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Journal : Chemistry Indonesian Journal of Chemical Research

Sintesis dan Karakterisasi Selulosa Asetat (CA) Fensia Analda Souhoka; Jolantje Latupeirissa
Indonesian Journal of Chemical Research Vol 5 No 2 (2018): Edisi Bulan Januri (Edition For January)
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598//ijcr.2018.5-fen

Abstract

Synthesis and characterization of cellulose acetate (CA) has been conducted. The cellulose used in this study was commecial a-cellulose in 92% content. All the CA products were analyzed by FTIR spectrometers. The determination of cellulose content was done using standart method of TAPPI T-203, while the determination of the degree of substitution (DS) was based on SNI 0444:2009 method. Conventional acetylation of cellulose was performed using gacial acetic acid, anhydride acetic acid, and sulfuric acid. The acetylation at 25 °C for 2.5 hours gave the DS of 1.482 and at 40 °C for 5 hours gave the higher DS 2.295.
Uji Aktivitas Antioksidan Ekstrak Metanol Biji Kesumba Keling (Bixa orellana L) Fensia Analda Souhoka; Nikmans Hattu; Marsye Huliselan
Indonesian Journal of Chemical Research Vol 7 No 1 (2019): Edisi Bulan Juli (Edition For July)
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598//ijcr.2019.7-fas

Abstract

Kesumba keling (Bixa orellana L) has been widely used as a natural dye on lips, hair, and cloth. The red pigment in kesumba keling seeds comes from a bixin and norbixin compound which have many conjugated double bonds, so it has the potential of antioxidants. This study aims to determine the antioxidant compound and an antioxidant activity of methanol extract of kesumba keling seeds. The moisture content of kesumba keling seeds is 78.74%. The powder of kesumba keling seeds was extracted using maceration method with 80% of methanol. Phytochemical test results of methanol extract positively contained flavonoid compound. An antioxidant activity test of methanol extract of kesumba keling seeds was carried out by determining DPPH free radical deterrent activity. The absorbance measurement were made using a UV-Vis spectrophotometer at a wavelength of 517 nm. Kesumba keling seeds extract has antioxidant activity which is indicated by IC50 value of 69.425 ppm, so it is classified as a strong antioxidant.
Patchouli Oil Isolation and Identification of Chemical Components Using GC-MS Fensia Analda Souhoka; Andi Zulkifli Al Aziz; Nazudin Nazudin
Indonesian Journal of Chemical Research Vol 8 No 2 (2020): Edisi Bulan September (Edition for September)
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598//ijcr.2020.8-fas

Abstract

This research aims to isolate oil from patchouli (Pogostemon cablin Benth) and identify the chemical components of patchouli oil using Gas Chromatography-Mass Spectrometry (GC-MS). Patchouli plant samples were obtained from Welulu Village, Kolaka Regency, Southeast Sulawesi Province. Fresh patchouli leaves are dried in the sun for four days to a constant weight. Patchouli leaves water content is 77.41% (w/w). Dry patchouli leaves are distilled using the water and steam method for two hours. Water and oil distillates are separated using a separating funnel. Patchouli oil obtained was dried using Na2SO4 anhydrous and yield 0.73% (w/w). The results of GC-MS analysis showed that patchouli oil contained 13 chemical components compounds, namely β-patchoulene (4.56%), cedr-8-ene (1.24%), trans-caryophyllene (7.96%), α-guaiene (18.61%), seychellene (5.70%), patchoulene (2.88%), eremophilene (1.33%), azulene (8.74%), delta-guaiene (18.90%), cyclohexanone (1.10%), globulol (1.88%), veridiflorol (4.39%), and alcohol patchouli (22.7%).
Chemical Composition Oil and Ethanol Extract of Nutmeg Leaf and Antibacterial Test Against Staphylococcus aureus and Pseudomonas aeruginosa Imanuel Berly Delvis Kapelle; Fensia Analda Souhoka; Ainun Maharani Walla
Indonesian Journal of Chemical Research Vol 10 No 1 (2022): Edition for May 2022
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598/ijcr.2022.10-ima

