chresiani Destiana Yoedistira Chresiani Destianita Yoedistira Chresiani Yoedistira Devi Natalia Dion Notario E. Monica Efriyana oksal Elda Alyatikah Fatchiyatun Ni’mah Fatiqin, Awalul Febri Nur Ngazizah FX Haryanto Susanto Gatut Ari Wardani Indri Susanti Iqbal, Rendy Muhamad Jumina Jumina Karyadi Karyadi Kestrilia Rega Prilianti Krisfian Tata Aneka Priyangga Lilis Rosmainar M. H. Afthoni Marvin Horale Pasaribu Melany Melany Miranti Maya Sylvani Mokhamat Ariefin Monica, Eva Muhammad Hilmi Afthoni Mulani Jeni Lestari Tampubolon Mu’afa Purwa Arsana P. N. Alfiyandri Pandu Gizta Rapi Paksi Rahman, Sudarman Rasidah Rasidah Riaa Safitri Riandy Putra Rollando, Rollando Ruth Febriana Kesuma Ruth Febriana Kesuma Shesanti Citra Riana Siti Unvaresi Misonia Beladona Sri Juari Santosa Sultan Arif Rahmadianto Tety Wahyuningsih Manurung Thathit Suprayogi W. Swastika Yahya Febrianto Yehezkiel Steven Kurniawan Yudhi Ekakristian Sahari Yuniati, Yuyun Yuyun Yuniati Yuyun Yuniati Zuri Rismiarti Zuri Rismiarti

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