Abstract

This study aims to determine the yield and composition of the essential oil and ethanol extract of nutmeg leaves and determine its antibacterial activity against Staphylococcus aureus and Pseudomonas aeruginosa bacteria. Nutmeg leaf oil was obtained by isolation using steam-water distillation and extraction methods using maceration with ethanol as solvent. The moisture content of nutmeg leaves is 11.11%. From the distillation method, 0.26% nutmeg oil was obtained, while the yield of nutmeg oil was 29.01% from the extraction method. Gas Chromatography-Mass Spectrometer analysis showed that distilled nutmeg oil contains 20 components with the main composition, namely myristicin (15.92%), b-phellandrene (14.35%), limonene (11.20%), b-pinene (10.81%), and a-pinene (8.59%). The ethanol extract of nutmeg leaf contains 37 components with the main composition being myristicin (7.64%), 1,1,3,3,5,5,7,7,9,9,11,11,13,13-tetradecamethylheptasiloxane (7.14%), 2,2-dimethyl-1-decanol (7.12%), bis(2-ethylhexyl) phthalate (5.55%), and 9-dodecane-1-al (4.63%). The antibacterial activity test of nutmeg oil was carried out using the good diffusion method. The inhibitory power of nutmeg oil and ethanol extract of nutmeg leaves against S. aureus bacteria were 20.31 mm and 23.56 mm, while against P. aeruginosa bacteria were 11.79 mm and 8.86 mm, respectively.
Effect of Heating Coarse Extract of Brown Macroalgae (Padina australis) from Tial Waters, Salahutu District, Central Maluku Regency on Antioxidant Activity Nurani Hasanela; Fensia Analda Souhoka
Indonesian Journal of Chemical Research Vol 10 No 2 (2022): Edition for September 2022
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598//ijcr.2022.10-nur

Abstract

Physical and chemical factors influence antioxidant activity. One of the physical factors that can affect antioxidant activity is heat. This study aims to determine the phytochemical content and the effect of heating the crude extract of marine macroalgae Padina australis on antioxidant activity. The research method used, namely maceration using methanol as a solvent to obtain a crude extract, then evaporation of the solvent at a temperature of 45 °C. Furthermore, phytochemical tests were carried out, characterization using TLC and UV-Vis spectrophotometer, and determination of free radical scavenging activity of DPPH. The results of the phytochemical test showed that the crude extract of Padina australis was positive for bioactive compounds, namely saponins, alkaloids, terpenoids, steroids, and flavonoids. Characterization by TLC and UV-Vis spectrophotometer showed the presence of secondary metabolites, namely chlorophyll a and carotenoids. The use of temperature in the solvent evaporation process affects the stability of bioactive compounds and secondary metabolites. The results of the antioxidant activity test (IC50) of the crude extract of Padina australis against DPPH obtained 163 ppm, so it is classified as an antioxidant in the medium category.
Characterization and Kinetic Study of Methylene Blue Photocatalytic on ZnO/ZSM-5 Hellna Tehubijuluw; Fensia Analda Souhoka; Yuly Kusumawati; Didik Prasetyoko; Riki Subagyo; Reva Edra Nugraha; Aishah Abdul Jalil
Indonesian Journal of Chemical Research Vol 11 No 2 (2023): Edition for September 2023
Publisher : Jurusan Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam, Universitas Pattimura

Show Abstract | Download Original | Original Source | Check in Google Scholar | DOI: 10.30598//ijcr.2023.11-hln

Abstract

Photodegradation of organic pollutants depends significantly on the structure of metal oxide-based semiconductor photocatalysts. ZnO/ZSM-5 has shown the potential to significantly improve its photocatalytic efficiency for removing waterborne pollutants. ZnO/ZSM-5 has been reported to be an active catalyst for degrading methylene blue. These methods commonly involve various catalytic reactions, with the Langmuir-Hinshelwood process being used to describe the reaction kinetics. A kinetic study on the photocatalytic degradation of methylene blue using ZnO/ZSM-5 was conducted under UV-LED lamp irradiation. ZnO/ZSM-5 was characterized using XRD, SEM, and N2 adsorption-desorption, and it was prepared via the impregnation method. The interaction between ZnO/ZSM-5 and methylene blue solutions over a period of 30 to 180 minutes was monitored using a UV-Vis spectrophotometer. The photocatalytic degradation of methylene blue followed first-order rate kinetics. The Langmuir-Hinshelwood (L-H) kinetic analysis revealed that the photocatalytic reaction constant (kc) was 4.207 L.mg-1. menit-1, and the Langmuir-Hinshelwood constant (K) was 261.509 L.mg-1.